Coated Solid Bleaching Agent for Detergent Stability

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Solution Overview

Problem

Existing solid bleaching agents face issues with deterioration, deactivation, and decomposition when mixed with other components, leading to reduced effectiveness in washing, sterilization, and bleaching, and they often cause foaming and residue formation, limiting their applications.

Innovation Solution

A solid bleaching agent with a coating layer formed from alkali metal salts of aromatic carboxylic acids, acyclic dicarboxylic acids, or acyclic monocarboxylic acids, which stabilizes the bleaching agent, prevents foaming, and ensures good solubility in water without residue formation, allowing for broader application in detergents.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If the solid bleaching agent is used as a mixture with other components, then the washing, sterilization, and bleaching effects are enhanced, but the solid bleaching agent reacts with other components causing deterioration, deactivation, or decomposition

Engineering Contradiction:
Improvestability of solid bleaching agentVSAvoidapplicability with other components
Core Design Contradiction:
ReliabilityVSAdaptability or versatility

Solution Approach 1:

The solid bleaching agent is separated from other detergent components by enclosing it in a coating layer, allowing the detergent to contain both the bleaching agent and other components without direct interaction. This segmentation maintains stability while enabling versatility.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The coating layer acts as an intermediary barrier between the solid bleaching agent and other detergent components. This intermediate layer prevents harmful reactions while allowing the components to coexist in the same detergent formulation.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Reliability

If synthetic surfactants or fatty acid soaps are used as coating materials, then stability of the solid bleaching agent is improved, but excessive foaming occurs requiring excessive rinsing work

Engineering Contradiction:
Improvestability of solid bleaching agentVSAvoidfoam generation
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The coating material is changed from conventional surfactants and fatty acid soaps to water-soluble polymers, fundamentally changing the foaming characteristics. This parameter change eliminates excessive foam generation while maintaining the protective function of the coating layer.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The coating layer is formed as a composite material comprising water-soluble polymer and optionally water-soluble inorganic salt, combining the protective function with low foaming properties, unlike conventional surfactant-based coatings.

Inventive Principle:
Principle #40Composite materials

3Reliability

If paraffin wax or microcrystalline wax is used as coating material, then the solid bleaching agent is protected, but residues remain and solubility in water is poor

Engineering Contradiction:
Improveprotection of solid bleaching agentVSAvoidresidue formation
Core Design Contradiction:
ReliabilityVSLoss of substance

Solution Approach 1:

The coating material is changed from water-insoluble waxes to water-soluble polymers, fundamentally changing the solubility parameter. This ensures the coating layer dissolves completely in water during washing, eliminating residue formation while maintaining protection during storage.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The coating layer is designed as a temporary protective structure that serves its purpose during storage and transport, then dissolves completely during use. This disposable approach eliminates residues while providing necessary protection when needed.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

4Reliability

If organic polymers such as polyoxyethylene-polyoxypropylene are used for coating, then the solid bleaching agent is protected, but reactivity occurs requiring isolation layers

Engineering Contradiction:
Improveprotection of solid bleaching agentVSAvoidcoating structure complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The coating material is changed from reactive organic polymers to water-soluble polymers with different chemical properties that do not react with the solid bleaching agent. This parameter change eliminates the need for additional isolation layers, simplifying the coating structure to a single functional layer.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The coated solid bleaching agent maintains stability and effectiveness in detergents, preventing deterioration and decomposition, reducing foaming, and ensuring effective washing and sterilization without residue formation, thus expanding its application range.

Implementation Method 1

a solid bleaching agent-containing material having a coating layer, and a detergent composition in which the same is blended, wherein the solid bleaching agent-containing material having a coating layer can be stabilized by protecting a solid bleaching agent from deterioration, deactivation and decomposition

Methodology Applied
Scientific EffectChemical stability:

Implementation Method 2

effects of generating only a small amount of foaming or no foaming can be exerted

Methodology Applied
Scientific EffectFoam suppression: Antifoam

Implementation Method 3

effects of having good solubility in water and of generating only a small amount of residues or no residues can be exerted

Methodology Applied
Scientific EffectSolubility: Solvation

Data Source

PatentEP3447114B1Material containing solid bleaching agent, and detergent composition
Publication Date: 2023.08.30 SHIKOKU CHEM CORP
  • EP3447114B1 patent drawing
  • EP3447114B1 patent drawing
  • EP3447114B1 patent drawing

AI summary

A stabilized solid bleaching agent which has good solubility in water without undergoing the occurrence of foaming and without generating residues has been demanded. The present invention provides a stabilized solid-bleaching-agent-containing material having a coating layer formed therein, wherein the coating layer contains at least one component selected from the group consisting of an alkali metal salt of an aromatic carboxylic acid, an alkali metal salt of a non-cyclic dicarboxylic acid, an alkali metal salt of a non-cyclic monocarboxylic acid having 1 to 7 carbon atoms and mixtures thereof.