Comb-Like Polymer Coating for Permanent Anti-Icing

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Solution Overview

Problem

Existing anti-icing solutions fail to provide a permanent and reliable method to prevent surfaces from icing, as they either rely on costly natural proteins or dissolved substances that do not persistently lower the freezing point.

Innovation Solution

A permanent coating using polymers with hydrophobic main chains and hydrophilic side chains, arranged in a comb-like structure, is applied to surfaces, where the side chains point away from the surface and are freely movable, creating a solvated layer that prevents ice adhesion and allows easy removal of ice formed beyond -10°C.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If antifreeze proteins are used to prevent ice crystal adhesion, then icing prevention is achieved, but the cost becomes excessively high

Engineering Contradiction:
Improveicing preventionVSAvoidcost
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent copies the functional effect of expensive antifreeze proteins by using a simplified polymer coating system. The comb-like polymer structure with hydrophilic side chains mimics the ice-preventing mechanism of natural proteins at a fraction of the cost, achieving similar icing prevention without relying on costly biological materials

Inventive Principle:
Principle #26Copying

Solution Approach 2:

The patent changes the chemical parameters of the coating by using polymers with specific hydrophilic side chains (such as carboxyl, hydroxyl, or amine groups) that can interact with ice crystals. This parameter modification allows the coating to prevent icing through chemical interaction rather than relying on expensive natural proteins

Inventive Principle:
Principle #35Parameter changes

2Reliability

If dissolved substances are used to lower the freezing point, then de-icing effect is achieved, but the coating is not permanent and the substance dissipates over time

Engineering Contradiction:
Improvede-icing effectVSAvoidcoating durability
Core Design Contradiction:
ReliabilityVSDuration of action of stationary object

Solution Approach 1:

The patent applies the polymer coating to the surface in advance before icing occurs. The comb-like structure with hydrophilic side chains is pre-positioned on the surface, creating a permanent protective layer that prevents ice adhesion from the outset, rather than relying on dissolved substances that need to be continuously present

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent uses a composite polymer structure combining hydrophobic main chains with hydrophilic side chains. This composite material provides both structural integrity for permanent coating and chemical functionality for ice prevention, creating a durable solution that combines the stability of polymers with the ice-preventing properties of hydrophilic groups

Inventive Principle:
Principle #40Composite materials

3Reliability

If a coating is applied to prevent ice adhesion, then icing prevention is achieved, but the coating must remain stable under moisture exposure while preventing ice formation

Engineering Contradiction:
Improveicing preventionVSAvoidcoating stability under moisture
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

The patent applies local quality differentiation within the polymer structure itself. The main chains provide structural stability and moisture resistance, while the side chains provide hydrophilic ice-preventing functionality. This local differentiation allows different parts of the coating to have specialized functions that work together

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The coating effectively and cost-effectively prevents icing on surfaces down to -10°C by maintaining a liquid or air layer at the surface interface, preventing ice adhesion and allowing easy removal of formed ice, while being durable and stable under moisture exposure.

Implementation Method 1

the side chains, arranged analogously to the teeth of a comb, all point away from the surface, as described above, and are essentially free to move in the space near the surface. As soon as the coated surface comes into contact with water or humid air, the free hydrophilic side chains are solvated

Methodology Applied
Scientific EffectSolvation: Solvation

Implementation Method 2

the polymer main chains are bonded to the surface via chemical and/or chemical-coordinative and/or physical interactions

Methodology Applied
Scientific EffectChemical bonding: Chemical Bonding

Implementation Method 3

the polymer main chains are bonded to the surface via chemical and/or chemical-coordinative and/or physical interactions

Methodology Applied
Scientific EffectAdsorption: Adsorption

Implementation Method 4

directly above the main polymer chains, i.e., in the solid/liquid or solid/gas boundary layer, the water remains liquid or an air layer is present

Methodology Applied
Scientific EffectBoundary layer: Boundary Layer

Data Source

PatentEP2102295B1Permanent coating of surfaces for inhibiting and/or preventing them from icing up, and use for that purpose
Publication Date: 2019.08.21 LEIBNIZ INST FUR POLYMERFORSCHUNG DRESDEN EV

AI summary

The invention pertains to the fields of chemistry and of mechanical engineering and relates to a permanent coating which exhibits functionalization of the surfaces for the purpose of preventing or reducing the spread of ice on said surface. The problem addressed by the present invention is that of specifying a permanent coating which is durable and which reliably inhibits and/or prevents the surface from icing up. This problem is solved by a permanent coating of surfaces for the purpose of inhibiting and/or preventing them from icing up down to ambient temperatures of -10°C, the coating being composed of polymers having main chains and side chains, the polymer main chains being hydrophobic and the side chains being hydrophilic, and the polymer main chains having entered into chemical and/or chemical-coordinative and/or physical interaction with the surface to be coated, and the side chains being disposed on the polymer main chain essentially in a direction away from the surface, and the side chains entering at least into no lasting interaction with one another.