Cold Box Process Integration for Natural Gas Liquid Recovery

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Solution Overview

Problem

Current natural gas liquid recovery systems face inefficiencies in energy consumption and heat recovery due to the lack of effective process integration, particularly in the heating and cooling processes required for transforming raw hydrocarbons into various petroleum products.

Innovation Solution

The implementation of a natural gas liquid recovery system that includes a cold box with a plate-fin heat exchanger and a refrigeration system using a primary refrigerant mixture of hydrocarbons, with LP and HP separators, and a subcooler, which transfers heat efficiently between hot and cold fluids, optimizing heat exchange across multiple compartments.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Use of energy by moving object

If traditional natural gas liquid recovery systems are used without process integration, then the system structure is simple, but energy consumption is high and heat recovery is inefficient

Engineering Contradiction:
Improveenergy consumptionVSAvoidsystem complexity
Core Design Contradiction:
Use of energy by moving objectVSDevice complexity

Solution Approach 1:

The patent combines multiple heat exchange operations into a single integrated cold box system where hot and cold streams exchange heat through shared walls. This merging of heat exchange functions reduces the number of separate equipment units, minimizes heat loss to the environment, and improves overall energy efficiency while maintaining manageable system complexity through modular design.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The cold box system performs multiple functions simultaneously: it cools process streams, recovers heat from hot streams, condenses natural gas liquids, and pre-cools feed gas. This multi-functionality allows a single integrated structure to replace multiple separate equipment units, reducing energy consumption while providing comprehensive process integration.

Inventive Principle:
Principle #6Universality (Multi-functionality)

2Loss of energy

If process integration with cold box is implemented, then heat recovery is enhanced and energy consumption is reduced, but the heat transfer area requirement decreases which may affect heat exchange efficiency

Engineering Contradiction:
Improveheat recovery efficiencyVSAvoidheat transfer area
Core Design Contradiction:
Loss of energyVSArea of stationary object

Solution Approach 1:

The cold box employs local quality optimization by configuring heat exchange walls with varying thermal conductivities and surface areas at different locations. Hot and cold streams are arranged to maximize temperature differences where most beneficial, and the shared walls are designed with specific thermal properties to optimize heat transfer in each local region, achieving high heat recovery efficiency with reduced total heat transfer area.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The system utilizes parameter changes by varying the temperature, pressure, and flow rates of hot and cold streams to optimize heat transfer conditions. By dynamically adjusting these parameters and arranging streams at different temperature levels within the cold box, the system maximizes the driving force for heat transfer, enabling effective heat recovery with compact heat exchange surfaces.

Inventive Principle:
Principle #35Parameter changes

3Productivity

If multiple refrigerant separators are used for phase separation, then the refrigeration system efficiency is improved, but the device complexity increases

Engineering Contradiction:
Improverefrigeration system efficiencyVSAvoidseparator configuration complexity
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The refrigeration system is segmented into multiple separators operating at different pressure levels (high-pressure and low-pressure separators). This segmentation allows phase separation to occur at optimal conditions for each pressure level, improving refrigeration efficiency by ensuring proper liquid-vapor separation before compression and expansion stages, while the modular separator design keeps the complexity manageable.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The separators act as intermediary devices between different pressure levels and temperature stages in the refrigeration cycle. They mediate the phase transition and pressure adjustment processes, ensuring that refrigerant enters each stage of the cycle in the correct state. This intermediary function improves overall system efficiency by preventing liquid carryover to compressors and ensuring proper expansion conditions.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This configuration reduces energy consumption, enhances heat recovery, and decreases operating costs by allowing for the production of high-purity natural gas liquids and sales gas, while also minimizing the required heat transfer area and equipment costs.

Implementation Method 1

The cold box includes a plate-fin heat exchanger including compartments. The cold box is configured to transfer heat from hot fluids in the natural gas liquid recovery system to cold fluids in the natural gas liquid recovery system.

Methodology Applied
Scientific EffectHeat exchange: Heat Exchanger

Implementation Method 2

The refrigeration system includes a primary refrigerant including a first mixture of hydrocarbons.

Methodology Applied
Scientific EffectPhase change: Phase Change

Implementation Method 3

The LP refrigerant separator is configured to receive a first portion of the primary refrigerant and configured to separate phases of the first portion of the primary refrigerant into a LP primary refrigerant liquid phase and a LP primary refrigerant vapor phase.

Methodology Applied
Scientific EffectPhase separation: Density Gradient

Implementation Method 4

The HP refrigerant separator is configured to receive a second portion of the primary refrigerant and configured to separate phases of the second portion of the primary refrigerant into a HP primary refrigerant liquid phase and a HP primary refrigerant vapor phase.

Methodology Applied
Scientific EffectPhase separation: Density Gradient

Implementation Method 5

The subcooler is configured to transfer heat between the first portion of the primary refrigerant and the LP primary refrigerant vapor phase.

Methodology Applied
Scientific EffectHeat transfer: Heat Exchanger

Data Source

PatentUS11644235B2Process integration for natural gas liquid recovery
Publication Date: 2023.05.09 SAUDI ARABIAN OIL CO
  • US11644235B2 patent drawing
  • US11644235B2 patent drawing
  • US11644235B2 patent drawing

AI summary

This specification relates to operating industrial facilities, for example, crude oil refining facilities or other industrial facilities that include operating plants that process natural gas or recover natural gas liquids.