Complex Waveform Electrolytic Plating for PCB Via Filling

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Solution Overview

Problem

Existing methods for metallizing through-holes and blind vias in electronic substrates often result in incomplete filling, leading to voids and dimples, which compromise the reliability and electrical properties of the substrates.

Innovation Solution

A complex multi-step waveform pulse plating regime is employed, combining forward and reverse pulses with optional rest periods, to initiate plating in the center of through-holes and ensure complete filling without defects.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If conventional plating methods are used, then plating process is simple, but filling is incomplete resulting in voids and dimples

Engineering Contradiction:
Improvefilling completenessVSAvoidplating process complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The patent employs a complex multi-step waveform consisting of alternating forward and reverse pulses with different durations and current densities. This periodic action creates controlled deposition and dissolution cycles that enable complete hole filling by preventing premature bridge formation and eliminating voids, thereby resolving the contradiction between filling completeness and process complexity.

Inventive Principle:
Principle #19Periodic action

Solution Approach 2:

The plating process uses dynamically adjusted current density and pulse timing parameters throughout the plating cycle. The waveform transitions between different phases (forward pulse, reverse pulse, rest periods) with varying current densities to adaptively control deposition rates, ensuring complete filling while managing process complexity through systematic parameter variation.

Inventive Principle:
Principle #15Dynamics

2Manufacturing precision

If plating parameters are optimized for hole filling, then filling improves, but surface copper deposition increases

Engineering Contradiction:
Improvethrough-hole fillingVSAvoidsurface copper deposition
Core Design Contradiction:
Manufacturing precisionVSQuantity of substance

Solution Approach 1:

The complex waveform creates different plating conditions at different locations: during forward pulses, high current density promotes preferential deposition in through-holes where resistance is higher, while the reverse pulses and rest periods allow surface copper to be partially dissolved or redistributed. This local quality differentiation enables selective filling of through-holes while controlling overall surface deposition.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent utilizes significant variations in current density parameters between forward and reverse pulses, as well as between different phases of the waveform. By changing current density from high during forward pulses to low or reversed during reverse pulses, the process optimizes copper ion transport and deposition kinetics to preferentially fill through-holes while minimizing net surface deposition.

Inventive Principle:
Principle #35Parameter changes

3Manufacturing precision

If pulse plating is used, then deposition control improves, but process time increases

Engineering Contradiction:
Improvedeposition controlVSAvoidplating cycle time
Core Design Contradiction:
Manufacturing precisionVSLoss of time

Solution Approach 1:

The complex multi-step waveform maintains continuous useful action by eliminating idle time between pulses and optimizing the duration of each phase. The sequence of forward pulses, reverse pulses, and rest periods is designed to maximize copper ion utilization and deposition efficiency throughout the entire cycle, ensuring that every moment contributes to the filling process rather than creating unnecessary downtime.

Inventive Principle:
Principle #20Continuity of useful action

Solution Approach 2:

The periodic waveform structure with optimized pulse frequencies and duty cycles enables rapid cycling between deposition and dissolution phases. By carefully selecting pulse durations and repetition rates, the process achieves thorough through-hole filling within a controlled time framework, balancing deposition control requirements with production efficiency.

Inventive Principle:
Principle #19Periodic action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The proposed method achieves reliable and defect-free metallization of through-holes and blind vias, enhancing the reliability and electrical properties of electronic substrates while minimizing surface copper deposition.

Implementation Method 1

A complex multi-step waveform pulse plating regime is employed, combining forward and reverse pulses with optional rest periods, to initiate plating in the center of through-holes and ensure complete filling without defects.

Methodology Applied
Scientific EffectElectroplating: Electroplating

Implementation Method 2

The present invention relates generally to an electrolytic deposition method for metallizing electronic substrates.

Methodology Applied
Scientific EffectElectrochemical deposition: Electrodeposition

Implementation Method 3

A complex multi-step waveform pulse plating regime is employed, combining forward and reverse pulses with optional rest periods

Methodology Applied
Scientific EffectElectrophoresis: Electrophoresis

Data Source

PatentUS12325927B2Complex waveform for electrolytic plating
Publication Date: 2025.06.10 MACDERMID ENTHONE INC
  • US12325927B2 patent drawing
  • US12325927B2 patent drawing
  • US12325927B2 patent drawing

AI summary

A method of copper electroplating in the manufacture of printed circuit boards. The method is used for filling through-holes and blind micro-vias with copper. The method includes the steps of: (1) preparing an electronic substrate to. receive copper electroplating thereon; (2) forming at least one of one or more through-holes and/or one or more blind micro-vias in the electronic substrate: and (3) electroplating copper in the at one or more through-holes and/or one or more blind micro-vias by contacting the electronic substrate with an acid copper electrolyte. The acid copper electrolyte is used to plate the one or more through-holes and/or the one or more blind micro-vias using a complex waveform including pulse reverse plating, DC plating and/or synchronous pulse plating. The complex waveforms can be used for filling through-holes and blind microvias with copper without defects.