CO2 Storage Plume Stabilization via Polymer Injection

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Solution Overview

Problem

Current methods for injecting supercritical CO2 into deep geological storage sites result in inefficient utilization of storage volume due to uneven 'fingering' of the CO2 injection front, leading to significant loss of storage capacity, and lack an economically viable method for monitoring CO2 plume movement and seepage.

Innovation Solution

The method involves injecting a first composition of CO2 followed by a second composition containing CO2 and one or more CO2-soluble polymers, cycling between gas-like and liquid-like supercritical phases to stabilize the CO2 plume and utilize the polymers' dual function as tracers for enhanced storage and monitoring.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If supercritical CO2 is injected into deep storage sites using current methods, then CO2 storage is achieved, but the storage volume utilization is inefficient due to uneven sweep and fingering phenomenon

Engineering Contradiction:
ImproveCO2 storage volumeVSAvoidstorage volume utilization efficiency
Core Design Contradiction:
Quantity of substanceVSProductivity

Solution Approach 1:

The patent changes the physical parameters of the injected fluid by adding polymers to CO2, transforming it from a simple supercritical fluid to a polymer-CO2 mixture with modified rheological properties. This parameter change allows the injected fluid to better match the reservoir fluid properties, reducing fingering and improving sweep efficiency, thereby increasing both storage volume and utilization efficiency

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite injection medium by combining CO2 with polymers (such as polyethylene glycol or fluorinated polymers). This composite material has tailored viscosity and density characteristics that enable more uniform distribution through the reservoir, overcoming the fingering problem and maximizing storage capacity utilization

Inventive Principle:
Principle #40Composite materials

2Stability of the object's composition

If Composition Swing Injection technique uses hydrocarbon components to achieve required phase behaviour, then CO2 plume stabilization is improved, but economic viability deteriorates due to loss of valuable hydrocarbons

Engineering Contradiction:
ImproveCO2 plume stabilityVSAvoideconomic loss of hydrocarbon value
Core Design Contradiction:
Stability of the object's compositionVSLoss of energy

Solution Approach 1:

The patent replaces valuable hydrocarbon components with inexpensive polymer alternatives that serve the same functional purpose of modifying phase behavior and stabilizing the CO2 plume. These polymers are much less valuable than hydrocarbons, thereby eliminating the economic loss while maintaining plume stability

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Solution Approach 2:

The patent introduces polymers as intermediary substances that mediate between CO2 and the reservoir environment to achieve the desired phase behavior and plume stabilization. These polymers act as substitutes for hydrocarbons, providing the necessary intermediate functionality without the associated economic cost

Inventive Principle:
Principle #24Intermediary (Mediator)

3Ease of manufacture

If existing storage sites are exploited to maximum capacity, then development costs are reduced, but storage volume is insufficient due to fingering loss

Engineering Contradiction:
Improvedevelopment costVSAvoidavailable storage volume
Core Design Contradiction:
Ease of manufactureVSQuantity of substance

Solution Approach 1:

By modifying the injection fluid parameters (adding polymers to change viscosity and density), the patent enables more efficient utilization of the existing storage site volume. This reduces the need to develop new sites, thereby lowering development costs while increasing the effective storage capacity of existing sites

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach significantly increases the storage capacity of geological formations by reducing fingering and allowing for effective monitoring of CO2 plume movement, thereby optimizing storage efficiency and reducing costs compared to conventional methods.

Implementation Method 1

a second composition comprising CO2 and at least one CO2 soluble polymer

Methodology Applied
Scientific EffectSolubility: Solvation

Implementation Method 2

the composition of the injected stream is changed in cycles to create gas-like and liquid-like states in order to stabilize the CO2 plume

Methodology Applied
Scientific EffectPhase transition: Phase Change

Implementation Method 3

CO2 is stored in supercritical state in the Utsira formation

Methodology Applied
Scientific EffectSupercritical fluid: Supercritical Fluid

Data Source

PatentEP2994515B1Method of storing co2
Publication Date: 2018.12.19 EQUINOR ENERGY AS
  • EP2994515B1 patent drawingFigure 1

AI summary

The present invention relates to a method of storing CO2 in a geological formation, said method comprising (i) injecting a first composition comprising CO2 into said formation; and (ii) injecting a second composition comprising CO2 and at least one CO2 soluble polymer into said formation, wherein steps (i) and (ii) are performed separately and in any order and wherein said first and second compositions are different.