Cold Spray Bond Coating for Cast Iron Adhesion

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Solution Overview

Problem

Cold-spraying coatings onto certain substrates, such as cast iron, often results in poor adhesion due to the difficulty in achieving mechanical interlocking between the coating and the substrate, particularly when using softer materials like non-metallic, intermetallic, or ceramic phases.

Innovation Solution

A method involving the cold-spraying of a harder bond material onto the substrate to form a bond coating, followed by the application of a coating material to create a top coating, enhancing adhesion through mechanical interlocking and potentially improving the hardness difference between the bond and coating materials.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If a softer coating material is cold-sprayed directly onto a substrate, then the coating process is simple, but the adhesion between the coating and substrate is poor

Engineering Contradiction:
Improvecoating process simplicityVSAvoidcoating adhesion
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

A bond coating is introduced as an intermediary layer between the substrate and the top coating. This bond coating serves as a mediator that facilitates mechanical interlocking with the substrate while providing a suitable surface for the top coating material to adhere to, thereby resolving the adhesion problem without complicating the overall coating process

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The coating system is segmented into two distinct functional layers: a bond coating layer that interfaces with the substrate and provides mechanical interlocking, and a top coating layer that provides the desired protective or functional properties. This segmentation allows each layer to be optimized for its specific function

Inventive Principle:
Principle #1Segmentation

2Reliability

If a harder bond material is used to create mechanical interlocking with the substrate, then the adhesion improves, but the material selection becomes more restricted

Engineering Contradiction:
Improvecoating adhesionVSAvoidmaterial selection flexibility
Core Design Contradiction:
ReliabilityVSAdaptability or versatility

Solution Approach 1:

The hardness parameter of the bond coating material is specifically increased relative to the substrate to enable mechanical interlocking during cold spraying. This parameter change is localized to the bond coating layer, while the top coating material can still be selected independently based on functional requirements, maintaining overall system versatility

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach significantly improves the adhesion of the top coating to the substrate, as demonstrated by increased interfacial bond strength and mechanical stability, especially when the bond material is harder than the substrate, and further enhanced by heat treatment.

Implementation Method 1

the surface of the substrate is deformed plastically during cold-spraying the bond material, leading to mechanical interlocking of the substrate and the bond material

Methodology Applied
Scientific EffectPlastic deformation: Plasticity

Implementation Method 2

leading to mechanical interlocking of the substrate and the bond material

Methodology Applied
Scientific EffectMechanical interlocking: Mechanical Fastener

Implementation Method 3

the top-coat adheres more strongly when cold-sprayed onto the bond coat

Methodology Applied
Scientific EffectPlastic deformation: Plasticity

Implementation Method 4

The powdered material is accelerated towards the substrate in a supersonic gas jet under such conditions that the powdered material does not melt during the spraying process

Methodology Applied
Scientific EffectSupersonic acceleration: Jet

Data Source

PatentUS11555248B2Cold spraying
Publication Date: 2023.01.17 ROLLS ROYCE PLC
  • US11555248B2 patent drawing
  • US11555248B2 patent drawing
  • US11555248B2 patent drawing

AI summary

A method comprising: cold-spraying a surface of a substrate with a bond material to form a bond coating; and cold-spraying a surface of the bond coating with a coating material to form a top coating. The bond material is different from the coating material and harder than the surface of the substrate.