Composite Gate Oxide Radiation Hardness via Segmentation

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Solution Overview

Problem

Cosmic radiation, such as gamma rays, affects semiconductor devices in space by creating electron/hole pairs, where holes can become trapped in oxide layers, leading to performance degradation and mode conversion of transistors, causing off-state leakage and threshold voltage shifts, rendering devices unreliable in harsh radiation environments.

Innovation Solution

Creating defect sites in insulator layers to trap holes, forming a composite thick gate oxide layer using CVD processes, which includes a thin thermal oxide and deposited spacer materials, improving radiation hardness with minimal perturbation to existing semiconductor fabrication processes.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a thick gate oxide layer is formed to improve radiation hardness, then device reliability in radiation environments improves, but manufacturing complexity and process perturbation increase

Engineering Contradiction:
Improveradiation hardnessVSAvoidprocess complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The gate oxide layer is segmented into multiple portions: a first portion formed by thermal oxidation and a second portion formed by CVD. This segmentation allows each portion to contribute different properties - the thermal oxide provides good interface quality while the CVD oxide adds thickness for radiation hardness, achieving the desired reliability without requiring a completely new thick oxide process

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The gate oxide is formed as a composite structure combining thermally grown oxide and CVD-deposited oxide. This composite approach leverages the advantages of both formation methods - the thermal oxide's excellent silicon interface and the CVD oxide's controllable thickness and radiation hardness - to achieve reliable radiation-hardened devices

Inventive Principle:
Principle #40Composite materials

2Reliability

If defect sites are created in insulator layers to trap holes, then threshold voltage control improves, but manufacturing precision requirements increase

Engineering Contradiction:
Improvethreshold voltage controlVSAvoiddefect site precision
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

Defect sites are preliminarily created in the insulator layer during the CVD process by controlling deposition conditions to form nitrogen-containing defects. These pre-formed defect sites are positioned to trap holes before they can migrate to critical regions, thereby controlling threshold voltage without requiring precise post-processing adjustment of defect locations

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent converts the potentially harmful effect of holes trapped in oxide layers (which causes threshold voltage shifts) into a beneficial control mechanism. By deliberately creating defect sites that trap holes in controlled locations, the invention transforms an uncontrolled harmful effect into a controlled feature that stabilizes threshold voltage

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

3Reliability

If CVD processes are used to form insulator layers, then radiation hardness improves, but manufacturing process complexity increases

Engineering Contradiction:
Improveradiation hardnessVSAvoidprocess ease
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent merges the CVD process with existing thermal oxidation steps in a unified gate oxide formation sequence. The CVD oxide deposition is integrated into the standard gate oxide fabrication flow, combining it with thermal oxidation to create a multi-layer structure that achieves radiation hardness while maintaining compatibility with existing manufacturing processes

Inventive Principle:
Principle #5Merging (Combining)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution effectively controls threshold voltage and other parameters, enhancing the reliability of semiconductor devices in radiation-hardened environments by trapping holes and maintaining device performance, reducing the risk of mode conversion and leakage.

Implementation Method 1

a second portion is formed by depositing a spacer material on the thin gate insulator layer

Methodology Applied
Scientific EffectChemical Vapour Deposition: Chemical Vapour Deposition

Implementation Method 2

a first portion is a thin gate insulator layer formed by a thermal method

Methodology Applied
Scientific EffectThermal oxidation: Oxidation

Data Source

PatentUS9147613B2Method of forming an insulator layer in a semiconductor structure and structures resulting therefrom
Publication Date: 2015.09.29 RENESAS ELECTRONICS AMERICA INC
  • US9147613B2 patent drawing
  • US9147613B2 patent drawing
  • US9147613B2 patent drawing

AI summary

An electronic system, method of manufacture of a semiconductor structure, and one or more semiconductor structures are disclosed. For example, a method of manufacture of a semiconductor structure is disclosed, which includes forming a first semiconductor substructure over a semiconductor substrate, forming a first spacer layer over the first semiconductor substructure and the semiconductor substrate, and forming a second semiconductor substructure over at least a portion of the first spacer layer.