Low-Stickiness Sunscreen Composition with Coated Microfine Zinc Oxide

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Solution Overview

Problem

Existing sunscreens with high UV filter content often exhibit stickiness and sand adhesion, leading to insufficient protection and consumer dissatisfaction, and some UV filters like octocrylene raise health concerns.

Innovation Solution

A sunscreen composition combining microfine zinc oxide with specific surface coatings, 2,4-bis{[4-(2-ethylhexyloxy)-2-hydroxy]phenyl}-6-(4-methoxyphenyl)-1,3,5-triazine, 2-phenylbenzimidazole-5-sulfonic acid, and 4,4'-((6((4 (((1,1-dimethylethyl)amino)carbonyl)phenyl)-amino)-1,3,5-triazine-2,4-diyl)diimino)bis(2-ethylhexyl)benzoate, with particle sizes and coatings optimized to reduce stickiness and sand adhesion.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If high UV filter content is used to achieve high sun protection factor, then skin protection effectiveness is improved, but stickiness and sand adhesion increase

Engineering Contradiction:
Improvesun protection factorVSAvoidstickiness and sand adhesion
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The patent applies parameter changes by using microfine zinc oxide with specifically controlled particle size (50-200 nm Dn50) and applying surface coatings (aluminum stearate, stearic acid, methicone, simethicone, triethoxycaprylylsilane, or octyltrimethoxysilane) to modify the physical and chemical properties of the UV filter, thereby reducing stickiness and sand adhesion while maintaining high SPF

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses composite materials by combining microfine zinc oxide with specific surface coatings to create a composite UV filter system that maintains high UV protection while reducing the harmful sticky properties through the coating layer

Inventive Principle:
Principle #40Composite materials

2Stability of the object's composition

If octocrylene is used as UV filter and solvent to improve solubility of triazine derivatives, then solubility is improved, but health concerns and consumer acceptance deteriorate

Engineering Contradiction:
Improvesolubility of UV filtersVSAvoidhealth concerns and consumer rejection
Core Design Contradiction:
Stability of the object's compositionVSObject-affected harmful factors

Solution Approach 1:

The patent extracts and removes octocrylene from the formulation, replacing it with microfine zinc oxide as the primary UV filter. This eliminates the controversial ingredient while maintaining the necessary UV protection and solubility through the zinc oxide-based system with surface coatings

Inventive Principle:
Principle #2Taking out (Extraction)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition achieves a high sun protection factor with reduced stickiness and sand adhesion, avoiding the use of controversial UV filters like octocrylene, ensuring effective and safe skin protection.

Implementation Method 1

a surface coating which is hydrophobic or lipophobic

Methodology Applied
Scientific EffectHydrophobe: Hydrophobe

Implementation Method 2

microfine zinc oxide, wherein preferably the microfine zinc oxide has a mean particle size Dn50 as determined by Laser diffraction selected in the range from 50 to 200 nm

Methodology Applied
Scientific EffectScattering: Scattering

Implementation Method 3

microfine zinc oxide... for protecting the skin against the detrimental effects of UV-light

Methodology Applied
Scientific EffectAbsorption (EM radiation): Absorption (EM radiation)

Data Source

PatentEP4054518B1Sunscreen composition with low stickiness
Publication Date: 2025.07.23 DSM IP ASSETS BV

AI summary

The present invention relates to a topical preparation comprising a UV filter combination of certain microfine zinc oxide, 2,4-bis{[4-(2-ethylhexyloxy)-2-hydroxy]phenyl}-6-(4-methoxyphenyl)-1,3,5-triazine (INCI: Bis-Ethylhexyloxyphenol methoxyphenyl Triazine), 2-phenylbenzimidazole-5-sulfonic acid and/or one or more salts thereof and 4,4'-((6((4 (((1,1-dimethylethyl)amino)carbonyl)phenyl)-amino)- 1,3,5-triazine-2,4-diyl)diimino)bis(2-ethylhexyl)benzoate (INCI: Diethylhexyl butamido triazone).