Cold Spray Aluminum on Ceramic Substrates

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Solution Overview

Problem

Current methods for producing ceramic circuit boards with aluminum or aluminum alloys as circuit materials are costly and inefficient, particularly the molten metal method and brazing method, which require complex facilities and high-temperature pressurization, and struggle with adhesion to ceramic substrates.

Innovation Solution

A method involving the cold spray technique, where aluminum or aluminum alloy powder is accelerated to 250-1050 m/s and heated to 10-270°C, then deposited onto a ceramic substrate in an inert gas atmosphere, followed by heat treatment at 400-600°C to form a metal layer with high adhesion.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Temperature

If copper is used as circuit material on highly thermal conductive ceramic substrate, then thermal conductivity is improved, but crack resistance under thermal cycles deteriorates

Engineering Contradiction:
Improvethermal conductivityVSAvoidcrack resistance
Core Design Contradiction:
TemperatureVSReliability

Solution Approach 1:

The invention changes the material parameter from copper to aluminum or aluminum alloy, which has different physical properties including lower yield strength but better thermal cycle resistance. This parameter change resolves the contradiction by selecting a material that maintains adequate thermal conductivity while significantly improving crack resistance under thermal cycling conditions.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention uses aluminum alloy instead of pure copper, creating a composite material solution that balances thermal conductivity and mechanical durability. The alloying elements in the aluminum alloy provide enhanced properties that resolve the contradiction between thermal performance and thermal cycle resistance.

Inventive Principle:
Principle #40Composite materials

2Strength

If molten metal method is used to form aluminum circuit, then adhesion to ceramic substrate is improved, but facility complexity and cost increase

Engineering Contradiction:
ImproveadhesionVSAvoidfacility complexity
Core Design Contradiction:
StrengthVSDevice complexity

Solution Approach 1:

The invention replaces the complex molten metal deposition system with a simpler cold spray technique. Instead of using molten aluminum requiring sophisticated heating and control facilities, the invention uses accelerated aluminum particles in solid or semi-solid state, substituting a complex thermal-mechanical system with a simpler kinetic spray system that achieves comparable adhesion.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The invention changes the temperature parameter from high (molten state) to low (cold spray state), forming aluminum circuit at room temperature or slightly elevated temperatures. This parameter change eliminates the need for complex high-temperature facilities while maintaining adhesion through kinetic energy of accelerated particles.

Inventive Principle:
Principle #35Parameter changes

3Strength

If brazing method is used to form aluminum circuit, then adhesion to ceramic substrate is improved, but productivity deteriorates due to high temperature pressurization

Engineering Contradiction:
ImproveadhesionVSAvoidproduction efficiency
Core Design Contradiction:
StrengthVSProductivity

Solution Approach 1:

The invention replaces the brazing process requiring high-temperature furnaces and pressurization equipment with a cold spray technique. This substitution eliminates time-consuming heating and pressurization cycles, enabling faster production while achieving equivalent or superior adhesion through particle kinetic energy and subsequent heat treatment.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The invention skips the lengthy high-temperature brazing process by using cold spray deposition followed by brief heat treatment. This rushing through the essential bonding step without unnecessary prolonged heating and pressurization significantly improves productivity while maintaining adhesion quality.

Inventive Principle:
Principle #21Skipping (Rushing through)

4Strength

If aluminum powder is sprayed at high velocity and heated, then adhesion to ceramic substrate is improved, but energy consumption increases

Engineering Contradiction:
ImproveadhesionVSAvoidenergy consumption
Core Design Contradiction:
StrengthVSUse of energy by moving object

Solution Approach 1:

The invention uses partial heating of aluminum powder to a moderate temperature range (10-270°C) rather than complete melting. This partial thermal action, combined with high-velocity kinetic energy, achieves sufficient adhesion while consuming less energy than full molten metal processes or prolonged high-temperature brazing.

Inventive Principle:
Principle #16Partial or excessive action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method efficiently produces ceramic circuit boards with high adhesion using a simple facility, eliminating the need for molten aluminum and brazing, and allows for pattern formation without etching, while maintaining thermal and electrical properties.

Implementation Method 1

accelerating metal powder to a velocity of from 250 to 1050 m/s

Methodology Applied
Scientific EffectKinetic energy:

Implementation Method 2

heating the metal powder to from 10°C to 270°C

Methodology Applied
Scientific EffectThermal energy: Heating

Implementation Method 3

subjecting the ceramic substrate and the metal layer formed on the ceramic substrate to a heat treatment in an inert gas atmosphere. The ceramic substrate and the metal layer are heated to from 400°C to 600°C

Methodology Applied
Scientific EffectThermal diffusion: Diffusion

Data Source

PatentEP3572555B1Method for manufacturing ceramic circuit board
Publication Date: 2021.03.03 DENKA CO LTD
  • EP3572555B1 patent drawingFigure 1
  • EP3572555B1 patent drawingFigure 2
  • EP3572555B1 patent drawingFigure 3

AI summary

Disclosed is a method for producing a ceramic circuit board including a ceramic substrate and a metal layer formed on the ceramic substrate. This method includes a step of forming the metal layer on the ceramic substrate by spraying a metal powder after accelerating the metal powder to a velocity of from 250 to 1050 m/s as well as heating the metal powder to from 10°C to 270°C and a step of subjecting the ceramic substrate and the metal layer to a heat treatment in an inert gas atmosphere.