Cold Pack Cooling Composition With Phosphate Stabilization
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Solution Overview
Problem
Existing cooling agents are often toxic, explosive, and non-recyclable, limiting their commercial success and environmental sustainability, especially with ammonium nitrate and urea-based compositions facing safety concerns and regulatory issues.
Innovation Solution
Combining ammonium phosphate compounds with strongly oxidizing compounds to create non-explosive, recyclable cooling compositions that can be reused as balanced NPK fertilizers, stabilizing mixtures like ammonium nitrate and urea, and incorporating thickening agents for enhanced safety and performance.
Engineering Contradictions & Design Principles
Engineering Contradiction Analysis
1Temperature
If ammonium nitrate and urea are used as cooling agents, then cooling capacity is improved, but safety and stability deteriorate due to explosive and combustion risks
Solution Approach 1:
Phosphate compounds are introduced as intermediary substances that suppress the explosive and combustion properties of ammonium nitrate and urea. The phosphate acts as a stabilizing mediator that allows the cooling agents to maintain their endothermic cooling capacity while reducing safety risks associated with detonation and combustion
Solution Approach 2:
The chemical composition parameters of the cooling mixture are changed by adding phosphate compounds, which modifies the physical and chemical properties of the system. This parameter change reduces the sensitivity to detonation and combustion while preserving the endothermic dissolution process that provides cooling
2Temperature
If traditional cooling agents are used, then cooling effectiveness is improved, but environmental sustainability and recyclability worsen
Solution Approach 1:
The invention enables recovery and reuse of the cooling agent mixture after it has served its cooling purpose. The spent cooling mixture, containing ammonium nitrate, urea, and phosphate compounds, can be recovered and applied as fertilizer, transforming waste material into a valuable agricultural product and eliminating the need for disposal
Solution Approach 2:
The cooling agent mixture serves dual functions: first as a cooling agent through endothermic dissolution, and then as a balanced NPK fertilizer when applied to soil. This multi-functionality allows the same material to provide cooling effectiveness and then environmental benefit through recyclability as fertilizer
3Temperature
If highly oxidizing compounds are used to enhance cooling, then cooling capacity is improved, but combustion and explosion risks worsen
Solution Approach 1:
The harmful oxidizing properties of compounds like ammonium nitrate and urea are converted into a beneficial stabilizing effect when phosphate compounds are added. The phosphate transforms the potentially dangerous high reactivity into a stable, safe mixture that maintains cooling capacity while eliminating combustion and explosion hazards
Applied Scientific Principles
This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.
Function Achieved in This Case
The solution provides safe, effective, and recyclable cooling agents that reduce environmental impact by converting spent cooling agents into reusable fertilizers, maintaining cooling capacity while minimizing safety risks and regulatory concerns.
Implementation Method 1
Combining ammonium phosphate compounds with strongly oxidizing compounds to create non-explosive, recyclable cooling compositions
Implementation Method 2
Compositions producing an endothermic reaction when mixed with water
Data Source
AI summary
Safe, stable, non-toxic and recyclable cooling agent compositions comprising solid particulate compounds undergo an endothermic process when mixed with water such that the resulting mixture is useful for cooling surfaces, liquids and solids. The mixtures include ammonium nitrate in an amount of at least 45 wt % of the mixture. Total nitrogen-containing salts exclusive of phosphates are present in an amount less than 68% by weight of the composition. A phosphate salt is also present in an amount as needed to stabilize the composition against detonation. A balance of additional salts is formulated to provide the mixture with a cooling capacity of at least 240 kJ/kg of the mixture.


