Coated Retaining Ring for CMP Wear Resistance

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Solution Overview

Problem

The retaining rings in polishing systems for semiconductor substrates experience wear and require frequent replacement due to chemical and mechanical degradation during the CMP process, necessitating a solution to enhance their durability.

Innovation Solution

A process-resistant coating, comprising materials like linear polyparaxylylene or polyether ether ketones, is applied to the retaining ring, providing a thin, conformal layer that resists chemical and physical degradation, with a thickness less than 100 μm, and can be selectively applied to areas with varying wear profiles, improving the ring's durability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If the retaining ring is made durable through material selection, then it can withstand mechanical stress, but it remains vulnerable to chemical degradation from polishing materials

Engineering Contradiction:
Improvemechanical strengthVSAvoidchemical resistance
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The retaining ring is constructed as a composite structure with a metal substrate providing mechanical strength and a process-resistant coating layer providing chemical resistance. This composite approach allows each material to contribute its superior properties, resolving the contradiction between mechanical durability and chemical resistance.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

A process-resistant coating layer acts as an intermediary between the metal retaining ring and the harsh polishing environment. This coating layer protects the underlying metal from direct chemical contact with polishing materials while allowing the metal to provide structural support.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Productivity

If the retaining ring surfaces are made contact with polishing pad to facilitate polishing, then polishing effectiveness is improved, but wear of the retaining ring increases

Engineering Contradiction:
Improvepolishing effectivenessVSAvoidretaining ring lifespan
Core Design Contradiction:
ProductivityVSDuration of action of stationary object

Solution Approach 1:

The process-resistant coating serves as an intermediary protective layer between the retaining ring and the polishing pad contact interface. It allows the retaining ring to perform its polishing function while the coating absorbs the wear and chemical degradation from pad contact.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The surface properties of the retaining ring are modified through the application of a process-resistant coating with different material properties than the base metal. This changes the surface's resistance to wear and chemical attack while maintaining the structural integrity needed for polishing operations.

Inventive Principle:
Principle #35Parameter changes

3Manufacturing precision

If the retaining ring is replaced frequently to maintain polishing quality, then polishing effectiveness is maintained, but production time is lost and cost increases

Engineering Contradiction:
Improvepolishing qualityVSAvoidreplacement downtime
Core Design Contradiction:
Manufacturing precisionVSLoss of time

Solution Approach 1:

The process-resistant coating is applied in advance to the retaining ring before it enters service. This preliminary protective action ensures the retaining ring is pre-equipped with wear and chemical resistance, extending its service life and reducing the frequency of replacements needed to maintain polishing quality.

Inventive Principle:
Principle #10Preliminary action

4Reliability

If a thick coating is applied to the retaining ring to maximize protection, then chemical resistance is improved, but the coating may peel or delaminate under mechanical stress

Engineering Contradiction:
Improvechemical resistanceVSAvoidcoating adhesion
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The coating thickness is optimized to a specific range that balances chemical resistance with mechanical durability. The coating is applied as a thin to moderate thickness layer, thick enough to provide chemical protection but thin enough to maintain good adhesion and flexibility under mechanical stress.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The coating significantly extends the lifespan of the retaining ring by protecting it from chemical interaction and wear, reducing the need for frequent replacements and maintaining the effectiveness of the polishing process.

Implementation Method 1

the coating comprising a vapor deposited, process-resistant material

Methodology Applied
Scientific EffectVapor deposition: Physical Vapour Deposition

Data Source

PatentUS9731399B2Coated retaining ring
Publication Date: 2017.08.15 APPLIED MATERIALS INC
  • US9731399B2 patent drawing
  • US9731399B2 patent drawing
  • US9731399B2 patent drawing

AI summary

A retaining ring for a polishing system is disclosed. The retaining ring has a process-resistant coating over a portion thereof. The process-resistant coating is a thin, smooth, conformal layer that is resistant to wear and chemical attack. The process-resistant coating is formed by a method that includes vapor deposition from a precursor gas mixture, which may deposit polyparaxyxylene from a gas mixture comprising paracyclophane. Adhesion of the process-resistant coating to the retaining ring may be enhanced by treating the surface of the ring prior to forming the coating. Resistance of the coating to the process may be further enhanced by treating the surface of the coating with an etching or deposition gas to impart texture.