Cold-Sprayed Nickel Coating for Oxide-Free Braze Joints

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Solution Overview

Problem

Existing brazing methods for metal components, such as those in gas turbine engines, face challenges due to the formation of oxide films on metal surfaces during heating, which hinder the formation of effective braze joints, and current coating methods like chemical baths generate waste, require extensive cleaning, and struggle with uniformity and thickness control.

Innovation Solution

A cold-spray method is used to deposit a nickel-based alloy coating on the braze region of metal components, eliminating the need for special cleaning and heat treatments, allowing for uniform and thicker coatings, and preventing oxide formation during brazing.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If chemical bath coating methods are used to coat metal components before brazing, then oxide film formation can be prevented, but the process generates waste, requires extensive cleaning, and struggles with uniformity and thickness control

Engineering Contradiction:
Improveoxide film preventionVSAvoidwaste generation
Core Design Contradiction:
ReliabilityVSLoss of substance

Solution Approach 1:

The patent transitions from chemical bath coating to cold spray coating, fundamentally changing the coating process parameters from wet chemical deposition to cold gas dynamic spraying. This parameter change eliminates the need for chemical baths, solvents, and associated cleaning processes, thereby preventing waste generation while maintaining oxide film prevention capabilities through the formation of a protective nickel-based alloy coating

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention replaces the chemical-based coating system (chemical bath) with a mechanical/physical coating system (cold spray). The cold spray process uses high-velocity particle impact to deposit coating material, substituting chemical reactions with mechanical deposition, thereby eliminating waste streams and cleaning requirements while achieving uniform, controllable coating thickness

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Reliability

If chemical bath coating methods are used, then oxide film formation can be prevented, but extensive cleaning and heat treatments are required

Engineering Contradiction:
Improveoxide film preventionVSAvoidprocess complexity
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The cold spray coating process replaces the multi-step chemical bath process (coating, cleaning, heat treatment) with a single mechanical deposition step. The high-velocity particle impact creates a metallurgically bonded coating that requires no subsequent cleaning or heat treatment, dramatically simplifying the manufacturing process while maintaining oxide protection

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The invention extracts and eliminates the unnecessary process steps (cleaning and heat treatment) from the coating workflow. By using cold spray coating, the process directly produces a clean, adherent coating that is ready for brazing without additional processing steps, thereby reducing overall process complexity

Inventive Principle:
Principle #2Taking out (Extraction)

3Quantity of substance

If conventional coating methods are used, then coating can be applied, but uniformity and thickness control are difficult to achieve

Engineering Contradiction:
Improvecoating thicknessVSAvoidcoating uniformity
Core Design Contradiction:
Quantity of substanceVSManufacturing precision

Solution Approach 1:

The cold spray process uses dynamic, high-velocity particle delivery where coating material is sprayed as individual particles accelerated to supersonic speeds. This dynamic delivery mechanism allows precise control over coating thickness and uniformity by adjusting spray parameters, unlike static chemical bath methods where uniformity is difficult to control

Inventive Principle:
Principle #15Dynamics

Solution Approach 2:

The invention changes the coating deposition parameters from chemical diffusion-controlled (bath coating) to kinetic-energy-controlled (cold spray). This parameter change enables precise control over coating thickness and uniformity through adjustable spray velocity, distance, and particle size, achieving manufacturing precision unattainable with conventional methods

Inventive Principle:
Principle #35Parameter changes

4Strength

If metal components are heated for brazing, then bonding between components can be achieved, but oxide films form on metal surfaces that hinder effective braze joint formation

Engineering Contradiction:
Improvebonding strengthVSAvoidoxide film formation
Core Design Contradiction:
StrengthVSObject-generated harmful factors

Solution Approach 1:

The cold spray coating is applied in advance of the brazing operation, creating a protective nickel-based alloy layer on the metal surface before heating occurs. This preliminary protective action prevents oxide film formation during the subsequent brazing heat cycle, ensuring clean metal surfaces for effective bonding

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The cold spray coating acts as an intermediary protective layer between the metal component and the oxidizing atmosphere during brazing. This intermediate coating prevents direct oxidation of the base metal while allowing the brazing process to proceed, thereby maintaining bonding strength without oxide interference

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The cold-spray method reduces waste, achieves uniform and thicker coatings, and ensures effective braze joints by preventing oxide formation, enhancing the bonding process and mechanical properties of the coated components.

Implementation Method 1

operating a cold-spray apparatus to deposit a feedstock comprising nickel-based alloy particles on a braze region of a first metallic component to form a nickel-containing coating on the braze region

Methodology Applied
Scientific EffectCold spray deposition: Deposition (physical)

Data Source

PatentEP4074456A1Methods of coating components with cold spray and brazing coated components
Publication Date: 2022.10.19 GENERAL ELECTRIC CO
  • EP4074456A1 patent drawingFigure 1~2
  • EP4074456A1 patent drawingFigure 3
  • EP4074456A1 patent drawingFigure 4

AI summary

A method for joining two or more metallic components. The method includes operating a cold-spray apparatus to deposit a feedstock comprising nickel-based alloy particles on a braze region of a first metallic component to form a nickel-containing coating on the braze region. The method also includes brazing the first metallic component and a second metallic component by exposing the braze region to a braze material to form a braze joint that bonds the first metallic component to the second metallic component.