Composite Mesoporous Microporous Material for Tobacco Smoke Filtration

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Solution Overview

Problem

Current filter materials in cigarettes are inadequate for removing gaseous components from tobacco smoke, such as volatile organic compounds, as they primarily focus on particulate and condensable components.

Innovation Solution

Incorporation of a composite mesoporous/microporous material, capable of sorption and catalysis, into cigarette filters or tobacco filler compositions to selectively remove constituents like aldehydes, carbon monoxide, and other harmful gases from tobacco smoke, utilizing zeolites and metals like iron, copper, and palladium.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If traditional filter materials (cotton, paper, cellulose, synthetic fibers) are used, then particulate and condensable components are removed effectively, but gaseous components (volatile organic compounds) are not removed

Engineering Contradiction:
Improveremoval of gaseous componentsVSAvoidfiltration effectiveness for gases
Core Design Contradiction:
Object-affected harmful factorsVSReliability

Solution Approach 1:

The patent employs mesoporous silica materials with controlled pore sizes (2-50 nm) that are specifically designed to adsorb gaseous components through their porous structure. The mesoporous material provides high surface area and appropriate pore dimensions for capturing volatile organic compounds while maintaining breathability for smoke flow.

Inventive Principle:
Principle #31Porous materials

Solution Approach 2:

The invention creates a composite filter structure combining traditional filter materials (cotton, cellulose, synthetic fibers) with mesoporous silica materials. This composite approach integrates the particulate filtration capability of traditional materials with the gas adsorption capability of mesoporous materials, achieving both functions simultaneously.

Inventive Principle:
Principle #40Composite materials

2Object-affected harmful factors

If filter materials are designed to remove particulate components, then particulate filtration is effective, but gas phase constituents remain in the smoke

Engineering Contradiction:
Improvegaseous component removalVSAvoidmulti-component filtration capability
Core Design Contradiction:
Object-affected harmful factorsVSAdaptability or versatility

Solution Approach 1:

The mesoporous silica material serves multiple functions: it adsorbs gaseous components through its porous structure, provides catalytic activity for decomposing certain compounds, and maintains structural integrity within the filter assembly. This single material addresses multiple harmful factors (gases, volatiles, and potentially particulates) simultaneously, enhancing the versatility of the filtration system.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composite mesoporous/microporous material effectively removes at least 30% of targeted constituents from mainstream tobacco smoke, enhancing the filtration capabilities beyond traditional filter materials by incorporating both microporous and mesoporous regions with interconnected channels.

Implementation Method 1

the composite mesoporous/microporous material is capable of removing at least one constituent from tobacco smoke through sorption and/or catalysis

Methodology Applied
Scientific EffectSorption: Sorption

Implementation Method 2

the composite mesoporous/microporous material is capable of removing at least one constituent from tobacco smoke through sorption and/or catalysis

Methodology Applied
Scientific EffectCatalysis: Catalysis

Data Source

PatentUS8439047B2Composite mesoporous/microporous materials and their use in smoking articles for removing certain gas phase constituents from tobacco smoke
Publication Date: 2013.05.14 PHILIP MORRIS USA INC
  • US8439047B2 patent drawing
  • US8439047B2 patent drawing
  • US8439047B2 patent drawing

AI summary

Cut filler compositions, cigarettes, methods for making cigarettes and methods for smoking cigarettes are provided, which involve the use of a composite mesoporous/microporous material. The composite material is capable of removing at least one constituent from tobacco smoke, preferably selectively. The composite material may also be used for removing at least one constituent from tobacco smoke through sorption and/or catalysis. The composite material comprises channels interconnecting at least one mesoporous region and at least one microporous region. The mesopores of the composite material may further comprise a carbon lining and/or be further functionalized with a surfactant. Alternatively, the composite material may further comprise a metal, a metal oxide, or mixtures thereof.