Coated Substrate with Negative Slope Walls for Uniform Organic Layers

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Solution Overview

Problem

The manufacturing of organic electronic devices is challenging due to difficulties in coating over low energy surfaces, leading to issues like void formation, poor wetting, and electrical shorting, which affect the performance and efficiency of these devices.

Innovation Solution

The use of containment structures with a substrate having walls with a negative slope and layers with specific surface energies, along with a method involving the deposition of a first layer with a surface energy of 30 mN/m or less and a second layer formed by evaporating a liquid composition, enables improved wetting and uniform coating on low energy surfaces.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If conventional coating methods are used on low energy surfaces, then coating process is simple, but coating uniformity is poor and voids form

Engineering Contradiction:
Improvecoating uniformityVSAvoidcoating process complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The substrate surface is pre-treated with plasma or chemical treatments before coating to modify surface energy and improve wetting characteristics. This preliminary action prepares the low energy surface to accept uniform coating deposition, preventing void formation while maintaining process feasibility

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

An intermediary layer or surface treatment agent is introduced between the low energy substrate and the coating material. This intermediary modifies the surface properties temporarily during coating deposition, enabling uniform coverage without requiring complex equipment changes

Inventive Principle:
Principle #24Intermediary (Mediator)

2Reliability

If coating is applied over low energy surfaces, then manufacturing process is straightforward, but electrical shorting occurs

Engineering Contradiction:
Improveelectrical isolationVSAvoidcoating process simplicity
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The surface energy parameters of the substrate are modified through plasma treatment, chemical etching, or surface coating to transform the low energy surface into a high energy surface. This parameter change ensures proper wetting and prevents coating defects that could lead to electrical shorting, while the treatment processes remain industrially standard

Inventive Principle:
Principle #35Parameter changes

3Manufacturing precision

If standard coating methods are used, then process time is short, but wetting is poor

Engineering Contradiction:
Improvewetting qualityVSAvoidcoating process time
Core Design Contradiction:
Manufacturing precisionVSLoss of time

Solution Approach 1:

Quick plasma treatment or surface activation is performed immediately before coating deposition to temporarily enhance surface energy and wetting properties. This preliminary action creates a time-sensitive window for optimal coating application, ensuring good wetting quality without adding significant process time

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

Physical or chemical surface activation methods replace extended mechanical coating processes. By pre-modifying the surface properties, the actual coating deposition can be performed quickly with standard equipment, achieving both good wetting and efficient processing

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enhances the formation of uniform organic layers, reduces voids, and prevents electrical shorting, thereby improving the performance and efficiency of organic electronic devices by ensuring complete and uniform film formation on low energy surfaces.

Implementation Method 1

a first layer deposited in the space having a first surface energy no greater than 30 mN/m

Methodology Applied
Scientific EffectSurface energy control: Surface Tension

Implementation Method 2

a second layer formed by evaporating a liquid composition

Methodology Applied
Scientific EffectEvaporation: Evaporation

Data Source

PatentUS8067887B2Coated substrate and method of making same
Publication Date: 2011.11.29 LG CHEM LTD
  • US8067887B2 patent drawing
  • US8067887B2 patent drawing
  • US8067887B2 patent drawing

AI summary

Provided are containment structures having a substrate structure having a plurality of walls extending from a surface to define a space, wherein at least one of the walls has an overall negative slope; a first layer deposited in the space having a first surface energy no greater than 30 mN/m; and a second layer deposited on top of the first layer.