Composite Host Materials for OLED Driving Voltage and Efficiency

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Solution Overview

Problem

Current organic electroluminescent devices face challenges in achieving improved driving voltage, luminous efficiency, and lifespan characteristics, with existing materials not meeting practical requirements for enhanced performance.

Innovation Solution

A combination of specific host compounds, represented by formulas 1, 2, 3, and 4, are used to form a plurality of host materials that improve the performance of organic electroluminescent devices by reducing driving voltage and increasing luminous efficiency and lifespan, comprising aryl and heteroaryl groups with various substituents and linkages, allowing for their use in light-emitting layers.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Power

If conventional host materials are used in OLED, then device structure is simple, but driving voltage is high and luminous efficiency is low

Engineering Contradiction:
Improvedriving voltageVSAvoidhost material structure
Core Design Contradiction:
PowerVSDevice complexity

Solution Approach 1:

The patent employs composite host materials comprising a first host compound (formula 1) and a second host compound (formula 2) in specific weight ratios. The first host compound contains aryl/heteroaryl groups with electron-donating or electron-withdrawing substituents, while the second host compound contains carbazole or triphenylene core structures. This composite approach enables optimization of both driving voltage and luminous efficiency by combining the advantageous properties of different material classes, resolving the contradiction between simple structure and improved power performance.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent systematically varies key parameters including molecular weight (150-500 Da for first host, 200-600 Da for second host), substituent types (electron-donating groups like alkyl/arylamino, electron-withdrawing groups like cyano/carboxyl), and weight ratios (95:5 to 50:50) to achieve optimal balance between driving voltage reduction and luminous efficiency enhancement, demonstrating parameter optimization to resolve the technical contradiction.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If conventional host materials are used in OLED, then manufacturing process is simple, but luminous efficiency is low and lifespan is short

Engineering Contradiction:
Improvelifespan characteristicsVSAvoidmaterial synthesis complexity
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent optimizes molecular weight parameters within specific ranges (150-500 Da for first host, 200-600 Da for second host) to balance lifespan enhancement with manufacturability. These controlled parameter adjustments ensure materials maintain reasonable synthesis complexity while achieving improved reliability through optimized molecular structures that reduce degradation pathways.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

By combining first host compounds with aryl/heteroaryl cores and second host compounds with carbazole/triphenylene structures in controlled ratios, the patent creates composite materials that enhance lifespan through synergistic effects while maintaining compatibility with existing manufacturing processes. The composite structure provides both improved reliability and feasibility for industrial production.

Inventive Principle:
Principle #40Composite materials

3Loss of energy

If phosphorescent materials are used to improve luminous efficiency, then luminous efficiency increases, but driving voltage increases and lifespan decreases

Engineering Contradiction:
Improveluminous efficiencyVSAvoiddriving voltage
Core Design Contradiction:
Loss of energyVSPower

Solution Approach 1:

The patent uses composite host materials as an alternative approach to phosphorescent materials, combining first host compounds (formula 1) with aryl/heteroaryl groups and second host compounds (formula 2) with carbazole or triphenylene cores. This composite organic host system achieves improved luminous efficiency through enhanced exciton utilization while maintaining lower driving voltages and extended lifespan through the specific molecular structures and their synergistic interactions in the light-emitting layer.

Inventive Principle:
Principle #40Composite materials

Data Source

PatentUS20240349527A1Plurality of host materials, organic electroluminescent compound, and organic electroluminescent device comprising the same
Publication Date: 2024.10.17 DUPONT SPECIALTY MATERIALS KOREA LTD
  • US20240349527A1 patent drawing
  • US20240349527A1 patent drawing
  • US20240349527A1 patent drawing

AI summary

The present disclosure relates to a plurality of host materials comprising a first host material comprising a compound represented by formula 1 and a second host material comprising a compound represented by formula 2, an organic electroluminescent compound represented by formula 3 and formula 4, and an organic electroluminescent device comprising the same.