Coated Substrate Feathering Reduction Trivalent Chromium Pretreatment

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Solution Overview

Problem

Coatings used in food and beverage packaging often lack multiple desirable properties such as high-speed application, good adhesion, and safety for food contact, with hexavalent chromium-free substrates experiencing undesirable feathering issues that pose safety risks due to potential ingestion of coating materials.

Innovation Solution

A coating composition comprising a polymeric binder and a feathering reducing agent with a carboxylic acid reactive functional group, applied over a pretreatment layer containing a trivalent chromium compound, which reduces feathering and enhances adhesion and safety.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If hexavalent chromium-free substrates (trivalent chromium) are used, then safety for food contact is improved, but feathering occurs causing coating integrity to deteriorate

Engineering Contradiction:
Improvesafety for food contactVSAvoidcoating integrity
Core Design Contradiction:
Object-affected harmful factorsVSReliability

Solution Approach 1:

A pretreatment layer comprising chromium hydroxide or chromium oxyhydroxide is applied as an intermediary between the trivalent chromium substrate and the coating composition. This intermediary layer modifies the substrate surface properties to prevent feathering while maintaining the safety benefits of chromium-free substrates, enabling both coating integrity and food contact safety

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent changes the chemical and physical parameters of the substrate surface through the pretreatment layer, modifying surface energy, roughness, and reactivity to eliminate feathering. The coating composition parameters are also adjusted with specific resins and additives to optimize performance on the pretreated surface

Inventive Principle:
Principle #35Parameter changes

2Productivity

If conventional coatings are applied to achieve high-speed application, then productivity is improved, but adhesion to the substrate deteriorates

Engineering Contradiction:
Improveapplication speedVSAvoidadhesion
Core Design Contradiction:
ProductivityVSStrength

Solution Approach 1:

The pretreatment layer is applied in advance to prepare the substrate surface for optimal coating adhesion. This preliminary action creates a surface that promotes strong bonding, allowing conventional high-speed coating application methods to achieve both productivity and adhesion requirements

Inventive Principle:
Principle #10Preliminary action

3Manufacturing precision

If feathering is reduced to improve coating integrity, then manufacturing precision is improved, but process complexity increases

Engineering Contradiction:
Improvecoating uniformityVSAvoidprocess complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The pretreatment layer serves as a simple intermediary that addresses the feathering problem without requiring complex equipment modifications. This approach achieves manufacturing precision through material selection rather than process complexity

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution effectively reduces feathering by at least 20% and improves adhesion and safety, ensuring the coating remains intact and safe for use in food packaging applications.

Implementation Method 1

a feathering reducing agent comprising a carboxylic acid reactive functional group

Methodology Applied
Scientific EffectChemical reaction: Chemical Bonding

Implementation Method 2

contacting a coating composition with a substrate that comprises a pre-treatment layer

Methodology Applied
Scientific EffectDeposition: Deposition (physical)

Data Source

PatentUS20240132747A1Coated substrate
Publication Date: 2024.04.25 PPG INDUSTRIES OHIO INC
  • US20240132747A1 patent drawing
  • US20240132747A1 patent drawing
  • US20240132747A1 patent drawing

AI summary

A coated substrate comprising a coating extending over at least a part of the substrate. The coating is obtainable from a coating composition comprising (a) a polymeric binder; and (b) a feathering reducing agent comprising a carboxylic acid reactive functional group. The coated portion of the substrate comprises a pretreatment layer. The pretreatment layer is obtainable from a pretreatment composition that comprises a trivalent chromium compound. The invention extends to a method of coating a pre-treated substrate and a coated package, such as a metal can.