Cold Spray Tantalum Cladding Steel Joints

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Solution Overview

Problem

Existing methods for joining tantalum clad steel sections are costly and inefficient, often requiring high-temperature processes that lead to the dissolution of steel into tantalum, resulting in brittle and non-corrosion-resistant phases, and are challenging when forming complex structures like vessels or piping.

Innovation Solution

The process involves cold spraying tantalum powder onto welded steel edge regions to form a dense, corrosion-resistant joint without heating the tantalum, eliminating the need for battens and high-temperature processes, and allowing for the use of thinner tantalum cladding.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If high-temperature welding processes are used to join tantalum clad steel sections, then the steel sections can be fused together, but the steel dissolves into the tantalum forming brittle and non-corrosion-resistant phases

Engineering Contradiction:
Improvejoint strengthVSAvoidcorrosion resistance
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The invention changes the temperature parameter from high-temperature welding to low-temperature cold spray deposition. The tantalum is deposited at temperatures below the melting point of steel, preventing steel dissolution and brittle phase formation while still achieving strong metallurgical bonding between the tantalum layers and substrate

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention replaces the thermal field (welding heat) with a kinetic field (cold spray particle acceleration). High-velocity particles are accelerated and impact the substrate, creating mechanical interlocking and metallurgical bonding without thermal input that would cause steel dissolution

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Quantity of substance

If traditional thermal spray processes are used to deposit tantalum, then tantalum coating can be formed, but the substrate and surrounding areas are heated to high temperatures causing oxidation and thermally induced stresses

Engineering Contradiction:
Improvetantalum coating depositionVSAvoidoxidation and thermal stress
Core Design Contradiction:
Quantity of substanceVSObject-affected harmful factors

Solution Approach 1:

The invention changes the temperature parameter from high-temperature thermal spray to low-temperature cold spray. Particles are accelerated to high velocities through gas expansion without being heated to melting or vaporization temperatures, eliminating oxidation and thermal stress problems while still achieving dense coating deposition

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention replaces thermal energy with kinetic energy for particle acceleration. Compressed gas expands through a de Laval nozzle to accelerate tantalum particles to supersonic velocities, depositing them on the substrate through mechanical impact rather than thermal melting

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

3Strength

If high-temperature brazing or diffusion bonding is used to attach tantalum cladding, then the tantalum can be bonded to steel substrate, but elaborate joint designs and fabrication techniques are required to prevent tantalum reaction with steel

Engineering Contradiction:
Improvebond strengthVSAvoidjoint design complexity
Core Design Contradiction:
StrengthVSDevice complexity

Solution Approach 1:

The invention changes the bonding temperature from high-temperature brazing/diffusion bonding to low-temperature cold spray deposition. This eliminates the need for elaborate joint designs and protective measures, as the low-temperature process inherently prevents steel dissolution and brittle phase formation, allowing simpler joint geometries

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention uses a consumable layer of tantalum powder that is deposited and then removed or integrated into the final structure. This temporary material serves as both the bonding medium and the final protective coating, eliminating the need for separate joint design elements

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method creates a high-density, low-cost, corrosion-resistant joint with no porosity or thermal stresses, enabling the use of thinner tantalum cladding and reducing fabrication costs while maintaining structural integrity and corrosion resistance.

Implementation Method 1

Cold spray or kinetic spray is an emerging industrial technology that is being employed to solve many industrial manufacturing challenges

Methodology Applied
Scientific EffectKinetic spray:

Implementation Method 2

Cold spray employs a high velocity gas jet to rapidly accelerate powder particles to high velocity such that when they impact a surface the particles bond to the surface

Methodology Applied
Scientific EffectHigh velocity gas jet acceleration:

Implementation Method 3

The fact that dense coatings can be formed at low temperatures present many advantages. Such advantages include reduced oxidation, high density deposits, solid state compaction

Methodology Applied
Scientific EffectSolid state compaction:

Data Source

PatentUS9095932B2Methods of joining metallic protective layers
Publication Date: 2015.08.04 MATERION NEWTON INC
  • US9095932B2 patent drawing
  • US9095932B2 patent drawing
  • US9095932B2 patent drawing

AI summary

In various embodiments, protective layers are bonded to a steel layer, overlapped, and at least partially covered by a layer of unmelted metal powder produced by cold spray.