Composite Electrolyte Gel for High-Conductivity Separator-Free Batteries

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Solution Overview

Problem

Existing electrolytes for secondary batteries face challenges in achieving both high ion conductivity and mechanical strength, particularly when a separator is not used.

Innovation Solution

An electrolyte comprising an ionic liquid, an inorganic oxide, and a binder formed from polycarbonate polyol and polyisocyanate, with functional groups such as trialkoxysilyl, epoxy, or oxetanyl, and optionally including boron or aluminum compounds, to enhance ion conductivity and mechanical properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If a separator is used in the electrolyte, then mechanical strength is improved, but device complexity increases

Engineering Contradiction:
Improvemechanical strengthVSAvoiddevice complexity
Core Design Contradiction:
StrengthVSDevice complexity

Solution Approach 1:

The patent merges the separator function and binder function into a single component. The binder containing inorganic oxide particles and having gel-forming capability performs both the binding function and the separator function (providing mechanical strength and preventing short circuit), thereby eliminating the need for a separate separator layer and reducing device complexity while maintaining mechanical strength

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The binder is designed to perform multiple functions simultaneously: it provides mechanical strength through inorganic oxide particles, creates gel structure for ion conduction, and acts as a separator preventing direct contact between electrodes. This multi-functional design eliminates the need for separate separator component

Inventive Principle:
Principle #6Universality (Multi-functionality)

2Reliability

If the electrolyte is made with high ion conductivity, then ion conductivity is improved, but mechanical strength deteriorates

Engineering Contradiction:
Improveion conductivityVSAvoidmechanical strength
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The electrolyte uses a composite structure where inorganic oxide particles (such as alumina, silica) are dispersed within a gel-forming binder matrix. The inorganic oxide provides mechanical strength and structural stability, while the gel-forming binder creates a three-dimensional network that allows efficient ion conduction. This composite approach enables simultaneous achievement of high ion conductivity and mechanical strength

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent modifies the physical and chemical parameters of the binder by selecting compounds with specific gel-forming capabilities and molecular weights. By controlling the gel fraction, crosslinking density, and molecular weight of the binder, the electrolyte achieves optimal balance between ion conductivity (requiring high mobility) and mechanical strength (requiring structural rigidity)

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The electrolyte achieves high ion conductivity and mechanical strength, with the addition of boron or aluminum compounds further increasing ion conductivity while maintaining strength, suitable for use in storage devices like lithium secondary batteries.

Implementation Method 1

the binder includes, at an end, at least one functional group selected from the group consisting of a trialkoxysilyl group having 1 to 4 carbon atoms, an epoxy group, and an oxetanyl group

Methodology Applied
Scientific EffectGel formation: Gel

Implementation Method 2

an inorganic oxide, and a binder

Methodology Applied
Scientific EffectDispersion: Dispersion (of waves)

Data Source

PatentUS20240047742A1Electrolyte and storage device
Publication Date: 2024.02.08 DKS CO LTD

AI summary

Techniques relating to an electrolyte having high ion conductivity and high strength are provided. The electrolyte includes an ionic liquid, an inorganic oxide, and a binder, wherein the binder is formed from raw materials that are a polycarbonate polyol and a polyisocyanate, and the binder includes, at an end, at least one functional group selected from the group consisting of a trialkoxysilyl group having 1 to 4 carbon atoms, an epoxy group, and an oxetanyl group.