Colored Nylon via Condensation Dye Chromogenic Groups

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Solution Overview

Problem

Existing nylon dyeing methods suffer from poor dyeing stability, uneven dyeing, and high pollution due to incomplete dye reactions and low water resistance, particularly in organic solvents.

Innovation Solution

A colored nylon is produced by incorporating dye chromogenic groups into the nylon structure through a condensation reaction, ensuring uniform distribution and strong bonding, thereby enhancing dyeing uniformity and stability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Adaptability or versatility

If physical dyeing methods (dip dyeing or dope dyeing) are used to color nylon, then the nylon can be dyed into different colors, but the dyeing uniformity is poor and color stability is poor especially in organic solvents

Engineering Contradiction:
Improvecolor varietyVSAvoiddyeing stability
Core Design Contradiction:
Adaptability or versatilityVSReliability

Solution Approach 1:

The patent introduces dyeing auxiliary groups (such as carboxyl groups, hydroxyl groups, or amine groups) into the nylon molecular chain before the actual dyeing process. These auxiliary groups are pre-installed at specific positions along the polymer chain to facilitate subsequent dye binding, ensuring uniform and stable coloration that resists fading in organic solvents.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent uses dyeing auxiliary groups as intermediary structures that mediate between the nylon base polymer and the dye molecules. These auxiliary groups act as binding sites that form strong interactions (hydrogen bonds, ionic bonds, or coordination bonds) with dye molecules, enabling stable color fixation without relying on weak physical forces alone.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Reliability

If copolymerization process is used to directly add dye into nylon system, then chemical bonding can be achieved, but the reaction is incomplete and water resistance is poor

Engineering Contradiction:
Improvechemical bondingVSAvoiddyeing uniformity
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The patent segments the dyeing process into two distinct stages: first, introducing dyeing auxiliary groups into the nylon molecular chain through controlled polymerization; second, adding dye molecules that bind to these auxiliary groups. This segmentation allows each stage to be optimized independently, ensuring complete reaction and uniform distribution without the drawbacks of attempting to incorporate dye directly during polymerization.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent applies local quality by introducing dyeing auxiliary groups at specific locations within the nylon molecular chain rather than uniformly throughout. This localized modification creates specific binding sites that enhance dye attachment while maintaining the overall properties of the nylon polymer, resulting in both complete reaction and uniform water-resistant coloration.

Inventive Principle:
Principle #3Local quality

3Ease of manufacture

If traditional dip dyeing high temperature process is used, then dyeing can be achieved, but energy consumption is high and pollution is serious

Engineering Contradiction:
Improvedyeing effectivenessVSAvoidenergy consumption
Core Design Contradiction:
Ease of manufactureVSLoss of energy

Solution Approach 1:

The patent replaces the traditional high-temperature mechanical heating process with a chemical mechanism-based dyeing approach. By introducing functional groups that enable low-temperature chemical bonding between dye and nylon, the process eliminates the need for high-temperature steam or hot water treatment, dramatically reducing energy consumption while maintaining effective dyeing.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent changes the fundamental parameters of the dyeing process by introducing chemical functional groups that enable dye binding at much lower temperatures than traditional methods. This parameter change from high-temperature physical processes to low-temperature chemical processes reduces energy consumption and minimizes pollution while achieving equivalent or superior dyeing effectiveness.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The colored nylon exhibits excellent dyeing stability, high color fastness, and resistance to organic solvents without discoloration, reducing environmental impact and energy consumption.

Implementation Method 1

contacting a condensate containing the dye chromogenic groups with a nylon monomer to carry out the condensation reaction

Methodology Applied
Scientific EffectCondensation reaction:

Implementation Method 2

incorporating dye chromogenic groups into the nylon structure through a condensation reaction, ensuring uniform distribution and strong bonding

Methodology Applied
Scientific EffectChemical bonding: Chemical Bonding

Data Source

PatentEP4644463A9Colored nylon and preparation method therefor and application thereof
Publication Date: 2025.12.17 CHINA PETROLEUM & CHEMICAL CORP
  • EP4644463A9 patent drawingFigure 1~3b
  • EP4644463A9 patent drawingFigure 4a~6
  • EP4644463A9 patent drawingFigure 7~10

AI summary

The present invention relates to a colored nylon preparation technology, and disclosed are colored nylon and a preparation method therefor and an application thereof. The colored nylon comprises nylon structure units and chromogenic structure units. The chromogenic structure units comprise dye chromogenic groups. The chromaticity of a supernatant obtained by steaming a mixture of the colored nylon and an organic solvent in a weight ratio of 1:3 does not exceed 10, and the difference in color depth of the colored nylon does not exceed 0.2. The preparation method for the colored nylon comprises: enabling a condensate containing the dye chromogenic groups to be in contact with a nylon monomer for a condensation reaction, so that at least some of the dye chromogenic groups are located between and/or at the ends of the structure units formed from the nylon unit. The colored nylon provided by the present invention has excellent water resistance and organic solvent resistance, high dyeing uniformity and good dyeing stability, low energy consumption and little pollution in the preparation process, and good economic and social benefits.