CO2 Sensor Using Amine Nanoparticle Hybrid Material

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Solution Overview

Problem

Current CO2 sensors face challenges with high energy consumption, large size, high cost, and limited sensitivity, especially at lower temperatures, and lack stability and reversibility, making them unsuitable for efficient CO2 detection in various applications.

Innovation Solution

A hybrid CO2 sensor using a mixture of amines and nanoparticles, which changes electrical or optical properties in response to CO2 concentrations, allowing for rapid detection and low-power operation with improved selectivity and stability, integrated with transducers to output electrical signals.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If NDIR optical detection method is used, then measurement accuracy and long-term stability are improved, but device size, power consumption, and cost increase

Engineering Contradiction:
ImproveCO2 detection accuracyVSAvoidpower consumption
Core Design Contradiction:
Measurement precisionVSUse of energy by moving object

Solution Approach 1:

The patent replaces the complex optical NDIR detection system with a chemical sensing mechanism using metal oxide layers that directly interact with CO2 molecules. This substitution eliminates the need for infrared light sources, detectors, and associated optical components, thereby dramatically reducing power consumption while maintaining detection capability through electrochemical reactions between the metal oxide sensing layer and CO2

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent extracts and eliminates the power-intensive optical components (infrared LED, photodetector, optical path) from the sensor system. By using only the chemical interaction between metal oxide and CO2, the design removes unnecessary mechanical and optical subsystems, achieving low-power operation suitable for portable and continuous monitoring applications

Inventive Principle:
Principle #2Taking out (Extraction)

2Measurement precision

If NDIR optical detection method is used, then measurement accuracy is improved, but device size increases

Engineering Contradiction:
ImproveCO2 detection accuracyVSAvoiddevice size
Core Design Contradiction:
Measurement precisionVSVolume of moving object

Solution Approach 1:

The patent removes the bulky optical components including infrared light sources, optical chambers, and photodetectors from the sensor design. The remaining chemical sensing core using metal oxide layers occupies minimal space, enabling miniaturization of the entire device while preserving CO2 detection functionality through surface-level chemical reactions

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent employs thin film metal oxide layers as the sensing element, which can be deposited on small substrate areas. This thin-film approach replaces the need for large optical paths and chambers, allowing the sensor to be integrated into compact form factors suitable for portable devices and distributed monitoring networks

Inventive Principle:
Principle #30Flexible shells and thin films

3Measurement precision

If metal oxide sensors operate at high temperature (>100°C), then sensitivity is improved, but energy consumption increases

Engineering Contradiction:
Improvesensor sensitivityVSAvoidoperating energy
Core Design Contradiction:
Measurement precisionVSUse of energy by moving object

Solution Approach 1:

The patent modifies the operating temperature parameter from conventional high temperatures (>100°C) to ambient or near-ambient conditions. By selecting metal oxide materials and configurations that maintain sensitivity at lower temperatures, the system achieves acceptable detection performance without the energy penalty of active heating, thereby reducing power consumption for portable and continuous operation

Inventive Principle:
Principle #35Parameter changes

4Reliability

If metal oxide sensors are used, then long-term stability is improved, but cross-sensitivity to other gases worsens

Engineering Contradiction:
Improvelong-term stabilityVSAvoidgas selectivity
Core Design Contradiction:
ReliabilityVSAdaptability or versatility

Solution Approach 1:

The patent applies local quality by creating distinct metal oxide sensing layers with specific compositions and properties tailored to detect particular gases. Each sensing layer is optimized for specific gas interactions, allowing the sensor array to distinguish between different gases through pattern recognition while maintaining the inherent stability of metal oxide materials

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent uses composite or mixed metal oxide materials that combine the stability of metal oxides with enhanced selectivity properties. By creating composite sensing layers with specific material compositions, the system achieves both long-term stability and improved gas discrimination capability, reducing cross-sensitivity to non-target gases

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The sensor achieves rapid response and recovery times, high selectivity for CO2, and long-term stability without hysteresis, while being miniaturized and cost-effective, suitable for integration in mobile devices and various applications.

Implementation Method 1

a hybrid sensing material having a mixture of at least amines and nanoparticles, wherein the hybrid sensing material has an electrical or optical property and is configured to change the electrical or optical property dependent on a CO2 concentration

Methodology Applied
Scientific EffectChemical interaction between amines and CO2: Chemical Bonding

Data Source

PatentUS11435308B2CO2 sensor and method for manufacturing same
Publication Date: 2022.09.06 FRAUNHOFER GESELLSCHAFT ZUR FORDERUNG DER ANGEWANDTEN FORSCHUNG EV
  • US11435308B2 patent drawing
  • US11435308B2 patent drawing
  • US11435308B2 patent drawing

AI summary

A sensor device for sensing CO2 comprises a hybrid sensing material and a transducer. The hybrid sensing material comprises at least amines and nanoparticles, wherein the hybrid sensing material has a property and is configured to change the property dependent on a current CO2 concentration in the surrounding. The transducer is configured to output an electrical sensor signal dependent on the property of the hybrid sensing material.