Composite Dispersant for Dyes Resolving Foam and Viscosity

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Solution Overview

Problem

Existing dispersants for disperse dyes and pigments are inefficient in achieving quick dispersion and stability, often requiring high quantities and causing issues like high viscosity and foam formation, with limited effectiveness across different dye and pigment types.

Innovation Solution

A dispersant composition comprising acetylenic surfactants, nonionic aryl phenol compounds, and anionic aryl phenol compounds, which enables efficient dispersion and stability in small additive quantities, improving wettability and defoamability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-generated harmful factors

If a nonionic surfactant including an acetylene group is used as a dispersant, then penetrability and anti-foamability of ink are improved, but dispersing performance deteriorates and dispersion time increases

Engineering Contradiction:
Improvefoam formationVSAvoiddispersion time
Core Design Contradiction:
Object-generated harmful factorsVSProductivity

Solution Approach 1:

The patent uses a composite dispersant system combining nonionic surfactant (acetylene glycol or ethoxylated acetylene glycol) with aryl phenol compound and carboxylic acid. This composite approach leverages the foam-control capability of the acetylenic surfactant while the aryl phenol and carboxylic acid components provide rapid dispersion performance, resolving the contradiction between anti-foamability and dispersing speed

Inventive Principle:
Principle #40Composite materials

2Productivity

If polymeric dispersants are used, then dispersing performance is improved, but dispersion viscosity increases and preparation becomes difficult

Engineering Contradiction:
Improvedispersing performanceVSAvoiddispersion viscosity
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The patent changes the molecular weight parameter of the dispersant components, using low-molecular-weight compounds (aryl phenol with 6-20 carbons, carboxylic acid with 2-10 carbons) instead of high-molecular-weight polymers. This parameter change maintains dispersing performance while significantly reducing dispersion viscosity and simplifying preparation

Inventive Principle:
Principle #35Parameter changes

3Productivity

If polymeric dispersants are used, then dispersing performance is improved, but ink composition dries easily

Engineering Contradiction:
Improvedispersing performanceVSAvoidink stability
Core Design Contradiction:
ProductivityVSDuration of action of stationary object

Solution Approach 1:

The patent changes the molecular weight and functional group parameters of the dispersant, using small-molecule compounds with specific functional groups (aryl phenol and carboxylic acid) instead of large polymers. This provides adequate dispersing performance while maintaining better ink stability and preventing excessive drying

Inventive Principle:
Principle #35Parameter changes

4Productivity

If a large quantity of dispersant is added to achieve good dispersion, then dispersing performance is improved, but foam formation increases

Engineering Contradiction:
Improvedispersing performanceVSAvoidfoam formation
Core Design Contradiction:
ProductivityVSObject-generated harmful factors

Solution Approach 1:

The patent employs a composite dispersant system where the nonionic acetylenic surfactant component specifically targets foam suppression while the aryl phenol and carboxylic acid components provide dispersion power. This functional division allows achieving good dispersing performance with reduced total dispersant quantity and minimized foam formation

Inventive Principle:
Principle #40Composite materials

5Object-generated harmful factors

If dispersant quantity is reduced, then foam formation is reduced, but dispersing performance deteriorates

Engineering Contradiction:
Improvefoam formationVSAvoiddispersing performance
Core Design Contradiction:
Object-generated harmful factorsVSProductivity

Solution Approach 1:

The composite dispersant system allows each component to contribute its strength: the acetylenic surfactant controls foam at low concentrations while the aryl phenol and carboxylic acid provide efficient dispersion. This synergistic combination breaks the trade-off between foam reduction and dispersing performance

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The dispersant achieves rapid dispersion and excellent stability for various disperse dyes and pigments, maintaining performance over time and reducing viscosity and foam issues.

Implementation Method 1

Nonionic surfactants, anionic surfactants, and polymer surfactants have been proposed as examples of such dispersants. a nonionic surfactant including an acetylene group is useful as a pigment dispersant

Methodology Applied
Scientific EffectSurfactant: Surfactant

Data Source

PatentUS11066568B2Dispersant, dispersion and ink composition, and preparing method thereof
Publication Date: 2021.07.20 NISSHIN CHEM IND CO LTD
  • US11066568B2 patent drawing
  • US11066568B2 patent drawing
  • US11066568B2 patent drawing

AI summary

A dispersant, a dispersion and an ink composition including the dispersant, and a method of preparing the dispersion and the ink composition, in which the dispersant includes: (A) 0.5 to 30% by weight of a compound selected from at least one of acetylene glycol represented by the specific formula (1) and an ethoxylated substance of acetylene glycol represented by the specific formula (2); (B) 5 to 98% by weight of a nonionic aryl phenol compound represented by the specific formula (3); and (C) 1 to 70% by weight of an anionic aryl phenol compound represented by the specific formula (4), and wherein the total amount of components (A) to (C) is 100% by weight.