CO2 Nanobubble Well Stimulation for Condensate Blockage Removal

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Solution Overview

Problem

Existing acid stimulation methods for enhancing well performance in subsurface formations face limitations, particularly with CO2 use, which is underutilized due to its potential benefits in reducing carbon footprint and addressing formation damage, yet lacks effective application in creating conductive channels and clearing condensate blockages.

Innovation Solution

The use of nanobubbles, specifically CO2 nanobubbles, in a stimulation fluid to enhance well stimulation by generating nano-sized bubbles that penetrate porous formations, deliver thermal and mechanical energy, and increase miscibility with condensate, thereby enhancing the effectiveness of acid stimulation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Loss of energy

If CO2 is used in acid stimulation fluid, then carbon footprint is reduced and miscibility with condensate is improved, but the effectiveness in creating conductive channels and clearing blockages is insufficient

Engineering Contradiction:
Improvecarbon footprintVSAvoidwell stimulation efficiency
Core Design Contradiction:
Loss of energyVSProductivity

Solution Approach 1:

The patent transforms CO2 from a dissolved gas state to nanobubble form, fundamentally changing its physical state and interaction mechanisms with the formation. This parameter change enables CO2 to provide both environmental benefits (replacing hydrofluoric acid) and enhanced stimulation effectiveness through mechanical energy delivery and improved condensate miscibility

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates a composite stimulation fluid system combining traditional acid components (HCl, surfactants, corrosion inhibitors) with CO2 nanobubbles. This composite approach integrates the chemical etching capability of acid with the mechanical energy and miscibility benefits of nanobubbles, achieving multiple functions simultaneously

Inventive Principle:
Principle #40Composite materials

2Productivity

If nanobubbles are generated in stimulation fluid, then conductive channels are created and condensate blockages are cleared, but fluid viscosity and hydraulic pressure increase

Engineering Contradiction:
Improveconductive channel creationVSAvoidhydraulic pressure
Core Design Contradiction:
ProductivityVSStress or pressure

Solution Approach 1:

The patent segments the gas phase into nanoscale bubbles distributed throughout the fluid, creating numerous small interfaces rather than large bubbles. This segmentation enables the gas to penetrate porous formations and deliver mechanical energy at the pore level without creating large gas pockets that would significantly increase bulk fluid pressure

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The nanobubbles are designed to interact with porous formation materials, penetrating into pore spaces to deliver mechanical energy and clear blockages. The porous structure of the formation itself becomes the medium through which nanobubbles operate, allowing localized action without global pressure increase

Inventive Principle:
Principle #31Porous materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Nanobubbles improve well stimulation efficiency by effectively creating conductive channels, clearing condensate blockages, and reducing formation damage without increasing viscosity or hydraulic pressure, thus improving well performance and reducing carbon footprint.

Implementation Method 1

deliver thermal and mechanical energy

Methodology Applied
Scientific EffectThermal energy delivery: Heating

Implementation Method 2

deliver thermal and mechanical energy

Methodology Applied
Scientific EffectMechanical energy delivery: Mechanical Force

Implementation Method 3

CO being miscible with the condensate

Methodology Applied
Scientific EffectMiscibility: Solvation

Data Source

PatentUS12352146B2Method for well stimulation using nanobubbles
Publication Date: 2025.07.08 SAUDI ARABIAN OIL CO
  • US12352146B2 patent drawing
  • US12352146B2 patent drawing
  • US12352146B2 patent drawing

AI summary

A composition and methods are provided for stimulating a well with nanobubbles. An exemplary method includes obtaining a stimulation fluid and generating a nanobubbles solution, wherein the nanobubbles solution includes nano-sized bubbles in the stimulation fluid. The nanobubbles solution is injected into the oil well.