Liquid Fuel Synthesis from Carbon Dioxide and Water

Solution Overview

Problem

Current methods fail to efficiently produce liquid fuels from carbon dioxide and water, and existing fuel production processes contribute to global warming and resource depletion, necessitating a novel process for converting electrical energy into chemical energy for synthetic liquid hydrocarbon fuels that can replace conventional gasoline and diesel without requiring significant technical or infrastructural changes.

Innovation Solution

An integrated process that electrolyzes water to produce hydrogen, which is then reacted with carbon dioxide to form methanol or carbon monoxide, subsequently converted into high octane gasoline or diesel, utilizing reverse water gas shift reaction and Fisher-Tropsch synthesis, allowing for the production of sulfur-free liquid fuels.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If conventional electrolysis methods are used to produce hydrogen from water, then hydrogen can be obtained, but the process consumes large amounts of electrical energy and produces oxygen that must be separated and handled

Engineering Contradiction:
Core Design Contradiction:
Quantity of substanceVSUse of energy by moving object

Solution Approach 1:

The patent combines the electrolysis of water with the subsequent reaction of hydrogen and carbon dioxide in an integrated reactor system. The electrolyzer produces hydrogen that immediately reacts with carbon dioxide in the same system to form hydrocarbons, eliminating the need for separate hydrogen storage and handling, and utilizing the oxygen produced in the electrolysis process for the oxidation reactions that drive hydrocarbon formation.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The patent converts the oxygen byproduct of electrolysis, which would normally be a waste product requiring separation and handling, into a useful oxidizing agent for the hydrocarbon synthesis reactions. The oxygen generated during water electrolysis is used to oxidize carbon dioxide and facilitate the formation of hydrocarbons, turning a potentially harmful or wasteful byproduct into a beneficial reactant.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

2Quantity of substance

If existing fuel production processes are used, then liquid fuels can be produced, but they contribute to global warming through carbon dioxide emissions and deplete finite petroleum resources

Engineering Contradiction:
Core Design Contradiction:
Quantity of substanceVSObject-generated harmful factors

Solution Approach 1:

The patent takes carbon dioxide, a harmful greenhouse gas, and converts it into useful hydrocarbon fuels through a series of chemical reactions. The process uses electrolytically produced hydrogen to reduce carbon dioxide into carbon monoxide and then into hydrocarbons, effectively transforming a pollutant into a valuable energy carrier and closing the carbon cycle.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Solution Approach 2:

The patent fundamentally changes the source of carbon for fuel production - instead of extracting carbon from finite petroleum deposits, the process uses carbon dioxide from the atmosphere or industrial emissions as the carbon source. This parameter change in the carbon source transforms the process from depleting finite resources to utilizing abundant, renewable carbon.

Inventive Principle:
Principle #35Parameter changes

3Use of energy by moving object

If sulfur-containing fuels are used for combustion, then energy can be provided, but sulfur emissions contribute to acidification of rainwater

Engineering Contradiction:
Core Design Contradiction:
Use of energy by moving objectVSObject-generated harmful factors

Solution Approach 1:

The patent produces hydrocarbons from carbon dioxide and hydrogen through controlled chemical reactions that do not involve sulfur. The resulting fuels are inherently sulfur-free because sulfur is not introduced at any stage of the synthesis process, eliminating sulfur emissions at the source rather than requiring post-processing or cleanup.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

4Object-generated harmful factors

If new fuel production methods are developed to address environmental issues, then sustainable fuel can be produced, but significant technical developments and infrastructural changes are required

Engineering Contradiction:
Core Design Contradiction:
Object-generated harmful factorsVSDevice complexity

Solution Approach 1:

The patent merges multiple functions into a single integrated system: water electrolysis, hydrogen production, carbon dioxide reduction, and hydrocarbon synthesis all occur in one coupled system. This integration reduces the number of separate units and processes needed, simplifying the overall technical infrastructure compared to having separate facilities for each function.

Inventive Principle:
Principle #5Merging (Combining)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This process provides a nearly emission-free method to produce high octane gasoline or diesel from carbon dioxide and water using electricity, offering a sustainable alternative to conventional fuels that can immediately replace existing gasoline and diesel without the need for major technical developments or infrastructural changes.

Implementation Method 1

providing water and electricity and electrolyzing the water into hydrogen and oxygen

Methodology Applied
Scientific EffectElectrolysis: Electrolysis

Implementation Method 2

reacting it with the obtained hydrogen to produce carbon monoxide and water

Methodology Applied
Scientific EffectReverse water gas shift reaction:

Implementation Method 3

reacting the obtained carbon monoxide and hydrogen in one or more steps to produce liquid fuel

Methodology Applied
Scientific EffectFisher-Tropsch synthesis:

Data Source

PatentUS8506910B2Process and system for producing liquid fuel from carbon dioxide and water
Publication Date: 2013.08.13
  • US8506910B2 patent drawing
  • US8506910B2 patent drawing
  • US8506910B2 patent drawing

AI summary

A process and system for producing high octane fuel from carbon dioxide and water is disclosed. The feedstock for the production line is industrial carbon dioxide and water, which may be of lower quality. The end product can be high octane gasoline, high cetane diesel or other liquid hydrocarbon mixtures suitable for driving conventional combustion engines or hydrocarbons suitable for further industrial processing or commercial use. Products, such as dimethyl ether or methanol may also be withdrawn from the production line. The process is nearly emission free and reprocesses all hydrocarbons not suitable for liquid fuel to form high octane products. The heat generated by exothermic reactions in the process is fully utilized as is the heat produced in the reprocessing of hydrocarbons not suitable for liquid fuel.