Compatibilized Heterophasic Polymer Blends for Melt Flow and Impact Strength

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Solution Overview

Problem

Existing polymer compositions with high recycled content suffer from reduced impact strength and melt flow rate, necessitating compromises that degrade performance.

Innovation Solution

A method involving a compatibilizing agent with functional groups capable of reacting with free radicals is used to enhance the interaction between a heterophasic polymer composition and recycled polymer, generating free radicals to improve compatibility and maintain or enhance impact resistance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If peroxide is used to increase melt flow rate of recycled resin, then melt flow rate is improved, but impact resistance and stiffness deteriorate

Engineering Contradiction:
Improvemelt flow rateVSAvoidimpact resistance
Core Design Contradiction:
ProductivityVSStrength

Solution Approach 1:

The patent introduces a compatibilizing agent as an intermediary substance that mediates between the recycled resin and the peroxide treatment. This agent contains functional groups that react with free radicals generated by peroxide decomposition, thereby controlling the free radical activity to improve melt flow rate while protecting the polymer chains from excessive degradation that would harm impact resistance

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent changes the chemical parameters of the system by introducing a compatibilizing agent with specific functional groups (such as hydroxyl, carboxyl, or amine groups) that can react with free radicals. This parameter change allows selective modification of the polymer properties - increasing melt flow rate through controlled chain scission while maintaining impact resistance by preventing uncontrolled degradation

Inventive Principle:
Principle #35Parameter changes

2Reliability

If recycled polymer content is increased in polymer composition, then sustainability is improved, but impact strength and stiffness deteriorate

Engineering Contradiction:
ImprovesustainabilityVSAvoidimpact strength
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The compatibilizing agent serves as an intermediary that improves the interfacial adhesion between different polymer phases in the recycled composition. By containing functional groups that can interact with both the recycled polymer chains and the matrix polymer, it enhances compatibility and maintains mechanical properties even at high recycled content levels

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent creates a composite material system where the compatibilizing agent forms a third phase or interfacial layer between the recycled polymer and the matrix polymer. This composite structure allows the combination of high recycled content with maintained mechanical properties by providing a bridging phase that transfers stress effectively between different polymer domains

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method results in polymer compositions with improved impact strength and melt flow rate while maintaining high recycled content, balancing performance and sustainability.

Implementation Method 1

providing a compatibilizing agent which (i) comprises two or more functional groups capable of reacting with a free radical in a radical addition reaction

Methodology Applied
Scientific EffectRadical addition reaction: Chemical Bonding

Implementation Method 2

generating free radicals in the propylene polymer phase and the ethylene polymer phase of the heterophasic polymer composition and in the polymer of the second polymer composition

Methodology Applied
Scientific EffectFree radical generation: Decomposition (biological)

Data Source

PatentEP3585835B1Method for making heterophasic polymer compositions
Publication Date: 2025.08.20 MILLIKEN & CO
  • EP3585835B1 patent drawing
  • EP3585835B1 patent drawing
  • EP3585835B1 patent drawing

AI summary

A method for producing a polymer composition comprises the steps of providing a compatibilizing agent, providing a heterophasic polymer composition, providing a second polymer composition comprising recycled polymer; mixing the compatibilizing agent, the heterophasic polymer composition, and the second polymer composition, and generating free radicals in the heterophasic polymer composition and the second polymer composition. At least a portion of the compatibilizing agent is believed to react with the free radicals generated in the heterophasic polymer composition and the second polymer composition.