Compact SCR System with Vaporizer Module for Uniform Ammonia Distribution

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Solution Overview

Problem

Existing SCR systems for reducing NOx in engines face space constraints and inefficiencies due to long urea injection ducts and uneven ammonia distribution, leading to reduced NOx conversion and potential precipitation issues, particularly in smaller engines like those in marine and power generation sectors.

Innovation Solution

A compact SCR system with a vaporizer module and inlet flow system that uses hot treated exhaust gas to decompose urea into ammonia, providing a longer residence time and uniform distribution across the SCR reactor, eliminating the need for an ammonia injection grid and reducing system size.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Duration of action of moving object

If long injection ducts are used to provide sufficient residence time for urea decomposition, then ammonia generation is improved, but system size and space requirements increase

Engineering Contradiction:
Improveurea residence timeVSAvoidinjection duct volume
Core Design Contradiction:
Duration of action of moving objectVSVolume of stationary object

Solution Approach 1:

The patent increases the temperature parameter in the vaporizer module (using hot exhaust gas at 150-450°C) to accelerate urea decomposition kinetics, allowing sufficient residence time (0.5-5 seconds) to be achieved in a much shorter duct length compared to lower temperature systems

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent divides the exhaust flow into two separate streams: one passing through the vaporizer module for urea decomposition, and another bypassing it. These streams are then recombined, allowing the decomposition process to occur in a dedicated small-volume zone rather than requiring a long common duct for all exhaust

Inventive Principle:
Principle #1Segmentation

2Volume of stationary object

If urea is injected directly into exhaust gas without sufficient decomposition time, then system size is reduced, but precipitation on reactor walls and catalyst occurs

Engineering Contradiction:
Improveinjection duct volumeVSAvoidprecipitation prevention
Core Design Contradiction:
Volume of stationary objectVSReliability

Solution Approach 1:

The patent performs preliminary decomposition of urea in the vaporizer module before the exhaust enters the SCR reactor. The hot exhaust gas pre-heats and decomposes urea in advance, ensuring complete vaporization and conversion to ammonia before catalyst contact, preventing precipitation

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent introduces hot exhaust gas as an intermediary medium in the vaporizer module to transfer thermal energy to urea, facilitating its decomposition. This intermediary approach allows controlled decomposition in a dedicated zone before mixing with the main exhaust stream

Inventive Principle:
Principle #24Intermediary (Mediator)

3Device complexity

If ammonia is directly introduced into exhaust flow without uniform distribution, then system complexity is reduced, but temperature unevenness leads to precipitation and corrosion

Engineering Contradiction:
Improveammonia distribution system complexityVSAvoidtemperature uniformity
Core Design Contradiction:
Device complexityVSReliability

Solution Approach 1:

The patent segments the ammonia introduction process into two stages: (1) decomposition in the vaporizer module where hot exhaust gas creates turbulent mixing, and (2) recombination of the decomposed stream with the bypass stream, achieving uniform distribution without complex injection grids

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent utilizes turbulent flow (a form of mechanical motion) in the vaporizer module to enhance mixing of urea decomposition products with exhaust gas. The chaotic eddies and vortices in turbulent flow promote uniform ammonia distribution, preventing localized cold spots

Inventive Principle:
Principle #18Mechanical vibration

4Manufacturing precision

If long ducts with large diameter are used for SCR systems in 500-4500 kW engines, then NOx conversion is improved, but space constraints in marine and power generation applications are worsened

Engineering Contradiction:
ImproveNOx conversion efficiencyVSAvoidSCR system volume
Core Design Contradiction:
Manufacturing precisionVSVolume of stationary object

Solution Approach 1:

The patent changes the temperature parameter in the vaporizer module to optimize urea decomposition rate, achieving high conversion efficiency in a compact volume. The controlled temperature range (150-450°C) ensures complete decomposition without requiring long residence times

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent combines multiple functions into integrated components: the vaporizer module serves both as a heating zone and decomposition reactor, while the flow distribution system combines separation and recombination functions, reducing overall system volume compared to conventional separate components

Inventive Principle:
Principle #5Merging (Combining)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This configuration achieves efficient NOx reduction with a more compact design, ensuring uniform ammonia distribution and longer decomposition time, thereby enhancing NOx conversion efficiency and reducing space requirements for installation.

Implementation Method 1

a stream of hot treated exhaust gas is used to provide for decomposition of the urea into its active components including ammonia

Methodology Applied
Scientific EffectThermal decomposition: Pyrolysis

Implementation Method 2

The inlet flow system is located adjacent to at least four sides of the SCR reactor and is configured to provide an approximately uniform flow of the exhaust gas through the catalyst

Methodology Applied
Scientific EffectFluid flow distribution:

Implementation Method 3

The flow of exhaust gases through flow ducts around the SCR provides additional heat to the vaporizer module to volatilize a solution of urea

Methodology Applied
Scientific EffectHeat transfer: Convection

Implementation Method 4

Nitrogen oxides formed in the combustion process of fossil and renewable fuels are reduced with a reductant, such as ammonia, on a catalytic surface

Methodology Applied
Scientific EffectCatalytic reduction: Catalysis

Data Source

PatentEP3102800B1Compact selective catalytic reduction system for nitrogen oxide reduction in the oxygen-rich exhaust of 500 to 4500 kw internal combustion engines
Publication Date: 2018.10.31 JOHNSON MATTHEY CATALYSTS (GERMANY) GMBH
  • EP3102800B1 patent drawingFigure 1~2
  • EP3102800B1 patent drawingFigure 3~4
  • EP3102800B1 patent drawingFigure 5~6

AI summary

A Selective Catalytic Reduction (SCR) system comprises an SCR reactor (3), comprising at least one SCR catalyst and is in communication with the inlet flow system (1) and the vaporizer module, an inlet flow system (1), comprising one or more entrances for exhaust gases from an engine, wherein the flow of gases through at least one flow duct (11, 12) is located around the SCR reactor (3) and provides heat to the vaporizer module and is introduced into the SCR reactor after the introduction of an ammonia-laden gas stream and after passing through a plurality of baffle plates to provide an uniform gas concentration profile across the cross section of the SCR reactor (3), and a vaporizer module, comprising a means for introducing urea into a heated pre-reactor in which it is at least partially decomposed and prior to introducing the exhaust gas stream to the SCR reactor (3).