Composite Filler Dispersion via Rotating Surface Ligaments

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Conventional methods for dispersing micro- and nano-fillers in polymer composites face limitations due to filler agglomeration, leading to restricted loading levels and altered composite properties, particularly when using nano-fillers, which increase viscosity and require energy-intensive processes and surfactants that can be costly and environmentally harmful.

Innovation Solution

A method involving a combination of mechanical and electrical forces to disperse fillers by forming ligaments on a rotating surface, where centrifugal and electrostatic forces induce shear and extensional flow deformations, breaking down agglomerations and achieving higher filler loading levels without the need for surfactants.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If conventional mechanical mixing methods are used to disperse fillers in polymer composites, then the mixing process is simple and equipment is readily available, but filler agglomeration occurs and loading levels are restricted

Engineering Contradiction:
Improvefiller loading levelVSAvoidfiller dispersion uniformity
Core Design Contradiction:
Quantity of substanceVSStability of the object's composition

Solution Approach 1:

The continuous polymer stream is segmented into discrete ligaments as it passes over the rotating surface. This segmentation increases the surface area to volume ratio and allows fillers to be distributed more uniformly throughout the polymer matrix, preventing agglomeration and enabling higher loading levels.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The rotating surface imparts mechanical energy and vibration to the polymer-filler mixture, creating shear forces that break down filler agglomerations. The rotational motion generates dynamic mixing action that enhances filler dispersion while maintaining uniform distribution throughout the composite material.

Inventive Principle:
Principle #18Mechanical vibration

2Stability of the object's composition

If surfactants are added to reduce surface energy and facilitate nano-filler dispersion, then filler distribution improves, but composite properties are altered and environmental harm increases

Engineering Contradiction:
Improvefiller dispersion uniformityVSAvoidenvironmental impact and property alteration
Core Design Contradiction:
Stability of the object's compositionVSObject-affected harmful factors

Solution Approach 1:

The invention removes surfactants from the composite formulation entirely. By using mechanical and electrical field forces for filler dispersion, the need for chemical additives is eliminated, preserving the intrinsic properties of the polymer and filler while avoiding environmental harm associated with surfactant use.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

Conventional mechanical mixing is replaced with a combination of electrical field forces and mechanical ligament formation. This substitution uses non-contact electrical forces to achieve filler dispersion without requiring chemical surfactants, thereby avoiding property alterations and environmental issues.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

3Strength

If high shear mixers and extrusion compounders are used for dispersive mixing, then mechanical mixing is effective for micro-sized fillers, but nano-sized agglomerations cannot be broken up

Engineering Contradiction:
Improvemixing effectiveness for micro-fillersVSAvoidnano-filler dispersion quality
Core Design Contradiction:
StrengthVSManufacturing precision

Solution Approach 1:

The invention changes the physical parameters of the mixing process by applying electrical field forces and creating ligament structures. This parameter change enables effective dispersion of nano-sized fillers that cannot be achieved with conventional mechanical shear mixing alone, while still maintaining effectiveness for micro-sized fillers.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

Conventional mechanical shear mixing is supplemented and enhanced with electrical field forces. This substitution introduces a new mechanism for applying stress to filler agglomerations, enabling breakdown of nano-sized structures that are resistant to traditional mechanical mixing methods.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

4Use of energy by moving object

If conventional mixing methods are used, then processing is energy efficient, but production rates are limited and filler distribution is inadequate

Engineering Contradiction:
Improveenergy consumptionVSAvoidproduction rate and filler distribution quality
Core Design Contradiction:
Use of energy by moving objectVSProductivity

Solution Approach 1:

The rotating surface operates continuously to form and process ligaments, enabling continuous production of dispersed composite material. This continuous action maintains high production rates while the efficient ligament formation process ensures adequate filler distribution throughout the polymer matrix.

Inventive Principle:
Principle #20Continuity of useful action

Solution Approach 2:

The rotational motion creates dynamic mechanical energy input that enhances mixing efficiency. This vibration and mechanical energy transfer improves both production rate and filler distribution quality simultaneously, overcoming the limitations of conventional static mixing methods.

Inventive Principle:
Principle #18Mechanical vibration

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach results in well-dispersed composite materials with higher filler loading levels, improved mechanical properties, and reduced viscosity, enhancing production rates and filler distribution compared to conventional methods.

Implementation Method 1

subjecting the liquid composite mixture to a first force on a rotating surface to form liquid ligaments... wherein the first force is a mechanical force... the first force is a centrifugal force

Methodology Applied
Scientific EffectCentrifugal force: Centrifugal Force

Implementation Method 2

the at least one second force are a centrifugal force and an electrostatic force... the at least one second force imparts both shear flow deformation and extensional flow deformation to the liquid ligaments

Methodology Applied
Scientific EffectElectrostatic force: Electrostatics

Data Source

PatentEP3071397B1Method for forming composites
Publication Date: 2024.04.17 TRUSSCORE INC
  • EP3071397B1 patent drawingFigure 1
  • EP3071397B1 patent drawingFigure 2
  • EP3071397B1 patent drawingFigure 3

AI summary

There is provided a method and system for forming a composite material. The method includes: combining a first component element with a second component element to form a composite mixture; subjecting the composite mixture to a first force to in order to form ligaments and disperse the first component element and second component element in relation to each other, wherein the first force is a mechanical force; subjecting the ligaments to at least one second force in order to form attenuated ligaments and further disperse the first component element and second component element in relation to each other, wherein the at least one second force imparts both shear flow deformation and extensional flow deformation to the ligaments to form the attenuated ligaments; and collecting the attenuated ligaments. There is also provided a composite material prepared using the method described above.