Cold-Rolled Packaging Steel for Strength-Formability Isotropy

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Solution Overview

Problem

There is a need for high-strength cold-rolled flat steel products with isotropic material properties for packaging materials that maintain formability and reduce scrap, while also considering the effects of aging and the complexity of achieving uniform properties across different geometries and forming operations.

Innovation Solution

The solution involves solution hardening using interstitially incorporated alloying components like carbon and nitrogen, with nitrogen nitriding in an annealing furnace to enhance strength, formability, and isotropy, while limiting carbon content to prevent crack formation and optimizing nitrogen content for economic viability and uniform distribution.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Loss of substance

If the thickness of cold-rolled packaging steel is reduced to improve resource efficiency and reduce cost, then material cost decreases, but the stiffness and strength of the material decrease

Engineering Contradiction:
Improvematerial costVSAvoidstiffness and strength
Core Design Contradiction:
Loss of substanceVSStrength

Solution Approach 1:

The patent changes the chemical composition parameters of the steel by precisely controlling carbon content (0.02-0.10 wt%) and nitrogen content (0.012-0.0250 wt%), and by introducing free nitrogen (minimum 0.0100 wt%) to achieve solution hardening and age hardening, thereby increasing strength while maintaining reduced thickness

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite microstructure through controlled alloying elements (C, N, Mn, Si, Al) that form a polyphase structure with enhanced strength properties, combining multiple hardening mechanisms (solution hardening, precipitation hardening, grain boundary hardening) in a single material system

Inventive Principle:
Principle #40Composite materials

2Strength

If strain hardening is increased to improve strength, then strength increases, but anisotropy increases and ductility decreases disproportionately

Engineering Contradiction:
ImprovestrengthVSAvoidanisotropy and ductility
Core Design Contradiction:
StrengthVSStability of the object's composition

Solution Approach 1:

The patent optimizes the strain hardening exponent through precise control of chemical composition (C: 0.02-0.10 wt%, N: 0.012-0.0250 wt%, Mn: 0.17-0.50 wt%, Si: 0.03-0.35 wt%) to achieve uniform deformation characteristics and minimize anisotropy while maintaining high strength

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent promotes homogeneous distribution of alloying elements and free nitrogen throughout the steel matrix to ensure uniform hardening and minimize directional differences in mechanical properties, reducing anisotropy in the cold-rolled product

Inventive Principle:
Principle #33Homogeneity

3Strength

If alloying elements (C, N, P, Mn, Si) are added to increase strength through solution hardening, then strength increases, but surface quality deteriorates and anisotropy increases

Engineering Contradiction:
ImprovestrengthVSAvoidsurface quality and anisotropy
Core Design Contradiction:
StrengthVSObject-affected harmful factors

Solution Approach 1:

The patent precisely controls the content of each alloying element within specific ranges (C: 0.02-0.10 wt%, N: 0.012-0.0250 wt%, Mn: 0.17-0.50 wt%, Si: 0.03-0.35 wt%, P: ≤0.030 wt%) to achieve optimal strength while minimizing harmful effects on surface quality and anisotropy

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent introduces free nitrogen (minimum 0.0100 wt%) that distributes uniformly throughout the material to provide localized hardening without the surface quality deterioration associated with traditional alloying, creating different quality characteristics in the bulk material versus the surface

Inventive Principle:
Principle #3Local quality

4Strength

If carbon content is increased to improve strength, then strength increases, but anisotropy in the form of banding develops and surface quality deteriorates

Engineering Contradiction:
ImprovestrengthVSAvoidanisotropy and surface quality
Core Design Contradiction:
StrengthVSStability of the object's composition

Solution Approach 1:

The patent optimizes carbon content within a specific range (0.02-0.10 wt%) to achieve sufficient strength through solution hardening while preventing excessive carbide formation that would cause banding and anisotropy, balancing strength gains with microstructural stability

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent combines controlled carbon content with nitrogen and other alloying elements to create a composite hardening system where carbon provides baseline strength and nitrogen provides additional hardening through free nitrogen, reducing reliance on high carbon content that would cause banding

Inventive Principle:
Principle #40Composite materials

5Strength

If high-strength sheet steels with yield strength higher than 550 MPa are produced, then strength increases, but formability characteristics deteriorate

Engineering Contradiction:
Improveyield strengthVSAvoidformability
Core Design Contradiction:
StrengthVSEase of operation

Solution Approach 1:

The patent optimizes the chemical composition parameters (C, N, Mn, Si, Al contents) to achieve a specific strength-formability balance, targeting yield strength >550 MPa while maintaining elongation ≥5% and Erichsen index ≥5 mm through controlled solution hardening and free nitrogen

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent ensures homogeneous distribution of free nitrogen and alloying elements throughout the steel matrix to create uniform mechanical properties that maintain formability across the entire material, preventing localized weak points that would compromise overall formability during deep drawing and ironing

Inventive Principle:
Principle #33Homogeneity

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The approach results in a flat steel product with high yield strength, sufficient elongation, and homogeneous mechanical properties, enabling the production of packaging materials with excellent isotropic properties and reduced scrap, even after aging, by ensuring uniform nitrogen distribution and minimizing anisotropy.

Implementation Method 1

solution hardening using interstitially incorporated alloying components like carbon and nitrogen

Methodology Applied
Scientific EffectInterstitial incorporation: Absorption (physical)

Implementation Method 2

nitrogen nitriding in an annealing furnace to enhance strength, formability, and isotropy

Methodology Applied
Scientific EffectNitriding: Nitriding

Implementation Method 3

solution hardening (by adding carbon, nitrogen, phosphorus, manganese and/or silicon as alloying elements)

Methodology Applied
Scientific EffectSolution hardening: Solid Solution Strengthening

Implementation Method 4

nitrogen nitriding in an annealing furnace

Methodology Applied
Scientific EffectAnnealing: Annealing

Data Source

PatentUS11560608B2Cold-rolled flat steel product for packaging materials
Publication Date: 2023.01.24 THYSSENKRUPP RASSELSTEIN
  • US11560608B2 patent drawing
  • US11560608B2 patent drawing
  • US11560608B2 patent drawing

AI summary

A cold-rolled flat steel product for packaging materials has a thickness of less than 0.6 mm, which has been cold-rolled from steel along a rolling direction (0°) and which has an excellent isotropy with respect to its mechanical properties.