Composite material, method for producing same, and method for producing reinforcing fiber base material

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Solution Overview

Problem

Carbon fiber-reinforced molded articles require enhanced mechanical, electrical, and thermal properties, necessitating a composite material that further leverages the properties of carbon nanotubes (CNTs).

Innovation Solution

A composite material is developed with bent-shaped CNTs forming a network structure on a carbon fiber base, where a carbodiimide-derived cross-linking agent is used to strengthen the adhesion between CNTs, creating a robust network that enhances mechanical and electrical conductivity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If carbon nanotubes are adhered to carbon fiber surfaces to enhance mechanical and electrical properties, then the composite material achieves improved strength and conductivity, but the CNTs tend to peel off from the fiber surfaces, reducing the effectiveness of the enhancement

Engineering Contradiction:
Improvemechanical strengthVSAvoidadhesion stability
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The patent applies a sizing agent to the carbon fiber base material before adhering the carbon nanotubes. This preliminary action modifies the surface properties of the carbon fibers, creating a more effective bonding interface that prevents subsequent peeling of the CNTs while maintaining their adhesion for mechanical and electrical enhancement.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The sizing agent acts as an intermediary substance between the carbon fiber base material and the carbon nanotubes. It facilitates strong adhesion between these two components, ensuring that the CNTs remain firmly attached to the fiber surfaces and effectively transfer mechanical and electrical properties without peeling off.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Reliability

If a network structure of carbon nanotubes is formed on the base material surface to improve electrical and thermal conductivity, then the conductivity properties are enhanced, but the structural complexity increases making production more difficult

Engineering Contradiction:
Improveelectrical conductivityVSAvoidstructure complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The base material surface is pre-treated with a sizing agent before CNT deposition. This preliminary surface modification creates optimal conditions for forming a uniform, well-adhered CNT network structure, reducing production difficulties while achieving the desired conductive network.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent modifies surface parameters of the base material through sizing agent treatment, changing surface energy, roughness, or chemical composition. These parameter changes facilitate the formation of a uniform CNT network structure with improved electrical and thermal conductivity while simplifying the overall production process.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution results in improved mechanical strength, thermal conductivity, and electrical conductivity by ensuring strong adhesion and reduced peeling of CNTs from the carbon fibers, leading to enhanced performance in carbon fiber-reinforced molded articles.

Implementation Method 1

cross-links the carbon nanotubes which are in direct contact with each other by a carbodiimide-derived structure obtained by reaction between a functional group of the carbon nanotubes and a carbodiimide group

Methodology Applied
Scientific EffectChemical reaction: Chemical Bonding

Implementation Method 2

a dispersion in which a plurality of carbon nanotubes having a bent shape with a bent portion are dispersed and to which ultrasonic vibration is applied to adhere the plurality of carbon nanotubes to the base material

Methodology Applied
Scientific EffectUltrasonic vibration: Ultrasonic Vibration

Data Source

PatentUS20240052557A1Composite material, method for producing same, and method for producing reinforcing fiber base material
Publication Date: 2024.02.15 NITTA CORP
  • US20240052557A1 patent drawing
  • US20240052557A1 patent drawing
  • US20240052557A1 patent drawing

AI summary

A composite material includes: a base material; a structure which includes a plurality of carbon nanotubes having a bent shape with a bent portion, forms a network structure including a contact portion where the carbon nanotubes are in direct contact with each other, and is provided on a surface of the base material; and a first sizing agent that is provided at least around the contact portion, and cross-links the carbon nanotubes which are in direct contact with each other by a carbodiimide-derived structure obtained by reaction between a functional group of the carbon nanotubes and a carbodiimide group.