CO2 Splitting via Kinetic Acceleration and Surface Collision

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Solution Overview

Problem

Current methods for converting carbon dioxide (CO2) into molecular oxygen (O2) are inefficient and energetically unfavorable, with existing pathways offering low yields and high energy costs, particularly in the context of atmospheric CO2 sequestration and extraterrestrial exploration.

Innovation Solution

Accelerating CO2 molecules against a solid surface with kinetic energies between 10 and 300 eV, either through electric fields or plasma ionization, to induce direct dissociation into O2 and C, utilizing specific surface materials like metals and oxides to enhance conversion efficiency.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If conventional methods are used to convert CO2 to O2, then the process is simpler, but the conversion efficiency is low and energy cost is high

Engineering Contradiction:
Improveconversion efficiencyVSAvoidenergy cost
Core Design Contradiction:
ProductivityVSUse of energy by moving object

Solution Approach 1:

The patent changes the kinetic energy parameter of CO2 molecules by accelerating them to specific energies (10-300 eV) before surface collision, transforming the low-efficiency thermal process into a high-efficiency kinetic process that achieves up to 33% conversion efficiency with lower energy input

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent replaces conventional thermal/chemical conversion mechanisms with a mechanical acceleration and collision system, where CO2 molecules are accelerated and directed to collide with solid surfaces, inducing dissociation through mechanical energy transfer rather than thermal processes

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Productivity

If CO2 molecules are accelerated to higher kinetic energies, then conversion efficiency improves, but energy input increases

Engineering Contradiction:
Improveconversion efficiencyVSAvoidenergy input
Core Design Contradiction:
ProductivityVSLoss of energy

Solution Approach 1:

The patent applies partial acceleration by limiting CO2 kinetic energy to the optimal range of 10-300 eV, which is sufficient to induce surface collision dissociation but not excessive, achieving high conversion efficiency while minimizing unnecessary energy input and loss

Inventive Principle:
Principle #16Partial or excessive action

3Productivity

If specific surface materials are used to enhance conversion, then productivity improves, but device complexity increases

Engineering Contradiction:
Improveconversion efficiencyVSAvoidsurface material selection
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The patent applies local quality by selecting specific solid surface materials with particular properties (metals, oxides) that are optimized for CO2 dissociation, concentrating the functional requirement in the surface layer rather than throughout the entire device structure

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Achieves a conversion efficiency of up to 33% for CO2 to O2, significantly surpassing previous methods, facilitating efficient CO2 removal from Earth's atmosphere and providing a viable source of O2 in CO2-rich extraterrestrial environments.

Implementation Method 1

Accelerating CO2 molecules against a solid surface with kinetic energies between 10 and 300 eV, either through electric fields or plasma ionization

Methodology Applied
Scientific EffectElectric field acceleration: Electric Field

Implementation Method 2

the carbon dioxide molecules subjected to acceleration are produced in a carbon dioxide plasma. In some such embodiments the plasma ionizes the carbon dioxide molecules to produce carbon dioxide ions

Methodology Applied
Scientific EffectPlasma ionization: Plasma

Implementation Method 3

accelerating carbon dioxide molecules against a solid surface at an incident angle such that the carbon dioxide molecules have kinetic energy E0 of between 10 and 300 eV at collision against the solid surface

Methodology Applied
Scientific EffectCollision-induced dissociation: Impact Force

Data Source

PatentUS11958741B2Method for splitting carbon dioxide into molecular oxygen and carbon
Publication Date: 2024.04.16 CALIFORNIA INST OF TECH
  • US11958741B2 patent drawing
  • US11958741B2 patent drawing
  • US11958741B2 patent drawing

AI summary

Apparatus and methods for facilitating an intramolecular reaction that occurs in single collisions of CO2 molecules (or their derivatives amenable to controllable acceleration, such as CO2+ ions) with a solid surface, such that molecular oxygen (or its relevant analogs, e.g., O2+ and O2− ions) is directly produced are provided. The reaction is driven by kinetic energy and is independent of surface composition and temperature. The methods and apparatus may be used to remove CO2 from Earth's atmosphere, while, in other embodiments, the methods and apparatus may be used to prevent the atmosphere's contamination with CO2 emissions. In yet other embodiments, the methods and apparatus may be used to obtain molecular oxygen in CO2-rich environments, such as to facilitate exploration of extraterrestrial bodies with CO2-rich atmospheres (e.g. Mars).