Metal Matrix Composite Feedstock With In-Situ Ceramic Dispersion

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Solution Overview

Problem

Existing additive manufacturing processes face challenges in achieving proper mixing and distribution of nanoparticles within bulk feedstock, particularly in Laser Powder Bed Fusion, where nanoparticles are not evenly dispersed throughout the metal matrix composite, leading to undesirable microstructures and properties.

Innovation Solution

A feedstock powder comprising a pre-ceramic polymer and a base material, where the pre-ceramic polymer is tailored to pyrolyze at specific temperatures matching the melt pool temperature of the base material, ensuring even dispersion and formation of well-distributed fine precipitates, thereby facilitating graded properties in the manufactured articles.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If nanoparticles are added to feedstock for metal matrix composite additive manufacturing, then the composite properties are improved, but the mixing and distribution of particles in bulk feedstock becomes difficult to achieve properly

Engineering Contradiction:
Improvecomposite propertiesVSAvoidparticle distribution
Core Design Contradiction:
StrengthVSManufacturing precision

Solution Approach 1:

The pre-ceramic polymer is added to the feedstock before the additive manufacturing process, allowing it to pyrolyze in advance during the build process. This preliminary inclusion ensures that the ceramic particles are generated in-situ within the melt pool, eliminating the distribution problems that would occur if pre-mixed nanoparticles were used.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The pre-ceramic polymer acts as an intermediary substance that converts into ceramic particles during pyrolysis. Instead of directly adding problematic nanoparticles to the feedstock, the polymer serves as a precursor that transforms into the desired ceramic reinforcement, mediating between the metal matrix and the ceramic phase.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Manufacturing precision

If pre-ceramic polymer is used in feedstock, then even dispersion of secondary phases is achieved, but the process complexity increases due to temperature tailoring requirements

Engineering Contradiction:
Improvedispersion uniformityVSAvoidprocess control
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The invention changes the chemical composition parameter of the feedstock by incorporating pre-ceramic polymer with specific pyrolysis temperatures. By selecting polymers whose decomposition temperatures match the melt pool temperatures of specific base materials, the process achieves controlled ceramic formation without requiring additional process complexity.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The pre-ceramic polymer self-regulates the ceramic particle formation process through its inherent pyrolysis temperature characteristics. The polymer automatically decomposes at its characteristic temperature, which is matched to the base material's melt pool temperature, eliminating the need for external control mechanisms to regulate particle generation.

Inventive Principle:
Principle #25Self-service

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of pre-ceramic polymer and base material feedstock enables even dispersion of secondary phases within the metal matrix composite, resulting in exceptional graded properties and improved microstructure, overcoming the issue of nanoparticle aggregation and uneven distribution in the additive manufacturing process.

Implementation Method 1

the pre-ceramic polymer is tailored to pyrolyze at specific temperatures matching the melt pool temperature of the base material

Methodology Applied
Scientific EffectPyrolysis: Pyrolysis

Implementation Method 2

Laser Powder Bed Fusion (LPBF) is an additive manufacturing process involving the construction of a three-dimensional article by selectively projecting a laser beam having the desired energy onto a layer of feedstock particles

Methodology Applied
Scientific EffectLaser heating: Laser

Data Source

PatentEP3096937B1Additive manufacturing of metal matrix composite feedstock
Publication Date: 2022.03.23 RTX CORP
  • EP3096937B1 patent drawingFigure 1
  • EP3096937B1 patent drawingFigure 2~3

AI summary

A feedstock for an additive manufacturing process includes a pre-ceramic polymer intermixed with a base material. A method of additive manufacturing includes melting and pyrolizing a feedstock containing metal and a pre-ceramic polymer. An article of manufacture includes an additive manufacturing component including a pyrolized feedstock.