Composite Dielectric Layer for Etch Selectivity and Strength

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Solution Overview

Problem

The semiconductor industry faces challenges in scaling down semiconductor devices while maintaining high performance and low costs, leading to increased complexity in processing and manufacturing due to the need for high storage capacity and fast processing systems.

Innovation Solution

The development of a composite dielectric layer formed through alternately stacking silicon-containing dielectric layers with varying compositions of Si, C, O, and N, achieved by tuning precursor materials, deposition cycles, and plasma treatments, which enhances mechanical and chemical properties such as Young's modulus and etching selectivity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If semiconductor devices are scaled down to increase packing density and storage capacity, then device integration and storage capacity are improved, but processing and manufacturing complexity increases

Engineering Contradiction:
Improvestorage capacityVSAvoidprocessing complexity
Core Design Contradiction:
Quantity of substanceVSDevice complexity

Solution Approach 1:

The dielectric layer is segmented into multiple sub-layers with different compositions (first dielectric layer with higher nitrogen content, second dielectric layer with higher carbon content). This segmentation allows each sub-layer to provide specific functions independently, managing the complexity of scaled-down devices through modular structure design.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent employs composite dielectric materials with varying Si, C, O, and N compositions in different layers. This composite approach enables optimization of mechanical and chemical properties for specific processing requirements, addressing the manufacturing complexity challenge by providing tailored material properties for scaled-down device fabrication.

Inventive Principle:
Principle #40Composite materials

2Length of moving object

If dielectric layers are made thinner to accommodate scaled-down devices, then device dimension is reduced, but mechanical strength and processing control become more difficult to maintain

Engineering Contradiction:
Improvedevice dimensionVSAvoidmechanical strength
Core Design Contradiction:
Length of moving objectVSStrength

Solution Approach 1:

Different regions of the dielectric layer structure are assigned different compositions and properties. The first dielectric layer has higher nitrogen content for specific mechanical properties, while the second dielectric layer has higher carbon content for different mechanical characteristics. This local quality differentiation maintains overall mechanical strength even as the total thickness is reduced for scaled-down devices.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The composite dielectric structure combines materials with different compositions to achieve the required mechanical strength at reduced thickness. The synergistic combination of nitrogen-rich and carbon-rich layers provides enhanced mechanical properties that would not be achievable with a single uniform material at the same reduced thickness.

Inventive Principle:
Principle #40Composite materials

3Device complexity

If single-layer dielectric structures are used to simplify manufacturing, then device complexity is reduced, but etching selectivity and processing control are insufficient

Engineering Contradiction:
Improvestructure complexityVSAvoidetching selectivity
Core Design Contradiction:
Device complexityVSManufacturing precision

Solution Approach 1:

The dielectric layer is divided into multiple segments (first and second dielectric layers) with distinct compositions. This segmentation provides different etching rates and selectivities for each layer, enabling precise processing control during fabrication. The segmented structure allows selective etching operations to target specific layers, improving manufacturing precision despite increased structural complexity.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent varies compositional parameters (Si, C, O, N content) between different dielectric layers to achieve desired etching selectivity. By changing the chemical composition parameters of each layer, the etching behavior can be precisely controlled, allowing different layers to be etched at different rates or with different selectivities to underlying structures.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composite dielectric layer improves mechanical strength and chemical selectivity, enabling better processing control and integration in semiconductor structures, thereby addressing the complexity and performance demands of scaled-down semiconductor devices.

Implementation Method 1

a dielectric layer formed over the substrate and the gate structure

Methodology Applied
Scientific EffectDielectric insulation: Dielectric

Implementation Method 2

formed by a physical vapor deposition (PVD) process

Methodology Applied
Scientific EffectPhysical vapor deposition: Physical Vapour Deposition

Implementation Method 3

formed by a chemical vapor deposition (CVD) process

Methodology Applied
Scientific EffectChemical vapor deposition: Chemical Vapour Deposition

Data Source

PatentUS11935752B2Device of dielectric layer
Publication Date: 2024.03.19 TAIWAN SEMICONDUCTOR MANUFACTURING CO LTD
  • US11935752B2 patent drawing
  • US11935752B2 patent drawing
  • US11935752B2 patent drawing

AI summary

A device includes a first dielectric layer, a first conductor, an etch stop layer, a second dielectric layer, and a second conductor. The first conductor is in the first dielectric layer. The etch stop layer is over the first dielectric layer. The etch stop layer has a first surface facing the first dielectric layer and a second surface facing away from the first dielectric layer, and a concentration of carbon in the etch stop layer periodically varies from the first surface to the second surface. The second dielectric layer is over the etch stop layer. The second conductor is in the second dielectric layer and the etch stop layer and electrically connected to the first conductor.