Thermal Barrier Coatings with Columnar Voids for Low Conductivity

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Solution Overview

Problem

Current thermal barrier coatings for gas turbine engines face challenges in maintaining low thermal conductivity and high toughness, especially when exposed to demanding engine designs, as they often compromise on erosion resistance and cyclic life due to their microstructural characteristics.

Innovation Solution

The development of a thermal barrier coating system that incorporates a columnar microstructure with elongated surface-connected voids and nonspherical particles, along with surface-connected microporosity cracks, to reduce thermal conductivity while enhancing fracture toughness and cyclic life, using materials like yttria-stabilized zirconia and rare-earth containing oxides.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Temperature

If thermal barrier coatings are designed with traditional microstructures to maintain low thermal conductivity, then thermal insulation performance is improved, but erosion resistance and cyclic life deteriorate

Engineering Contradiction:
Improvethermal conductivityVSAvoiderosion resistance and cyclic life
Core Design Contradiction:
TemperatureVSReliability

Solution Approach 1:

The patent applies porous materials by designing a thermal barrier coating with a columnar microstructure containing elongated surface-connected voids. These voids create a porous network that reduces thermal conductivity while the columnar architecture provides crack deflection paths that improve erosion resistance and cyclic life, resolving the contradiction between thermal insulation and reliability

Inventive Principle:
Principle #31Porous materials

Solution Approach 2:

The patent employs composite materials by combining yttria-stabilized zirconia (YSZ) with rare-earth containing oxides in a specific composition ratio. This composite formulation achieves ultra-low thermal conductivity while the interaction between different ceramic phases enhances toughness and resistance to thermal cycling and erosion, simultaneously improving both thermal insulation and reliability

Inventive Principle:
Principle #40Composite materials

2Temperature

If thermal barrier coatings incorporate columnar microstructure with elongated voids to reduce thermal conductivity, then thermal insulation is improved, but coating complexity increases

Engineering Contradiction:
Improvethermal conductivityVSAvoidcoating microstructure complexity
Core Design Contradiction:
TemperatureVSDevice complexity

Solution Approach 1:

The patent applies segmentation by dividing the coating into distinct columnar units with elongated voids between them. This segmented columnar microstructure creates thermal barriers at each column interface while maintaining a relatively simple overall coating architecture that can be applied using conventional thermal spray processes, balancing thermal performance with manufacturing simplicity

Inventive Principle:
Principle #1Segmentation

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The coating achieves ultra-low thermal conductivity (less than 1.8 W/mK at 1000°C) and suitable toughness, improving the durability and efficiency of components in high-temperature environments by effectively managing thermal expansion and crack propagation.

Implementation Method 1

The coating achieves ultra-low thermal conductivity (less than 1.8 W/mK at 1000°C) and suitable toughness, improving the durability and efficiency of components in high-temperature environments by effectively managing thermal expansion and crack propagation

Methodology Applied
Scientific EffectThermal insulation: Thermal Insulation

Implementation Method 2

improving the durability and efficiency of components in high-temperature environments by effectively managing thermal expansion and crack propagation

Methodology Applied
Scientific EffectThermal expansion: Thermal Expansion

Data Source

PatentEP4261322A1Vertically cracked thermal barrier coatings compositions
Publication Date: 2023.10.18 GENERAL ELECTRIC CO
  • EP4261322A1 patent drawingFigure 1~2
  • EP4261322A1 patent drawingFigure 3
  • EP4261322A1 patent drawing

AI summary

Coated components (100), along with methods of their formation, are provided. The coated component (100) may include a substrate (120) having a surface (115) and a thermal barrier coating (110) on the surface (115) of the substrate (120). The thermal barrier coating (110) includes a plurality of elongated surface connected voids (130) therein, and wherein the thermal barrier coating (110) comprises a plurality of nonspherical particles (112) within a ceramic thermal barrier material (114).