Composite Organic EL Material Flash Deposition

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Solution Overview

Problem

Existing methods for producing organic electroluminescence (EL) devices face challenges in maintaining material integrity and uniformity due to high-temperature degradation and uneven evaporation during vacuum deposition, leading to inefficiencies in material usage and film formation.

Innovation Solution

A composite organic EL material is developed by combining an organic material with an organic metal complex, where the melting point of the organic material is lower than the decomposition temperature of the metal complex by at least 30°C, allowing for minimized decomposition and efficient flash deposition, using a method that involves mixing, heating, and cooling the materials to optimize their properties for use in organic EL devices.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If physical vapor deposition is used to form organic thin films, then film formation is achieved, but material decomposition occurs due to constant high-temperature heating

Engineering Contradiction:
Improvematerial integrityVSAvoiddeposition temperature
Core Design Contradiction:
ReliabilityVSTemperature

Solution Approach 1:

The patent employs flash deposition where the organic material is heated rapidly for a very short duration (milliseconds to seconds) and then cooled, creating a periodic heating-cooling cycle. This allows the material to be deposited before significant thermal decomposition can occur, resolving the contradiction between achieving deposition and maintaining material integrity

Inventive Principle:
Principle #19Periodic action

Solution Approach 2:

The flash deposition method rushes through the deposition process extremely quickly, completing film formation in milliseconds to seconds. This skimps the exposure time to high temperatures, allowing deposition to occur before decomposition can significantly degrade the material quality

Inventive Principle:
Principle #21Skipping (Rushing through)

2Manufacturing precision

If vacuum deposition is used to evaporate organic material, then thin film formation is achieved, but material usage efficiency decreases due to uncontrolled evaporation direction

Engineering Contradiction:
Improvefilm uniformityVSAvoidmaterial utilization
Core Design Contradiction:
Manufacturing precisionVSLoss of substance

Solution Approach 1:

The flash deposition creates a periodic process where material is rapidly vaporized and then quickly deposited onto the substrate. This time-controlled periodic action ensures that evaporation and deposition occur in a coordinated manner, improving both film uniformity and material utilization efficiency

Inventive Principle:
Principle #19Periodic action

Solution Approach 2:

The patent changes the temporal parameters of the deposition process by using extremely short heating pulses followed by rapid cooling. This parameter change in time control allows precise management of the evaporation and deposition rates, improving film quality and material efficiency

Inventive Principle:
Principle #35Parameter changes

3Adaptability or versatility

If mixed materials are supplied to flash deposition source, then composite film formation is achieved, but material uniformity deteriorates during mixing and deposition

Engineering Contradiction:
Improvecomposite material capabilityVSAvoidmaterial ratio uniformity
Core Design Contradiction:
Adaptability or versatilityVSManufacturing precision

Solution Approach 1:

The patent performs preliminary mixing of the organic material with the metal complex at controlled ratios before deposition. This preliminary preparation ensures uniform distribution of components, which is then maintained during the rapid flash deposition process, achieving both composite functionality and compositional uniformity

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composite material effectively suppresses decomposition during production, enabling high-performance organic electroluminescence devices with improved material utilization and film uniformity, suitable for flash deposition methods.

Implementation Method 1

an organic material is evaporated by heating to a high temperature in a vacuum environment, whereby a thin film of an organic material is formed on a substrate

Methodology Applied
Scientific EffectEvaporation: Evaporation

Implementation Method 2

physical deposition under a vacuum environment is generally used as a method for forming a thin film of an organic material

Methodology Applied
Scientific EffectPhysical vapor deposition: Physical Vapour Deposition

Data Source

PatentUS8425801B2Composite organic electroluminescent material and production method thereof
Publication Date: 2013.04.23 IDEMITSU KOSAN CO LTD
  • US8425801B2 patent drawing
  • US8425801B2 patent drawing
  • US8425801B2 patent drawing

AI summary

A composite organic EL material suited to flash deposition and a method for producing the same are provided. A composite organic electroluminescence material in which an organic material and an organic metal complex are combined with each other, wherein the melting point of the organic material is lower by 30° C. or more than the decomposition temperature of the organic metal complex.