Coated Glass for Photovoltaic Cells with Low Haze

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Solution Overview

Problem

Existing coated glass articles for photovoltaic cells face challenges in maximizing visible light entry and minimizing electrical resistance, which affects power output.

Innovation Solution

A coated glass article is developed with a glass substrate and multiple coating layers, including a first layer of fluorine doped tin oxide and a second layer of silicon dioxide with phosphorus or boron, optimized to reduce haze and electrical resistance, enhancing light transmission and conductivity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a coating is deposited on glass substrate to form conductive layer for photovoltaic cell, then electrical resistance is reduced, but visible light transmission is blocked

Engineering Contradiction:
Improveelectrical resistanceVSAvoidvisible light transmission
Core Design Contradiction:
ReliabilityVSIllumination intensity

Solution Approach 1:

The coating is divided into multiple layers: a first coating layer (conductive metal oxide like ITO or FTO) and a second coating layer (different material composition). This segmentation allows each layer to perform its specialized function - the first layer provides electrical conductivity while the second layer optimizes optical properties for light transmission, resolving the contradiction between electrical performance and optical transparency.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent employs composite material structure with at least two different coating materials deposited on the glass substrate. The first coating material provides electrical conductivity, while the second coating material is selected to have complementary optical properties. This composite approach enables simultaneous achievement of low electrical resistance and high visible light transmission, which cannot be achieved with a single material.

Inventive Principle:
Principle #40Composite materials

2Reliability

If coating thickness is increased to improve conductivity, then electrical resistance decreases, but light transmission is reduced

Engineering Contradiction:
Improveelectrical resistanceVSAvoidpower output
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

Instead of using a single thick coating layer, the patent segments the coating into multiple thinner layers with different material compositions. The first coating layer can be optimized for conductivity at a specific thickness, while the second coating layer compensates for any light transmission loss. This allows achieving low electrical resistance without sacrificing light transmission, thereby maintaining high power output.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent changes the material composition parameter between layers rather than simply increasing thickness. By selecting a second coating material with different optical and electrical properties, the system can tune the overall performance to achieve optimal balance between conductivity and light transmission, avoiding the trade-off that would result from merely thickening a single layer.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The coated glass article improves light transmission and reduces electrical resistance, leading to increased power output and reduced losses in photovoltaic cells.

Implementation Method 1

The first coating layer comprises fluorine doped tin oxide

Methodology Applied
Scientific EffectIonic conduction: Conduction (electrical)

Implementation Method 2

The second coating layer comprises silicon dioxide and at least one of phosphorus and boron

Methodology Applied
Scientific EffectRefraction: Refraction

Implementation Method 3

The coated glass article exhibits a haze of 2.0% or less

Methodology Applied
Scientific EffectAbsorption (EM radiation): Absorption (EM radiation)

Data Source

PatentUS11542194B2Coated glass article, method of making the same, and photovoltaic cell made therewith
Publication Date: 2023.01.03 PILKINGTON GRP LTD
  • US11542194B2 patent drawing
  • US11542194B2 patent drawing
  • US11542194B2 patent drawing

AI summary

A coated glass article includes a glass substrate. A coating is formed on the glass substrate. The coating includes a first coating layer. The first coating layer includes fluorine doped tin oxide. A second coating layer is provided between the glass substrate and the first coating layer. The second coating layer includes silicon dioxide and at least one of phosphorus and boron. The coated glass article exhibits a haze of 2.0% or less.