Comb Polymers Solubilize Molybdenum Friction Modifiers

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Solution Overview

Problem

Molybdenum dithiocarbamate friction modifiers have limited solubility in API Group III or Group III+ base oils, leading to reduced effectiveness in lubricating compositions, especially at lower temperatures, resulting in haze or precipitation, which affects the lubricant's performance.

Innovation Solution

The use of polyalkyl(meth)acrylate based comb polymers, comprising specific monomers such as esters of (meth)acrylic acid and hydroxylated hydrogenated polybutadiene, and nitrogen-containing (meth)acrylates, enhances the solubility of molybdenum in lubricating compositions by forming a stable dispersion, thereby improving lubricant performance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If molybdenum dithiocarbamate friction modifiers are added to API Group III or Group III+ base oils, then friction reduction performance is improved, but solubility deteriorates leading to haze or precipitation especially at lower temperatures

Engineering Contradiction:
Improvefriction reduction performanceVSAvoidsolubility
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

The patent introduces a solubilizing agent as an intermediary substance that mediates between the molybdenum dithiocarbamate friction modifier and the API Group III or Group III+ base oil. This solubilizing agent has affinity for both the polar friction modifier and the non-polar base oil, enabling the friction modifier to remain dissolved and effective without causing haze or precipitation. The solubilizing agent acts as a bridge that resolves the incompatibility between the polar head group of the friction modifier and the non-polar base oil matrix.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Use of energy by moving object

If the viscosity of engine oils is reduced to improve fuel economy, then friction at hydrodynamic lubrication is reduced, but the lubricant film thickness deteriorates leading to increased wear and friction

Engineering Contradiction:
Improvefuel economyVSAvoidlubricant film thickness
Core Design Contradiction:
Use of energy by moving objectVSReliability

Solution Approach 1:

The patent changes the chemical composition parameters of the lubricant by incorporating molybdenum dithiocarbamate friction modifiers and solubilizing agents. This allows the use of lower viscosity base oils (improving fuel economy) while the additive package compensates for the reduced film-forming capability. The molybdenum compound forms protective tribofilms on metal surfaces that maintain adequate lubrication even when the hydrodynamic film is thinner due to lower viscosity.

Inventive Principle:
Principle #35Parameter changes

3Reliability

If dosage of molybdenum dithiocarbamate is increased to improve friction reduction, then friction coefficient is reduced, but solubility limit is exceeded causing precipitation

Engineering Contradiction:
Improvefriction reductionVSAvoiddosage
Core Design Contradiction:
ReliabilityVSQuantity of substance

Solution Approach 1:

The solubilizing agent serves as a mediator that enables higher concentrations of molybdenum dithiocarbamate to remain in solution. By incorporating this intermediary substance, the patent overcomes the solubility limit that would otherwise constrain the dosage of friction modifier. The solubilizing agent molecules surround and stabilize the polar molybdenum compounds, allowing them to disperse uniformly in the non-polar base oil at higher concentrations without precipitating.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The polyalkyl(meth)acrylate based comb polymers increase the solubility of molybdenum in lubricating oils by up to 0.2% by weight, maintaining stability at low temperatures and reducing friction coefficients, ensuring effective lubrication without precipitation.

Implementation Method 1

enhances the solubility of molybdenum in lubricating compositions by forming a stable dispersion

Methodology Applied
Scientific EffectDispersion: Dispersion (of waves)

Implementation Method 2

increase the solubility of molybdenum in lubricating oils

Methodology Applied
Scientific EffectSolvation: Solvation

Implementation Method 3

Friction modifiers are used to modify a lubricant's coefficient of friction. They are designed to change the amount of energy needed to cause two surfaces to move past one another

Methodology Applied
Scientific EffectFriction modification: Friction

Implementation Method 4

The polar head attaches to the metal surfaces

Methodology Applied
Scientific EffectAdsorption: Adsorption

Data Source

PatentUS10941368B2Lubricating oil composition comprising dispersant comb polymers
Publication Date: 2021.03.09 EVONIK OPERATIONS GMBH

AI summary

Selected comb polymers contain specified amounts of macromonomer and nitrogen-containing (meth)acrylates. Lubricant compositions can contain such comb polymers. The selected comb polymers can be used as solubilizers in lubricant compositions, especially in engine oil (EO) compositions.