Colored Tire Sidewall Composition Without Barrier Layers

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Solution Overview

Problem

Existing vehicle tire decorative elements face issues such as discoloration, poor adhesion, scratching, and increased manufacturing complexity due to the migration of staining agents and the use of barrier layers, which affect the durability and productivity of tire production.

Innovation Solution

A tire design featuring a colored decorative element with a thickness of at least 200 μm, made from a cross-linkable elastomeric composition comprising diene elastomeric polymer, reinforcement filler, and an ozone protection system, applied directly to the tire sidewall and co-vulcanised with the tire during the manufacturing process.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a barrier layer comprising halogenated rubbers is used to prevent discoloration, then discoloration resistance is improved, but adhesion between the colored composition and the tyre surface deteriorates

Engineering Contradiction:
Improvediscoloration resistanceVSAvoidadhesion
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The patent removes the barrier layer (halogenated rubber layer) that was previously used to prevent discoloration. Instead, it uses a specially formulated elastomeric composition containing non-staining antioxidants and anti-ozonants that directly prevent discoloration without requiring a separate barrier layer, thus eliminating the adhesion problem while maintaining discoloration resistance

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent changes the chemical composition parameters of the elastomeric material by incorporating specific non-staining antioxidants (such as hindered phenols) and anti-ozonants (such as ethylene bis stearamide) that provide discoloration protection without the staining effects of traditional aromatic amine-based additives, allowing direct application to the tyre surface without barrier layers

Inventive Principle:
Principle #35Parameter changes

2Adaptability or versatility

If adhesive labels are applied to the sidewall after vulcanisation, then decorative elements can be added, but manufacturing complexity increases due to additional cleaning and gluing stations

Engineering Contradiction:
Improvedecorative element applicationVSAvoidmanufacturing process complexity
Core Design Contradiction:
Adaptability or versatilityVSDevice complexity

Solution Approach 1:

The patent merges the decorative element application with the tyre vulcanisation process by incorporating the elastomeric composition with colored pigments directly into the tyre building process. The decorative elements are formed simultaneously with the tyre structure during vulcanisation, eliminating the need for separate cleaning and gluing stations required by post-vulcanisation label application methods

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The patent performs preliminary action by applying and vulcanising the elastomeric composition containing decorative elements during the tyre building process before the tyre is completed. This allows the decorative elements to be integrated into the tyre structure in advance, avoiding the need for subsequent complex application processes

Inventive Principle:
Principle #10Preliminary action

3Loss of substance

If the decorative element layer is made thin to reduce material usage, then material consumption decreases, but resistance to scratching and abrasion deteriorates

Engineering Contradiction:
Improvematerial consumptionVSAvoidabrasion resistance
Core Design Contradiction:
Loss of substanceVSReliability

Solution Approach 1:

The patent uses composite materials by formulating an elastomeric composition that combines colored pigments with reinforcing fillers (such as carbon black, silica, or calcium carbonate) and protective additives. This composite structure provides both color and enhanced mechanical properties including abrasion and scratch resistance, allowing the use of sufficiently thick layers for durability while optimizing material consumption through efficient filler utilization

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution provides excellent adhesion, resistance to abrasion and impact, prevents discoloration, and simplifies the manufacturing process by integrating the decorative element directly into the tire production, enhancing durability and reducing production costs.

Implementation Method 1

co-vulcanising said layer together with said green tyre

Methodology Applied
Scientific EffectVulcanisation: Chemical Bonding

Implementation Method 2

an ozone protection system

Methodology Applied
Scientific EffectOzone protection: Ozone

Data Source

PatentUS12448499B2Tyre for vehicle wheels
Publication Date: 2025.10.21 PIRELLI TYRE SPA
  • US12448499B2 patent drawing
  • US12448499B2 patent drawing
  • US12448499B2 patent drawing

AI summary

The present disclosure relates to a tyre comprising a carcass structure, a tread band, a pair of sidewalls and at least one colored decorative element having a thickness equal to or greater than 200 μm applied by co-vulcanization on at least one side of the pair of sidewalls, wherein the pair of sidewalls comprises an elastomeric composition comprising (i) at least one diene elastomeric polymer, and (ii) an ozone protection system, and the at least one colored decorative element is made with a cross-linkable elastomeric composition comprising (i) 100 phr of elastomeric polymer comprising 30 phr to 70 phr of natural and/or synthetic isoprene rubber, and 30 phr to 70 phr of a rubber chosen from butyl rubber, halobutyl rubber, butadiene rubber, styrene-butadiene rubber, and mixtures thereof, and (ii) 5 phr to 120 phr of at least one reinforcement filler.