Coalescing Filter Purification of Epoxidized Ester Plasticizers

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Solution Overview

Problem

Current methods for purifying epoxidized ester plasticizers are cumbersome and costly, often requiring high temperatures, large volumes of water, and multiple washing steps, which can lead to heat-related defects and generate waste, while also being inefficient in removing metal ions and other impurities that affect the electrical properties and stability of PVC plastics.

Innovation Solution

A continuous purification process using a coalescer to remove ions, metals, and alcohol impurities from epoxidized ester plasticizers at room temperature, eliminating the need for heat, vacuum, extraction/washing steps, and phase separation, resulting in a purified plasticizer with reduced impurity content.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If traditional washing and extraction methods are used to purify plasticizers, then impurity removal is achieved, but the process becomes cumbersome and costly with heat-related defects and waste generation

Engineering Contradiction:
Improvepurity of plasticizerVSAvoidcomplexity of purification process
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The invention extracts and removes impurities (metal ions, alcohol, water) from the plasticizer composition through a simplified purification process that eliminates the need for complex multiple washing and extraction steps, achieving high purity while reducing process complexity

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The invention changes the parameters of the purification process by conducting it at room temperature instead of high temperatures, and uses a single-step method instead of multiple steps, thereby simplifying the process while maintaining or improving purification effectiveness

Inventive Principle:
Principle #35Parameter changes

2Manufacturing precision

If high temperatures and multiple washing steps are used, then purification is achieved, but heat-related defects occur and waste is generated

Engineering Contradiction:
Improvepurity of plasticizerVSAvoidheat-related defects and waste
Core Design Contradiction:
Manufacturing precisionVSObject-generated harmful factors

Solution Approach 1:

The invention converts the harmful effect of heat by eliminating the need for high temperature processing, achieving purification at room temperature and thereby preventing heat-related defects and waste generation while maintaining purification effectiveness

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Solution Approach 2:

The invention extracts and removes impurities (metal ions, alcohol, water) from the plasticizer composition through a simplified purification process that eliminates the need for complex multiple washing and extraction steps, achieving high purity while reducing process complexity

Inventive Principle:
Principle #2Taking out (Extraction)

3Manufacturing precision

If traditional purification methods are used, then some impurities are removed, but metal ions and other impurities affecting electrical properties remain

Engineering Contradiction:
Improveremoval of impuritiesVSAvoidelectrical properties and stability of PVC
Core Design Contradiction:
Manufacturing precisionVSReliability

Solution Approach 1:

The invention extracts and removes impurities (metal ions, alcohol, water) from the plasticizer composition through a simplified purification process, achieving high purity that improves the electrical properties and stability of PVC plastics

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The invention uses ion-selective electrodes to monitor and measure metal ion concentrations during the purification process, providing real-time feedback that enables precise control and ensures thorough removal of impurities affecting electrical properties

Inventive Principle:
Principle #23Feedback

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The process effectively reduces metal and ion impurities to below detection limits, significantly improving the purity and stability of the plasticizers, enhancing the electrical properties and sustainability of PVC plastics without causing heat-related defects.

Implementation Method 1

contacting a plasticizer composition containing at least one impurity selected from the group consisting of metal ions, alcohol, and water with a coalescing filter to effect phase separation into a phase enriched in impurities and a purified plasticizer effluent phase

Methodology Applied
Scientific EffectPhase separation: Phase Change

Data Source

PatentUS10745368B2Purification of plasticizers
Publication Date: 2020.08.18 ARCHER DANIELS MIDLAND CO

AI summary

Plasticizers are purified by contact with a coalescing filter to effect removal of ions, metals, monohydric alcohols, and polyhydric alcohols. The resulting purified plasticizer compositions are suitable for use in PVC due to their low levels of impurities that reduce PVC utility.