Coacervate Adhesive Wet Surface Bonding

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Solution Overview

Problem

Current adhesive technologies face challenges in providing a strong, water-borne adhesive that can effectively bond substrates in wet environments without dispersing into water and ensuring dimensional stability post-application, while also offering antimicrobial properties.

Innovation Solution

The development of a coacervate comprising a polycation and polyanion that forms a complex coacervate, which can crosslink to create a strong, insoluble adhesive with low interfacial tension, allowing it to spread evenly on wet surfaces and maintain structural integrity underwater, along with antimicrobial activity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of operation

If a water-borne adhesive is used to bond substrates in wet environments, then the adhesive can be applied in aqueous conditions, but it disperses into water and loses structural integrity

Engineering Contradiction:
Improveapplicability in wet environmentsVSAvoidstructural integrity
Core Design Contradiction:
Ease of operationVSReliability

Solution Approach 1:

The patent changes the physical-chemical parameters of the adhesive system by using complex coacervates with specific interfacial tension properties. The coacervate droplets maintain a balanced interfacial tension that prevents dispersion in water while allowing spreading on substrates, resolving the contradiction between water-borne applicability and structural integrity

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention uses composite coacervate systems formed by complexation of polycations and polyanions. This composite structure creates droplets with tailored interfacial properties that maintain structural integrity in water while enabling wet environment application

Inventive Principle:
Principle #40Composite materials

2Area of stationary object

If the adhesive spreads evenly on wet surfaces, then it achieves good coverage, but it may lose concentration and bonding strength

Engineering Contradiction:
Improvesurface coverageVSAvoidbonding strength
Core Design Contradiction:
Area of stationary objectVSStrength

Solution Approach 1:

The patent optimizes the interfacial tension parameter of the coacervate droplets to achieve a balance between spreading and concentration retention. The specific interfacial tension range enables the adhesive to spread evenly while maintaining sufficient concentration for strong bonding

Inventive Principle:
Principle #35Parameter changes

3Strength

If conventional adhesives are used, then they provide basic bonding, but they lack antimicrobial properties and require additional components

Engineering Contradiction:
Improvebonding capabilityVSAvoidnumber of components
Core Design Contradiction:
StrengthVSDevice complexity

Solution Approach 1:

The patent incorporates antimicrobial agents directly into the coacervate formulation, creating a multi-functional adhesive system. The single coacervate composition provides both bonding and antimicrobial protection, eliminating the need for separate antimicrobial components

Inventive Principle:
Principle #6Universality (Multi-functionality)

Solution Approach 2:

The invention merges the adhesive function and antimicrobial function into a single integrated coacervate system. The polycation-polyanion complex structure inherently provides antimicrobial activity while maintaining bonding capability, combining multiple functions in one material

Inventive Principle:
Principle #5Merging (Combining)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The coacervate adhesive effectively bonds substrates in wet conditions, maintains dimensional stability, and exhibits antimicrobial properties, enhancing mechanical properties and preventing infections.

Implementation Method 1

a coacervate comprising a polycation and polyanion

Methodology Applied
Scientific EffectElectrostatic interactions: Ion Repulsion/Attraction

Implementation Method 2

low interfacial tension, allowing it to spread evenly on wet surfaces

Methodology Applied
Scientific EffectInterfacial tension: Surface Tension

Implementation Method 3

forms a complex coacervate, which can crosslink to create a strong, insoluble adhesive

Methodology Applied
Scientific EffectPhase separation: Phase Change

Data Source

PatentEP2953992B1Polymers, preparation and use thereof
Publication Date: 2021.11.24 3M INNOVATIVE PROPERTIES CO
  • EP2953992B1 patent drawingFigure 1
  • EP2953992B1 patent drawingFigure 2
  • EP2953992B1 patent drawing

AI summary

The present teachings provide novel polymers, and methods of preparing and using thereof. The novel polymers each includes a sulfide, sulfinyl, or sulfonyl bond. The novel polymer are used to make polycations and/or polyanions, which can be used, for example, to produce adhesive complex coacervates.