Composite Coating for Corroding Steel Substrates

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Solution Overview

Problem

Current corrosion protection methods for metal substrates, particularly steel, are inadequate in providing a durable and cost-effective solution against corrosive substances like hydrogen sulfide and carbon dioxide under hydrothermal conditions, as they often lack abrasion resistance and mechanical stability.

Innovation Solution

A coating composition comprising a cross-linkable resin with polar groups, hydrophilic flakes having an aspect ratio greater than 10 with a metal oxide surface, and an organic solvent, which forms a highly structured composite that enhances adhesion and barrier properties against corrosive attacks.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If inorganic ceramic layers are used to provide gas barrier protection, then diffusion barrier effect is improved, but mechanical stability and abrasion resistance deteriorate due to brittleness

Engineering Contradiction:
Improvediffusion barrier effectVSAvoidmechanical stability
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The patent applies composite materials by combining inorganic ceramic particles (providing gas barrier properties) with an organic polymer matrix (providing mechanical stability and flexibility). This composite structure allows the coating to simultaneously achieve excellent diffusion barrier effect against corrosive gases like H2S and CO2, while maintaining abrasion resistance and mechanical stability that pure ceramic coatings lack.

Inventive Principle:
Principle #40Composite materials

2Reliability

If high-chromium-containing steels are used to improve corrosion resistance, then protection against corrosive substances is improved, but cost increases significantly

Engineering Contradiction:
Improvecorrosion resistanceVSAvoidcost
Core Design Contradiction:
ReliabilityVSQuantity of substance

Solution Approach 1:

The patent applies this principle by using a protective coating layer that can be applied to standard carbon steel substrates, replacing the need for expensive high-chromium-containing steels. The coating acts as a sacrificial protective layer that prevents corrosion of the underlying steel, achieving comparable or superior corrosion resistance at lower material cost.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Solution Approach 2:

The coating itself is a composite material combining organic polymer matrix with inorganic ceramic particles, creating a cost-effective alternative to expensive alloy steels while providing excellent barrier protection against corrosive substances including hydrogen sulfide and carbon dioxide.

Inventive Principle:
Principle #40Composite materials

3Ease of operation

If polymer-based coatings are used to improve flexibility and ease of application, then ease of operation is improved, but diffusion barrier effect deteriorates due to incomplete gastightness

Engineering Contradiction:
Improveease of applicationVSAvoiddiffusion barrier effect
Core Design Contradiction:
Ease of operationVSReliability

Solution Approach 1:

The patent combines organic polymer matrix (enabling easy application by spraying and maintaining flexibility) with inorganic ceramic particles (providing dense structure and gas barrier properties). This composite approach overcomes the limitation of pure polymer coatings being permeable to gases while retaining their ease of application and flexibility advantages.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution provides excellent adhesion, abrasion resistance, and impact resistance while effectively blocking the diffusion of corrosive gases and water vapor, significantly extending the lifespan of metal substrates in corrosive environments.

Implementation Method 1

a binder comprising at least one cross-linkable resin

Methodology Applied
Scientific EffectCross-linking: Chemical Bonding

Implementation Method 2

very good adhesion to the substrate

Methodology Applied
Scientific EffectAdhesion: Adhesive

Implementation Method 3

effective barrier against a particularly corrosive attack by hydrogen sulfide, carbon dioxide and sea water

Methodology Applied
Scientific EffectDiffusion barrier: Diffusion Barrier

Implementation Method 4

blocking the diffusion of corrosive gases and water vapor

Methodology Applied
Scientific EffectPhysical containment: Physical Containment

Implementation Method 5

at least one type of hydrophilic flakes with an aspect ratio of more than 10, wherein the surface of flakes at least partially comprises a metal oxide

Methodology Applied
Scientific EffectHydrophilicity: Hydrophile

Implementation Method 6

abrasion stable, for example against a grinding effect by sand

Methodology Applied
Scientific EffectAbrasion resistance: Abrasion

Implementation Method 7

resistant to the impact of mechanical load e.g. by tools

Methodology Applied
Scientific EffectImpact resistance: Impact Force

Data Source

PatentUS11427716B2Highly structured composite material and process for the manufacture of protective coatings for corroding substrates
Publication Date: 2022.08.30 LEIBNIZ INSTITUT FUR NEUE MATERIALIEN GMBH
  • US11427716B2 patent drawing
  • US11427716B2 patent drawing
  • US11427716B2 patent drawing

AI summary

A highly structured composite material, which can be applied and cured as a protective layer on corroding metal substrates, particularly on steel is provided. Due to its highly structured composition it is a particularly effective barrier to protect metals against attack by corrosive substances such as hydrogen sulfide, carbon dioxide and sea water, if necessary under hydrothermal conditions. At the same time it is also abrasion stable, for example against a grinding effect by sand, as well as resistant to the impact of mechanical load e.g. by tools. This is achieved by a coating composition comprising a binder comprising at least one cross-linkable resin, wherein the resin comprises at least one of polar group; at least one type of hydrophilic flakes with an aspect ratio of more than 10, wherein the surface of the flakes at least partially comprises a metal oxide; and an organic solvent.