Coloring Composition Striation Suppression via Solvent Surface Tension

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Solution Overview

Problem

The production of films using coloring compositions often results in striation, particularly on surfaces with unevenness, due to the existing limitations in coatability and drying properties.

Innovation Solution

A coloring composition comprising a coloring agent, resin, polymerizable compound, and photopolymerization initiator, with a specific ratio of ester-based and organic solvents that adjust surface tension and drying properties to suppress striation, including ester-based solvents with surface tensions between 25-35 mN/m and organic solvents with surface tensions below 25 mN/m, and a boiling point range of 50-135°C.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If a coloring composition is applied onto a surface having floor level difference such as unevenness, then coating coverage is achieved, but radial streaks called striation are generated

Engineering Contradiction:
Improvefilm uniformityVSAvoidstriation
Core Design Contradiction:
Manufacturing precisionVSObject-affected harmful factors

Solution Approach 1:

The patent applies parameter changes by carefully selecting and controlling the surface tension of organic solvents (combining high surface tension solvents of 25-35 mN/m with low surface tension solvents of less than 25 mN/m) to optimize the coloring composition's wetting properties. This parameter optimization enables the composition to flow smoothly over uneven surfaces without forming striation, thereby improving film uniformity while coating complex substrates

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses composite materials by combining multiple organic solvents with different surface tension characteristics in a specific ratio (50% or more of the total organic solvent content). This composite solvent system synergistically balances wetting ability and flow characteristics, allowing the coloring composition to adapt to surfaces with floor level differences while preventing radial streak formation

Inventive Principle:
Principle #40Composite materials

2Ease of operation

If conventional coloring compositions are used to improve coatability, then application ease is enhanced, but striation occurs on uneven surfaces

Engineering Contradiction:
ImprovecoatabilityVSAvoidfilm quality
Core Design Contradiction:
Ease of operationVSManufacturing precision

Solution Approach 1:

The patent improves both coatability and film quality through parameter changes by optimizing the surface tension parameters of the organic solvent system. The specific combination of high surface tension solvents (25-35 mN/m) and low surface tension solvents (<25 mN/m) creates ideal wetting properties that enhance application ease while simultaneously preventing striation, achieving both excellent coatability and high film quality

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition effectively suppresses striation during application, enhancing coatability and achieving improved film quality by optimizing wettability and drying properties.

Implementation Method 1

an organic solvent E including an ester-based solvent E1 having a surface tension at 25° C. of from 25 mN/m to 35 mN/m, an organic solvent E2 having a surface tension at 25° C. of less than 25 mN/m

Methodology Applied
Scientific EffectSurface tension: Surface Tension

Implementation Method 2

a polymerizable compound C; a photopolymerization initiator D

Methodology Applied
Scientific EffectPhotopolymerization: Photopolymerisation

Data Source

PatentUS11169439B2Coloring composition and method for producing film
Publication Date: 2021.11.09 FUJIFILM CORP
  • US11169439B2 patent drawing
  • US11169439B2 patent drawing
  • US11169439B2 patent drawing

AI summary

Provided are a coloring composition capable of producing a film with suppressed occurrence of striation, and a method for producing a film. The coloring composition includes a coloring agent A, a resin B, a polymerizable compound C, a photopolymerization initiator D, and an organic solvent E, in which the organic solvent E includes an ester-based solvent E1 having a surface tension at 25° C. of from 25 mN/m to 35 mN/m, an organic solvent E2 having a surface tension at 25° C. of less than 25 mN/m, a ratio of a mass of the ester-based solvent E1 to the mass of the organic solvent E2 is 80:20 to 30:70 in terms of the ratio of the mass of the ester-based solvent E1:the mass of the organic solvent E2, and the organic solvent E contains 50% by mass or more of a combination of the ester-based solvent E1 and the organic solvent E2 with respect to the total mass of the organic solvent E.