Composite Cementitious Material for Low-Density Well Cementing

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Cement compositions in well cementing often face challenges in achieving adequate compressive strength and slurry stability at low densities, requiring additional materials and increased pumping pressures, especially in weak formations.

Innovation Solution

A composite cementitious material comprising a micronized particulate solid and a monophase amorphous hydraulic binder is used, which functions as both a cement extender and a cementitious material, reducing slurry density while maintaining strength and stability, by forming a monophase amorphous hydraulic material with a suitable particle size distribution and processing techniques.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Weight of stationary object

If cement compositions are used at low densities, then slurry weight is reduced, but compressive strength and slurry stability deteriorate

Engineering Contradiction:
Improveslurry densityVSAvoidcompressive strength
Core Design Contradiction:
Weight of stationary objectVSStrength

Solution Approach 1:

The patent employs a composite material system combining Class G or Class H cement with specific additives including water-reducing agents, retarding agents, and dispersing agents. This composite formulation enables the slurry to achieve both low density (14.5-16.5 lb/gal) and adequate compressive strength (500-2000 psi at 24 hours) by creating a synergistic effect where additives modify the cement matrix structure and properties.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent systematically adjusts multiple parameters including water-to-cement ratio (0.4-0.6), slurry density (14.5-16.5 lb/gal), and additive concentrations to optimize both strength and stability. By controlling particle size distribution (D10, D50, D90 values) and using micronized extenders, the formulation achieves enhanced packing density and interparticle bonding, thereby maintaining strength at reduced densities.

Inventive Principle:
Principle #35Parameter changes

2Weight of stationary object

If cement compositions are used at low densities, then slurry weight is reduced, but slurry stability deteriorates

Engineering Contradiction:
Improveslurry densityVSAvoidslurry stability
Core Design Contradiction:
Weight of stationary objectVSStability of the object's composition

Solution Approach 1:

The patent controls critical parameters including water-to-cement ratio (0.4-0.6), slurry density (14.5-16.5 lb/gal), and particle size distribution (D10, D50, D90) to optimize stability. By adjusting these parameters and using micronized extenders, the formulation achieves enhanced packing density and interparticle bonding, thereby maintaining strength at reduced densities.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent incorporates retarding agents and dispersing agents that provide feedback control over slurry setting behavior and stability. These additives respond to changes in slurry composition and environment, automatically adjusting setting time and preventing premature settling or segregation, thus maintaining stability throughout the pumping and setting process.

Inventive Principle:
Principle #23Feedback

3Strength

If additional materials are added to low-density cement compositions, then compressive strength is improved, but device complexity increases

Engineering Contradiction:
Improvecompressive strengthVSAvoidcomposition complexity
Core Design Contradiction:
StrengthVSDevice complexity

Solution Approach 1:

The patent uses multi-functional additives that simultaneously achieve multiple objectives. For example, water-reducing agents not only lower water demand but also improve flowability and reduce slurry density. Dispersing agents simultaneously prevent particle aggregation, improve packing density, and enhance strength development. This multi-functionality reduces the need for separate additives for each property, thereby limiting complexity increase.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Solution Approach 2:

The patent combines multiple functional requirements into integrated formulations. Rather than adding separate materials for each property improvement, the composition merges cement, extenders, water-reducing agents, retarding agents, and dispersing agents into a unified system where components work synergistically, achieving strength enhancement without proportionally increasing formulation complexity.

Inventive Principle:
Principle #5Merging (Combining)

4Ease of operation

If pumping pressure is increased for low-density cement compositions, then slurry placement is improved, but energy consumption increases

Engineering Contradiction:
Improveslurry placementVSAvoidpumping energy
Core Design Contradiction:
Ease of operationVSUse of energy by moving object

Solution Approach 1:

The patent optimizes slurry rheological parameters including viscosity, yield stress, and flowability by controlling water-to-cement ratio (0.4-0.6) and using dispersing agents. These parameter adjustments enable the slurry to flow more easily at reduced pumping pressures while maintaining placement quality, thereby reducing the energy required for pumping low-density compositions.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composite cementitious material enhances compressive strength and slurry stability, allowing for lower hydrostatic pressures during pumping, reduced material usage, and increased water addition without compromising stability, suitable for low-density cement compositions.

Implementation Method 1

a monophase amorphous hydraulic binder, and wherein the monophase amorphous hydraulic binder reacts with water to form a set and hardened monophase amorphous hydraulic material

Methodology Applied
Scientific EffectHydraulic binder hydration: Chemical Bonding

Data Source

PatentUS11613689B2Composite cementitious material for cement compositions
Publication Date: 2023.03.28 HALLIBURTON ENERGY SERVICES INC
  • US11613689B2 patent drawing
  • US11613689B2 patent drawing
  • US11613689B2 patent drawing

AI summary

Disclosed herein are methods and compositions for cementing. An example method may comprise providing a cement composition. The cement composition may comprise a composite cementitious material comprising a micronized particulate solid and a monophase amorphous hydraulic binder. The micronized particulate solid may have a mean particle size of about 500 microns or less. The cement composition may further comprise water. The method may further comprise introducing the cement composition into a subterranean formation; and allowing the cement composition to set.