Colorless Transparent Toner with Urethane Bonds for Fixing Stability

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Current toners with crystalline resin for image forming face challenges in balancing low temperature fixability and high temperature stability, often resulting in poor offset resistance and peeling issues due to uneven crystallization, which affects image quality and durability.

Innovation Solution

Development of a colorless transparent toner with a binder resin containing a crystalline resin having a urethane bond and/or a urea bond, optimized to achieve a softening point to maximum peak temperature ratio of 0.8 to 1.55, ensuring strong attachment to substrates and improved viscoelasticity for balanced fixability and stability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Temperature

If a crystalline resin is used for low-temperature fixing, then the fixing temperature is reduced, but the attachment strength to substrate weakens due to crystallization

Engineering Contradiction:
Improvefixing temperatureVSAvoidattachment strength
Core Design Contradiction:
TemperatureVSStrength

Solution Approach 1:

The patent changes the chemical composition parameters of the crystalline resin by introducing urethane bonds and/or urea bonds into the polymer structure. This chemical modification allows the resin to maintain crystallinity for low-temperature fixing while the specific chemical bonds provide enhanced adhesion to substrates, resolving the contradiction between low fixing temperature and strong attachment.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite binder resin system combining crystalline resin with specific chemical functional groups (urethane/urea bonds). This composite material approach integrates the low-temperature fixing property of crystalline structure with the high adhesion property of urethane/urea bonded polymers, achieving both requirements simultaneously.

Inventive Principle:
Principle #40Composite materials

2Productivity

If the toner is fixed onto substrate, then the image is formed, but the toner layer peels off after image formation due to crystallization progression

Engineering Contradiction:
Improveimage formation capabilityVSAvoidimage durability
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent modifies the chemical structure parameters of the crystalline resin by incorporating urethane and/or urea bonds. These chemical modifications maintain the crystallinity needed for image formation while the specific chemical bonding characteristics prevent peeling and enhance long-term durability, resolving the contradiction between productivity and reliability.

Inventive Principle:
Principle #35Parameter changes

3Stability of the object's composition

If colorless transparent toner is applied to reduce uneven gloss, then the gloss uniformity is improved, but the offset resistance and abrasion resistance must be balanced

Engineering Contradiction:
Improvegloss uniformityVSAvoidoffset resistance and abrasion resistance
Core Design Contradiction:
Stability of the object's compositionVSReliability

Solution Approach 1:

The patent changes the chemical composition of the binder resin to include crystalline resin with urethane/urea bonds. This composition modification provides the right balance between gloss uniformity (through controlled crystallization) and surface durability (through strong chemical bonding), resolving the contradiction between aesthetic quality and functional reliability.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The toner achieves a good combination of low temperature fixability and high temperature stability, enhancing image durability and reducing peeling issues while maintaining uniform gloss and offset resistance.

Implementation Method 1

the toner described therein must strike a balance between offset resistance and abrasion resistance. In particular, when the toner using a crystalline resin is fixed onto a substrate like paper, the attachment of the toner to the paper weakens as crystallization progresses

Methodology Applied
Scientific EffectCrystallization: Crystallisation

Implementation Method 2

optimized to achieve a softening point to maximum peak temperature ratio of 0.8 to 1.55, ensuring strong attachment to substrates and improved viscoelasticity for balanced fixability and stability

Methodology Applied
Scientific EffectViscoelasticity: Viscoelasticity

Data Source

PatentUS9005859B2Colorless transparent toner, toner set, development agent, image forming apparatus, and printed matter
Publication Date: 2015.04.14 RICOH CO LTD
  • US9005859B2 patent drawing
  • US9005859B2 patent drawing

AI summary

A colorless transparent toner containing a crystalline resin having a urethane bond and/or a urea bond.