COF Crystal Composite for Fast Heat Storage and Dissipation

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Solution Overview

Problem

Existing heat storage/dissipation materials, such as magnesium oxide and sodium acetate trihydrate, have low thermal conductivity, leading to slow heat diffusion, and covalent organic frameworks (COFs) with low thermal conductivity due to fine crystal sizes have not been effectively utilized for heat storage/dissipation.

Innovation Solution

Production of large COF single crystals using a solution containing an ionic liquid and an equilibrium adjusting agent, combined with a heat-storage compound, to create a composite material with enhanced thermal conductivity and heat storage/dissipation characteristics.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional heat storage/dissipation materials (magnesium oxide, sodium acetate trihydrate) are used, then heat storage/dissipation function is achieved, but thermal conductivity is low leading to slow heat diffusion

Engineering Contradiction:
Improveheat storage/dissipation functionVSAvoidheat diffusion speed
Core Design Contradiction:
ReliabilityVSSpeed

Solution Approach 1:

The patent creates a composite material combining COF single crystals with heat storage/dissipation materials. The COF single crystal framework provides high thermal conductivity pathways, while the integrated heat storage/dissipation materials provide the phase change or chemical reaction functionality. This composite structure resolves the contradiction by allowing rapid heat diffusion through the COF framework while maintaining reliable heat storage/dissipation capacity.

Inventive Principle:
Principle #40Composite materials

2Stability of the object's composition

If COF materials with fine crystal sizes are used, then chemical stability and porous structure are achieved, but thermal conductivity remains low

Engineering Contradiction:
Improvechemical stabilityVSAvoidheat diffusion speed
Core Design Contradiction:
Stability of the object's compositionVSSpeed

Solution Approach 1:

The patent fundamentally changes the crystal size parameter of COF materials from conventional fine powders to large single crystals exceeding 120 μm in diameter. This parameter change dramatically improves thermal conductivity while maintaining the chemical stability and porous structure characteristic of COF materials. The large single crystal structure eliminates grain boundaries that impede heat diffusion in fine powder forms.

Inventive Principle:
Principle #35Parameter changes

3Speed

If COF single crystals larger than 120 μm are produced, then thermal conductivity is enhanced, but production complexity increases

Engineering Contradiction:
Improveheat diffusion speedVSAvoidproduction process complexity
Core Design Contradiction:
SpeedVSDevice complexity

Solution Approach 1:

The patent introduces an ionic liquid as an intermediary substance in the crystal growth process. The ionic liquid facilitates the formation and growth of large COF single crystals by providing a suitable reaction environment and mediating the self-assembly of COF building blocks. This intermediary approach enables the production of large crystals without requiring overly complex production processes.

Inventive Principle:
Principle #24Intermediary (Mediator)

4Speed

If COF single crystals exceeding 120 μm are produced, then thermal conductivity is enhanced, but manufacturing difficulty increases

Engineering Contradiction:
Improveheat diffusion speedVSAvoidcrystal production ease
Core Design Contradiction:
SpeedVSEase of manufacture

Solution Approach 1:

The patent employs a self-assembly approach where COF building blocks spontaneously organize into large single crystal structures under controlled conditions. The ionic liquid facilitates this self-assembly process, allowing the system to self-organize into the desired large crystal form without requiring complex external manipulation or processing steps. This self-service mechanism simplifies manufacturing despite the advanced crystal size requirements.

Inventive Principle:
Principle #25Self-service

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composite material achieves high thermal conductivity and rapid heat storage/dissipation capabilities, with COF single crystals exceeding 120 μm in size, allowing efficient heat management.

Implementation Method 1

Production of large COF single crystals using a solution containing an ionic liquid and an equilibrium adjusting agent

Methodology Applied
Scientific EffectCrystallisation: Crystallisation

Implementation Method 2

a heat-storage compound, the heat-storage compound being a compound that generates heat or absorbs heat by adsorption to or desorption from the COF single crystal, or a phase change or a chemical reaction occurring within a range of −20 to 200° C.

Methodology Applied
Scientific EffectPhase change: Phase Change

Implementation Method 3

a heat-storage compound, the heat-storage compound being a compound that generates heat or absorbs heat by adsorption to or desorption from the COF single crystal, or a phase change or a chemical reaction occurring within a range of −20 to 200° C.

Methodology Applied
Scientific EffectChemical reaction: Chemical Bonding

Implementation Method 4

The composite material achieves high thermal conductivity and rapid heat storage/dissipation capabilities

Methodology Applied
Scientific EffectThermal conduction: Conduction (thermal)

Data Source

PatentUS12492331B2Composite material including COF, heat dissipation/storage member, and method for producing said composite material, and COF single crystal and production method therefor
Publication Date: 2025.12.09 THE JAPAN SCI & TECH AGENCY
  • US12492331B2 patent drawing
  • US12492331B2 patent drawing
  • US12492331B2 patent drawing

AI summary

A composite material including a covalent organic framework (COF) single crystal having a major axis length of larger than 120 μm or a COF polycrystal including a plurality of the single crystals, and at least one heat-storage compound. The heat-storage compound is a compound that generates heat or absorbs heat by adsorption to or desorption from the COF single crystal. Also, a heat dissipation/storage member containing the composite material as a heat storage/dissipation material a COF single crystal having a major axis length of larger than 120 μm, and a method for producing a COF single crystal by crystallizing COF raw material compounds via a solution containing an ionic liquid or an organic salt and an equilibrium adjusting agent to grow a COF single crystal.