Three-Circulation Methanol Synthesis From Captured CO2

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Solution Overview

Problem

Existing methods for producing methanol from carbon dioxide are inefficient and do not effectively integrate carbon dioxide capture and utilization, particularly from industrial processes, leading to high CO2 emissions and high operational costs.

Innovation Solution

A three-circulation process apparatus and method that integrates carbon dioxide capture and utilization by using a liquid absorbent of methanol and water to remove CO2 from gas mixtures, followed by desorption with hydrogen and subsequent methanol synthesis, optimizing temperature and pressure conditions to enhance efficiency and reduce costs.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-generated harmful factors

If conventional methanol synthesis methods are used, then methanol production is achieved, but CO2 emissions remain high and process efficiency is low

Engineering Contradiction:
ImproveCO2 emissionsVSAvoidmethanol production efficiency
Core Design Contradiction:
Object-generated harmful factorsVSProductivity

Solution Approach 1:

The patent combines CO2 capture and methanol synthesis into a single integrated process. The CO2 absorption unit and methanol synthesis unit are merged such that CO2 captured from industrial gas streams is directly converted to methanol without separate processing steps, thereby reducing emissions while maintaining high production efficiency

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The patent converts harmful CO2 emissions into valuable methanol product. By using CO2 from industrial gas streams as a feedstock for methanol synthesis, the process transforms a harmful greenhouse gas into a useful chemical commodity, simultaneously reducing emissions and improving production efficiency

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

2Quantity of substance

If CO2 is removed from gas mixtures using conventional methods, then CO2 separation is achieved, but operational costs are high

Engineering Contradiction:
ImproveCO2 removal efficiencyVSAvoidoperational costs
Core Design Contradiction:
Quantity of substanceVSLoss of energy

Solution Approach 1:

The patent merges CO2 separation with methanol synthesis in an integrated process. The CO2 absorbed by the liquid solvent is directly fed to the methanol synthesis unit, eliminating the need for separate CO2 purification and compression steps, thereby reducing operational costs while maintaining high CO2 removal efficiency

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The patent operates the absorption and synthesis units at optimized pressure and temperature parameters. The liquid solvent absorption occurs at moderate conditions, and the synthesized methanol is efficiently separated, reducing energy consumption and operational costs compared to conventional high-pressure separation methods

Inventive Principle:
Principle #35Parameter changes

3Object-generated harmful factors

If integrated methanol synthesis from CO2 is implemented, then emissions are reduced and sustainability is improved, but process complexity increases

Engineering Contradiction:
ImproveCO2 emissionsVSAvoidprocess integration complexity
Core Design Contradiction:
Object-generated harmful factorsVSDevice complexity

Solution Approach 1:

The patent integrates CO2 capture, conversion, and methanol synthesis into a compact unified process. By combining these functions in a single integrated system rather than separate units, the patent reduces overall process complexity while achieving emission reduction goals

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The liquid solvent serves multiple functions: it absorbs CO2 from gas streams, transports CO2 to the synthesis unit, and facilitates the conversion process. This multi-functionality reduces the number of separate components needed, thereby simplifying the overall process despite the integrated nature

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The process achieves continuous CO2 removal from industrial gas streams at low pressures, reducing emissions and operational costs while producing methanol efficiently, integrating hydrogen electrolysis for a sustainable process.

Implementation Method 1

an absorption stage (5) for carbon dioxide, having a passage for a carbon dioxide-containing gas

Methodology Applied
Scientific EffectAbsorption: Absorption (physical)

Implementation Method 2

a first heat exchanger (7) arranged between the absorption stage (5) and the desorption stage (6)

Methodology Applied
Scientific EffectHeat exchange: Heat Exchanger

Implementation Method 3

an expansion throttle (9) arranged between the first heat exchanger (7) and the absorption stage (5)

Methodology Applied
Scientific EffectJoule-Thomson effect: Joule-Thomson Effect

Implementation Method 4

a methanol synthesis reactor (26) with a cooler (28)

Methodology Applied
Scientific EffectCatalysis: Catalysis

Implementation Method 5

a methanol synthesis reactor (26) with a cooler (28)

Methodology Applied
Scientific EffectCondensation: Condensation

Implementation Method 6

a circulation pump (8) arranged between the absorption stage (5) and the desorption stage (6)

Methodology Applied
Scientific EffectPumping: Pump

Data Source

PatentUS12466777B2Device and method for producing methanol from carbon dioxide
Publication Date: 2025.11.11 KARLSRUHER INST FUR TECH
  • US12466777B2 patent drawing
  • US12466777B2 patent drawing
  • US12466777B2 patent drawing

AI summary

An apparatus for producing methanol from carbon dioxide. The apparatus includes a first circulation process for a circulating water and methanol which includes an absorption stage for carbon dioxide, a desorption stage with a hydrogen feed, a first heat exchanger, an outlet, a circulation pump, and an expansion throttle. The second circulation process for methanol, water, carbon dioxide and hydrogen includes the desorption stage, a first liquid-gas phase separation stage with a return conduit for liquid phases to the desorption stage, and a gas outlet from and an inlet into the desorption stage. The third circulation process for carbon dioxide and hydrogen includes a methanol synthesis reactor, a gas outlet of the first liquid-gas phase separation stage which opens out into the third circular conduit and an inlet into which the third circular conduit opens, a second heat exchanger, a gas outlet in the third circular conduit, and a fan.