Coated Rubber Particle Plugging Material for Oil-Based Drilling Fluids

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Solution Overview

Problem

Current plugging materials for oil-based drilling fluids lack specialized components that provide high strength, oil resistance, and elastoplasticity, leading to ineffective plugging and potential re-leakage during deep well drilling.

Innovation Solution

Development of a coated rubber particle with a fluorine-containing coating layer and an inorganic particle component, which has a low 24-hour oil absorption rate and enhanced high-valence metal content, improving its oil resistance and pressure-bearing capacity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Adaptability or versatility

If conventional water-based drilling fluid plugging materials are used in oil-based drilling fluid, then plugging operation can be performed, but the materials have oil solubility and poor compatibility, leading to reduced plugging effect and potential reverse impact on drilling fluid performance

Engineering Contradiction:
Improvecompatibility with oil-based drilling fluidVSAvoidplugging effect
Core Design Contradiction:
Adaptability or versatilityVSReliability

Solution Approach 1:

The patent applies local quality by creating a coated rubber particle with distinct core and coating regions having different properties. The rubber core provides elasticity and deformation capability, while the fluorine-containing coating layer provides oil resistance and chemical stability. This local differentiation allows the material to simultaneously achieve compatibility with oil-based drilling fluid and reliable plugging effect, resolving the contradiction between adaptability and reliability.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent employs composite materials by combining rubber particles with fluorine-containing inorganic coating materials to create a coated rubber particle composite. This composite structure integrates the elastoplastic properties of rubber with the oil resistance and high-valence metal content of fluorine-containing inorganic materials, enabling the plugging material to function effectively in oil-based drilling fluid while maintaining both adaptability and plugging reliability.

Inventive Principle:
Principle #40Composite materials

2Duration of action of moving object

If elastoplastic plugging particles are used to achieve deformation capability, then plugging can be formed, but the particles have oil solubility and reduced strength after prolonged exposure to oil-based drilling fluid

Engineering Contradiction:
Improveduration of plugging performanceVSAvoidstrength and elasticity
Core Design Contradiction:
Duration of action of moving objectVSStrength

Solution Approach 1:

The coated structure creates local quality differentiation where the fluorine-containing coating layer protects the rubber core from oil penetration. This protective barrier maintains the strength and elasticity of the rubber core over extended periods in oil-based drilling fluid, resolving the contradiction between duration of action and strength retention.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent effectively creates a long-lasting plugging material by preventing the rubber core from degrading. The fluorine-containing coating acts as a protective barrier that prevents oil from penetrating and dissolving the rubber, thereby extending the service life and maintaining the strength and elasticity of the plugging particles throughout the drilling operation.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

3Object-affected harmful factors

If rubber particles are used as plugging material, then elastoplasticity is achieved, but oil resistance is poor and dissolution occurs in oil-based drilling fluid

Engineering Contradiction:
Improveoil resistanceVSAvoidchemical stability
Core Design Contradiction:
Object-affected harmful factorsVSStability of the object's composition

Solution Approach 1:

The fluorine-containing coating layer serves as an intermediary barrier between the rubber core and the oil-based drilling fluid. This intermediate layer prevents direct contact and chemical interaction between the rubber and oil, providing oil resistance and maintaining the chemical stability of the rubber core, thereby resolving the contradiction between oil resistance and compositional stability.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The coated rubber particle composite combines the elastoplastic properties of rubber with the oil resistance and chemical stability of fluorine-containing inorganic coating materials. This composite structure allows the material to withstand prolonged exposure to oil-based drilling fluid without dissolution, achieving both oil resistance and compositional stability simultaneously.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The coated rubber particle demonstrates improved oil resistance and strength, maintaining effective plugging performance even after prolonged exposure to oil-based drilling fluids under high-temperature and high-pressure conditions.

Implementation Method 1

the coating layer has a fluorine content (at %) of 30-80% and the coated rubber particle has a 24-hour oil absorption rate of 4% or less

Methodology Applied
Scientific EffectHydrophobe: Hydrophobe

Implementation Method 2

a coated rubber particle, comprising a rubber core and a coating layer

Methodology Applied
Scientific EffectAdhesion: Adhesive

Data Source

PatentUS12291668B2Coated rubber particle, its preparation and application thereof
Publication Date: 2025.05.06 CHINA PETROLEUM & CHEMICAL CORP
  • US12291668B2 patent drawing
  • US12291668B2 patent drawing

AI summary

Disclosed is a coated rubber particle, preparation thereof and its application as a plugging material in drilling fluids. The coated rubber particle comprises a rubber core and a coating layer, wherein the core has a fluorine content (at %) of 0-15%, the coating layer has a fluorine content (at %) of 30-80%, and the coated rubber particle has a 24-hour oil absorption rate of 4% or less. The coated rubber particle has good oil resistance, and is particularly suitable for use as a plugging material in drilling fluids, particularly oil-based drilling fluids.