Cocoa Product Extraction Process for Antioxidant Preservation

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Solution Overview

Problem

Current cocoa powder production methods fail to efficiently extract and preserve antioxidant compounds like epicatechin, procyanidin C1, and procyanidin B2, resulting in products with inferior solubility and antioxidant properties.

Innovation Solution

A process involving the extraction of roast and ground cocoa nibs with water at specific temperature ranges and draw-off ratios, followed by optional evaporation, which preserves epicatechin and favors the formation of volatile aroma compounds, enhancing the antioxidant capacity and solubility of the cocoa product.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If conventional extraction methods are used to produce cocoa powder, then production efficiency is maintained, but antioxidant compounds like epicatechin and procyanidins are not efficiently extracted and preserved

Engineering Contradiction:
Improveantioxidant compounds (epicatechin, procyanidin C1, procyanidin B2)VSAvoidextraction efficiency
Core Design Contradiction:
Quantity of substanceVSProductivity

Solution Approach 1:

The patent applies parameter changes by optimizing extraction temperature (95-115°C for first extraction, 160-180°C for second extraction), draw-off ratios (2-4), and extraction time (20-40 minutes) to maximize antioxidant compound extraction while maintaining production efficiency. These specific parameter ranges were determined to preserve epicatechin and favor formation of volatile aroma compounds.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The extraction process is divided into two sequential extraction steps with different temperature and draw-off ratio parameters. The first extraction uses water at 95-115°C with draw-off ratio 2-4 for 20-40 minutes, followed by a second extraction at 160-180°C. This segmentation allows optimization of different compound classes at different stages.

Inventive Principle:
Principle #1Segmentation

2Ease of operation

If cocoa powder is produced with conventional methods, then manufacturing process is simple, but solubility in water is poor requiring slurry preparation

Engineering Contradiction:
Improvesolubility in waterVSAvoidprocessing steps
Core Design Contradiction:
Ease of operationVSDevice complexity

Solution Approach 1:

The patent changes physical parameters including extraction temperature ranges and draw-off ratios to produce a cocoa product with improved water solubility. The specific temperature profile (95-115°C followed by 160-180°C) and draw-off ratios (2-4) create a product that dissolves more easily in water without requiring complex slurry preparation procedures.

Inventive Principle:
Principle #35Parameter changes

3Productivity

If high temperature extraction is used to improve extraction efficiency, then productivity increases, but antioxidant compounds may be degraded

Engineering Contradiction:
Improveextraction efficiencyVSAvoidpreservation of antioxidant compounds
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The extraction process is segmented into two temperature stages: a first extraction at moderate temperature (95-115°C) to preserve antioxidant compounds, followed by a second extraction at higher temperature (160-180°C) to maximize extraction efficiency. This segmentation allows both reliability and productivity goals to be achieved.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The first extraction at lower temperature (95-115°C) serves as a preliminary action to preserve antioxidant compounds before the second high-temperature extraction. This preliminary gentle extraction ensures that thermally sensitive compounds are protected while still achieving good extraction efficiency.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The resulting cocoa product exhibits significantly higher levels of epicatechin, procyanidin C1, and procyanidin B2, offering superior antioxidant properties and improved solubility, along with intense cocoa flavor and aroma, making it suitable for beverages and other applications.

Implementation Method 1

extracting first said roast and ground cocoa nibs with water at temperature between 95°C and 115°C

Methodology Applied
Scientific EffectDiffusion: Diffusion

Implementation Method 2

extracting first said roast and ground cocoa nibs with water at temperature between 95°C and 115°C

Methodology Applied
Scientific EffectDissolution: Solvation

Implementation Method 3

extracting the roast and ground cocoa nibs of step b) with water at temperature between 160°C and 180°C where part of the non water soluble polysaccharides are hydrolysed

Methodology Applied
Scientific EffectHydrolysis: Hydrolysis

Implementation Method 4

preserves epicatechin and favors the formation of volatile aroma compounds

Methodology Applied
Scientific EffectThermal protection:

Implementation Method 5

evaporating the extract to obtain a cocoa product

Methodology Applied
Scientific EffectEvaporation: Evaporation

Data Source

PatentEP4240171B1Cocoa product and method for making thereof
Publication Date: 2024.11.13 SOCIETE DES PRODUITS NESTLE SA
  • EP4240171B1 patent drawingFigure 1~1F
  • EP4240171B1 patent drawingFigure 2~2F
  • EP4240171B1 patent drawingFigure 3~3F

AI summary

The present invention relates to a cocoa product containing elevated amounts of antioxidant molecules. Further aspects of the invention relate to the use of this product for making a beverage and into a capsule and to the process of making this product.