Colored Coating Layer for Sanitary Equipment

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Solution Overview

Problem

Existing sanitary equipment parts with colored layers, particularly black-colored layers, face issues with color stability, strength, and interference colors due to thin layers, making it difficult to maintain a consistent black appearance.

Innovation Solution

A part comprising a base material with a colored layer containing 35 at % to 99 at % carbon, 0 at % to less than 40 at % chromium, 0 at % to less than 15 at % nitrogen, and 0 at % to less than 15 at % oxygen, an intermediate layer with a metal atom selected from Cr, Zr, and Si, and an oxidized state detected by XPS, and a surface layer that is water-repellent and includes a hydrophobic group.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Illumination intensity

If a colored layer mainly containing C is provided on a base material to achieve black color, then the appearance is improved, but the color stability and strength of the colored layer deteriorate

Engineering Contradiction:
Improveblack color appearanceVSAvoidcolor stability
Core Design Contradiction:
Illumination intensityVSReliability

Solution Approach 1:

The patent applies composite materials by creating a multi-layer structure consisting of a base material, a colored layer containing C, Cr, N, and O in specific proportions, and a water-repellent layer. This composite structure combines the aesthetic benefits of the colored layer with the protective properties of the water-repellent layer, resolving the contradiction between appearance and color stability.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent changes the compositional parameters of the colored layer by specifying precise atomic percentage ranges: C (35-99 at%), Cr (0-40 at%), N (0-15 at%), and O (0-15 at%). This parameter optimization ensures both the black color appearance and color stability, preventing the deterioration that occurs with conventional carbon-based colored layers.

Inventive Principle:
Principle #35Parameter changes

2Quantity of substance

If the colored layer is made thin to reduce material usage, then the manufacturing cost is reduced, but interference colors are generated and the intended black color cannot be achieved

Engineering Contradiction:
Improvecolored layer thicknessVSAvoidblack color uniformity
Core Design Contradiction:
Quantity of substanceVSIllumination intensity

Solution Approach 1:

The patent optimizes the thickness and composition parameters of the colored layer to eliminate interference colors. By controlling the atomic percentages of C, Cr, N, and O within specific ranges and adjusting the layer thickness, the patent achieves uniform black color appearance without the rainbow-like interference effects that occur in thin carbon-based layers.

Inventive Principle:
Principle #35Parameter changes

3Ease of operation

If a water-repellent layer is provided on the colored layer to prevent stain adhesion, then the ease of cleaning is improved, but the adhesion of the water-repellent layer deteriorates

Engineering Contradiction:
Improvestain removabilityVSAvoidlayer adhesion
Core Design Contradiction:
Ease of operationVSStrength

Solution Approach 1:

The patent introduces an intermediate functional layer between the colored layer and the water-repellent layer. This intermediate layer acts as a mediator that provides both adhesion promotion (bonding to the colored layer) and water repellency (bonding to the water-repellent layer), thereby resolving the contradiction between stain removability and layer adhesion.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent creates a composite multi-layer structure where each layer has specific functions: the colored layer provides appearance, the intermediate layer provides adhesion and water repellency, and the outer water-repellent layer provides stain resistance. This composite structure achieves both easy cleaning and strong adhesion simultaneously.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution achieves improved color stability, strength, and durability of the colored layer while maintaining a consistent black appearance, and imparts water-repellency to the part without affecting the color development.

Implementation Method 1

a colored layer which contains: more than 35 at % to 99 at % or less of C, 0 at % or more to less than 40 at % of Cr, 0 at % or more to less than 15 at % of N, and more than 0 at % to less than 15 at % of O

Methodology Applied
Scientific EffectLight absorption: Absorption (EM radiation)

Implementation Method 2

the intermediate layer contains at least one metal atom selected from Cr, Zr, and Si; and an oxygen atom, the metal element in an oxidized state is detected with XPS in the intermediate layer

Methodology Applied
Scientific EffectChemical bonding: Chemical Bonding

Implementation Method 3

the surface layer is water-repellent, and includes a hydrophobic group

Methodology Applied
Scientific EffectHydrophobic effect: Hydrophobe

Data Source

PatentUS12221690B2Sanitary equipment part
Publication Date: 2025.02.11 TOTO LTD
  • US12221690B2 patent drawing

AI summary

A part includes a base material, a colored layer, an intermediate layer, and a water-repellent-surface layer. The colored layer contains 35 at % to 99 at % of C, 0 at % to less than 40 at % of Cr, 0 at % to less than 15 at % of N, and more than 0 at % to less than 15 at % of O. The intermediate layer contains at least one metal atom selected from Cr, Zr, and Si; and an oxygen atom. The intermediate layer exhibits a sputtering time of 0.5 minutes or more to 9 minutes or less.