Co-Based Alloy Microstructure Control for High-Temperature Strength

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Solution Overview

Problem

Co-based alloy materials produced at an industrial level often form coarse, undesired heterogeneous phases during manufacturing, leading to degraded mechanical properties and increased production costs due to reduced yield.

Innovation Solution

A Co-based alloy material with a specific chemical composition and microstructure is developed, including Al, W, and O, with γ′ and μ phase grains finely dispersed within γ phase crystal grains, using an additive manufacturing method and aging treatment to control microstructure and prevent coarsening of undesired phases.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If Co-based alloy material is produced at industrial level with conventional manufacturing conditions, then production scale is achieved, but coarse grains of undesired heterogeneous phases (p phase) are formed/precipitated leading to degraded mechanical properties

Engineering Contradiction:
Improveproduction scaleVSAvoidmechanical properties
Core Design Contradiction:
ProductivityVSStrength

Solution Approach 1:

The patent applies parameter changes by precisely controlling the oxygen content within 0.007-0.05 mass% and aluminum content within 0.1-10 mass%, along with tungsten content of 3-45 mass%. These compositional parameter changes prevent the formation of coarse unwanted phases while maintaining industrial production scale, thereby preserving mechanical properties

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent implements preliminary action by controlling the chemical composition parameters before the manufacturing process begins. By pre-establishing the oxygen and aluminum content ranges, the alloy prevents phase coarsening during subsequent industrial production, avoiding the need for post-processing excision of defective regions

Inventive Principle:
Principle #10Preliminary action

2Productivity

If Co-based alloy material is produced at industrial level, then production volume increases, but production yield decreases due to need to excise regions with coarse undesired phases

Engineering Contradiction:
Improveproduction volumeVSAvoidproduction yield
Core Design Contradiction:
ProductivityVSLoss of substance

Solution Approach 1:

By changing the compositional parameters (oxygen: 0.007-0.05 mass%, aluminum: 0.1-10 mass%, tungsten: 3-45 mass%), the patent prevents the formation of excisable defective regions, thereby maintaining high production yield during industrial-scale production

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent takes out the problematic element (excess oxygen leading to p-phase formation) by strictly controlling oxygen content within 0.007-0.05 mass%. This extraction of the harmful factor prevents yield loss from excision operations

Inventive Principle:
Principle #2Taking out (Extraction)

3Productivity

If Co-based alloy material is produced at industrial level, then manufacturing cost increases due to reduced production yield

Engineering Contradiction:
Improveindustrial production levelVSAvoidproduction cost
Core Design Contradiction:
ProductivityVSEase of manufacture

Solution Approach 1:

The patent changes the compositional parameters (particularly oxygen content control at 0.007-0.05 mass% and aluminum at 0.1-10 mass%) to prevent phase coarsening, thereby eliminating the need for costly excision operations and reducing overall production cost at industrial scale

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The alloy exhibits mechanical properties comparable to or superior to conventional materials while maintaining high production yield, with improved high-temperature fatigue and tensile strength, and is suitable for high-temperature applications.

Implementation Method 1

γ′ (gamma prime) phase grains within a size of 0.01 μm or more and 0.5 μm or less including Co, Al and W are dispersively precipitated in the segregation cells

Methodology Applied
Scientific EffectPrecipitation: Precipitation

Implementation Method 2

using an additive manufacturing method and aging treatment to control microstructure and prevent coarsening of undesired phases

Methodology Applied
Scientific EffectAging treatment: Heat Treatment

Data Source

PatentUS11884995B2Co-based alloy material, co-based alloy product, and method for manufacturing said product
Publication Date: 2024.01.30 KYOWA PRECISE MFG CO LTD
  • US11884995B2 patent drawing
  • US11884995B2 patent drawing
  • US11884995B2 patent drawing

AI summary

There is provided a Co-based alloy material, having a chemical composition including: Al of 0.1 to 10 mass %; W of 3 to 45 mass %, the total content of Al and W being 50 mass % or less; O of 0.007 to 0.05 mass %; and the balance being Co and impurities, wherein in γ phase crystal grains as a matrix phase of the Co-based alloy material, segregation cells within an average size of 0.15 to 1.5 μm are formed, wherein in the segregation cells, γ′ phase grains within a size of 0.01 to 0.5 μm including Co, Al and W are dispersively precipitated, and wherein on boundary regions of the segregation cells and grain boundaries of the γ phase crystal grains, μ phase grains within a size of 0.005 to 2 μm including Co and W are dispersively precipitated.