Composite Carbon Material with Graphene Oxide for Flexible Electrodes

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Solution Overview

Problem

Current flexible electronic components require transparent and flexible electrodes, but existing indium tin oxide (ITO) and conventional conductive carbon materials suffer from poor dispersity and flexibility, leading to inadequate electrical conductivity, and the use of surfactants or solvents compromises conductivity and environmental sustainability.

Innovation Solution

A composite carbon material is developed using graphene oxide to enhance dispersion and conductivity, replacing conventional surfactants, with the graphene oxide forming a dense conductive network and allowing for better electrical conductivity without the need for further purification.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional conductive carbon materials are used, then electrical conductivity is achieved, but dispersity is poor due to hydrophobic nature

Engineering Contradiction:
Improveelectrical conductivityVSAvoiddispersity
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

The patent changes the surface chemical parameters of carbon materials by introducing oxygen-containing functional groups through oxidation treatment. This transforms the hydrophobic surface into a hydrophilic surface, enabling effective dispersion in aqueous solutions while preserving electrical conductivity. The oxidation process modifies surface chemistry without fundamentally changing the conductive carbon structure.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates composite structures by combining oxidized carbon materials (such as carbon nanotubes or graphite) with conductive polymers or other carbon-based conductive materials. This composite approach maintains the hydrophobic core for conductivity while adding hydrophilic surface groups for dispersity, effectively resolving the contradiction between electrical conductivity and dispersity.

Inventive Principle:
Principle #40Composite materials

2Stability of the object's composition

If surfactant or solvent is added to increase dispersity, then dispersity is improved, but electrical conductivity decreases due to non-conductive nature of surfactant

Engineering Contradiction:
ImprovedispersityVSAvoidelectrical conductivity
Core Design Contradiction:
Stability of the object's compositionVSReliability

Solution Approach 1:

The patent extracts and eliminates the need for external surfactants by incorporating oxygen-containing functional groups directly onto the carbon material surface. This self-functionalization approach removes the harmful non-conductive surfactant layer while maintaining dispersity, thereby preserving electrical conductivity.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The oxygen-containing functional groups act as an intermediary between the hydrophobic carbon core and the aqueous environment. Instead of using external non-conductive surfactants, these surface groups serve as the mediating interface that enables dispersion while maintaining the conductive pathway through the carbon material network.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Stability of the object's composition

If surfactant or solvent is used for dispersion, then dispersity is improved, but process complexity increases due to purification requirements

Engineering Contradiction:
ImprovedispersityVSAvoidprocess complexity
Core Design Contradiction:
Stability of the object's compositionVSDevice complexity

Solution Approach 1:

The carbon materials perform self-service by possessing inherent hydrophilic surface properties through oxygen-containing functional groups. This self-functionalization eliminates the need for external surfactant addition and subsequent purification steps, significantly simplifying the processing workflow while achieving effective dispersion.

Inventive Principle:
Principle #25Self-service

4Illumination intensity

If ITO is used for transparent flexible electrodes, then transparency is achieved, but flexibility is poor leading to easy breaking

Engineering Contradiction:
ImprovetransparencyVSAvoidflexibility
Core Design Contradiction:
Illumination intensityVSStrength

Solution Approach 1:

The patent replaces brittle ITO with composite carbon material structures that combine the transparency of carbon-based materials with the flexibility of their one-dimensional or two-dimensional morphology. The oxidized carbon materials maintain optical transparency while their flexible structure prevents breaking during bending, effectively resolving the transparency-flexibility contradiction.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composite carbon material exhibits improved electrical conductivity, flexibility, and dispersity, maintaining performance even when bent, and eliminates the complexity and environmental concerns associated with surfactant use.

Implementation Method 1

the graphene oxide itself also has electrical conductive property and can be used without requiring further purification

Methodology Applied
Scientific EffectElectrical conduction: Conduction (electrical)

Implementation Method 2

The graphene oxide is rich in oxygen-containing functional groups, has excellent dispersion property, and forms a dense conductive network with the substrate

Methodology Applied
Scientific EffectDispersion: Dispersion (of waves)

Implementation Method 3

a method of preparing the graphene oxide includes: embedding a nitrate, a sulfate, or a combination thereof between layers of a carbon material or between adjacent carbon materials, and adding an oxidizing agent to oxidize the carbon material

Methodology Applied
Scientific EffectOxidation: Oxidation

Data Source

PatentUS10535444B2Composite carbon material and method of preparing the same
Publication Date: 2020.01.14 NAT TAIWAN UNIV OF SCI & TECH
  • US10535444B2 patent drawing
  • US10535444B2 patent drawing
  • US10535444B2 patent drawing

AI summary

Provided is a composite carbon material including a substrate and a graphene oxide. The graphene oxide accounts for about 5 wt % to 60 wt % based on a total weight of the substrate and the graphene oxide. A method of preparing a composite carbon material is further provided. The prepared composite carbon material has excellent hydrophilic property, flexibility, electrical conductivity and dispersity.