Composite Adsorbent Material for Humidity Control

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Solution Overview

Problem

Existing adsorbent materials for humidity control and heat exchange face challenges such as difficulty in shaping, low mechanical strength, and limited thermal stability, which restrict their industrial applications due to the presence of toxic components and brittleness.

Innovation Solution

A composite material comprising a moisture adsorbent like zeolite or silica gel combined with a permeable polymer matrix made from cellulose acetate or non-crosslinked siloxane/silane elastomers, providing enhanced mechanical resistance and thermal stability up to 240°C, allowing for effective humidity control and heat exchange.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If thermoplastic polymer blend with plasticizers and wax is used as matrix, then rheological properties are improved for shaping and gas/water vapor permeability is provided, but operating temperature is limited to 100°C

Engineering Contradiction:
Improveshaping capabilityVSAvoidoperating temperature
Core Design Contradiction:
Ease of manufactureVSTemperature

Solution Approach 1:

The patent changes the polymer matrix from thermoplastic blend to thermosetting polymer, fundamentally altering the material's thermal behavior. This parameter change enables the matrix to maintain structural integrity at temperatures up to 200°C while preserving shaping capability through proper formulation and processing methods.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite material system combining polymer matrix with moisture adsorbent particles. This composite structure provides both the mechanical/thermal stability of the polymer and the functional sorption properties of the adsorbent, achieving multiple performance targets simultaneously.

Inventive Principle:
Principle #40Composite materials

2Strength

If epoxy-based polymer is used as matrix, then mechanical strength is improved, but toxicity from bisphenol and brittleness from repeated thermal cycling occur

Engineering Contradiction:
Improvemechanical strengthVSAvoidtoxicity and brittleness
Core Design Contradiction:
StrengthVSObject-affected harmful factors

Solution Approach 1:

The patent extracts and eliminates the harmful epoxy component from the material system. By replacing epoxy with alternative polymer matrices, the solution removes the source of toxicity and brittleness while maintaining the essential mechanical strength and thermal stability requirements.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent employs polymer matrices that can be easily replaced or degraded if needed, avoiding the use of persistent toxic substances like epoxy. The chosen polymers provide sufficient service life for the application while being environmentally benign and non-persistent.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

3Reliability

If adsorbent material is used alone, then sorbent properties are maintained, but difficulty in shaping and low mechanical strength lead to deterioration

Engineering Contradiction:
Improvesorbent propertiesVSAvoidmechanical strength
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The patent creates a composite material system combining polymer matrix with moisture adsorbent particles. This composite structure provides both the mechanical/thermal stability of the polymer and the functional sorption properties of the adsorbent, achieving multiple performance targets simultaneously.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The polymer matrix acts as an intermediary carrier that holds the adsorbent particles together, providing mechanical strength and shaping capability while allowing the adsorbent to maintain its sorption function. The matrix mediates between the conflicting requirements of structural integrity and functional performance.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composite material maintains the sorbent properties of the adsorbent while offering high mechanical resistance and thermal stability, enabling long-lasting industrial applications in humidity control and heat exchange devices, with the permeable polymer matrix ensuring vapor permeability and resistance to thermal cycling.

Implementation Method 1

the adsorbent material either absorbs moisture through an exothermic reaction that releases heat

Methodology Applied
Scientific EffectAdsorption: Adsorption

Implementation Method 2

absorbs moisture through an exothermic reaction that releases heat

Methodology Applied
Scientific EffectExothermic reaction: Exothermic Reaction

Implementation Method 3

it desorbs the moisture it contains through an endothermic reaction that consumes heat

Methodology Applied
Scientific EffectDesorption: Desorption

Implementation Method 4

desorbs the moisture it contains through an endothermic reaction that consumes heat

Methodology Applied
Scientific EffectEndothermic reaction: Endothermic Reaction

Implementation Method 5

the matrix of a permeable polymer... has a water vapor permeability greater than 6000 bars

Methodology Applied
Scientific EffectPermeation: Permeation

Data Source

PatentEP4026611A1Composite absorbent material designed for devices for controlling the humidity of heat exchange and storage devices
Publication Date: 2022.07.13 COMMISSARIAT A LENERGIE ATOMIQUE ET AUX ENERGIES ALTERNATIVES
  • EP4026611A1 patent drawingFigure 1~2
  • EP4026611A1 patent drawingFigure 3~5
  • EP4026611A1 patent drawing

AI summary

Adsorbent composite material (4) intended for humidity control devices, heat exchange or heat storage devices, the adsorbent composite material (4) comprising: - a moisture adsorbent (1), selected from the group comprising a zeolite, a silica gel, an activated carbon, an activated alumina and/or a combination thereof, and - a matrix (3) of a permeable polymer, said permeable polymer being obtained from a polymer (2) selected from cellulose acetate or a non-crosslinked elastomer, such as a siloxane and/or a silanized elastomer, so that the matrix (3) of a permeable polymer is stable up to 240°C and has a water vapor permeability greater than 6000 bars.